2,3,5,6-Tetra(1H-tetrazol-5-yl)pyrazine: A Thermally Stable Nitrogen-Rich Energetic Material
Source abstract
Abstract
A synthetic protocol was developed to create a unique nitrogen-rich (71.58% N) energetic material, namely, 2,3,5,6-tetra(1 H -tetrazol-5-yl)pyrazine (H 4 TTP). This compound was prepared using a convenient and straightforward method of synthesis and shows useful energetic properties such as detonation velocity ( V C-J = 8655 m s –1 ), detonation pressure ( p C-J = 28.0 GPa), and high temperature of decomposition ( T dec = 260 °C). H 4 TTP was isolated and characterized using mass spectrometry, multinuclear ( 1 H, 13 C) NMR spectroscopy, and vibrational spectroscopy (IR, Raman). The molecular structure was determined via single-crystal X-ray diffraction. High nitrogen content and relative planarity of the molecule, along with the attained properties such as hydrolytic stability, high thermal stability, density, detonation velocity, and its facile synthesis, make H 4 TTP a highly interesting energetic material.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Energetic Materials and Combustion · Thermal and Kinetic Analysis · Combustion and Detonation Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5
Defence Research and Development Canada—Suffield, P. O. Box 4000, Station Main, Medicine Hat, Alberta, Canada T1A 8K6
Funding
Defence Research and Development Canada
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