journal article·2018-03-26

High-Voltage Cr4+/Cr3+ Redox Couple in Polyanion Compounds

Kosuke Kawai, Wenwen Zhao, Shin-ichi Nishimura, Atsuo Yamada

ACS Applied Energy Materials· Volume 1· Issue 3
Publisher page

Abstract

Higher-voltage operation is crucial to increase the energy density of rechargeable batteries. Here we explored the Cr4+/Cr3+ redox couple in a polyanion framework for a high-voltage sodium battery cathode. An archetypal NASICON-phase Na3Cr2(PO4)3 exhibited a reversible redox activity at ca. 4.5 V versus Na/Na+, offering further scope for searching new high-voltage materials based on Cr4+/Cr3+ redox couple.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research

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Affiliations

Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-8656, Japan

Elemental Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

Funding

Ministry of Education, Culture, Sports, Science and Technology · The University of Tokyo

References (25)

Show source-provided references
1. 10.1149/2.0151514jes10.1149/2.0151514jes ↗
2. 10.1002/aenm.20160094310.1002/aenm.201600943 ↗
3. 10.1149/1.183786810.1149/1.1837868 ↗
4. 10.1021/cr300186210.1021/cr3001862 ↗
5. 10.1002/adma.20160192510.1002/adma.201601925 ↗
6. 10.1016/0025-5408(87)90112-710.1016/0025-5408(87)90112-7 ↗
7. 10.1021/ja311044t10.1021/ja311044t ↗
8. 10.1002/aenm.20120080310.1002/aenm.201200803 ↗
9. 10.1021/acs.chemmater.6b0209610.1021/acs.chemmater.6b02096 ↗
10. 10.1021/acs.nanolett.6b0404410.1021/acs.nanolett.6b04044 ↗
11. 10.1039/C7RA05214F10.1039/C7RA05214F ↗
12. 10.1002/anie.20160102210.1002/anie.201601022 ↗
13. 10.1016/j.jpowsour.2013.01.16210.1016/j.jpowsour.2013.01.162 ↗
14. 10.1038/am.2017.4110.1038/am.2017.41 ↗
15. 10.1021/ja406016j10.1021/ja406016j ↗
16. 10.1002/aenm.20150214710.1002/aenm.201502147 ↗
17. 10.1038/ncomms535810.1038/ncomms5358 ↗
18. 10.1021/cm200949v10.1021/cm200949v ↗
19. 10.1016/j.electacta.2014.06.17010.1016/j.electacta.2014.06.170 ↗
20. 10.1107/S090904950501271910.1107/S0909049505012719 ↗
21. 10.1016/0167-2738(83)90101-710.1016/0167-2738(83)90101-7 ↗
22. 10.1016/0167-2738(83)90096-610.1016/0167-2738(83)90096-6 ↗
23. 10.1016/0167-2738(86)90292-410.1016/0167-2738(86)90292-4 ↗
24. 10.1021/ja204321y10.1021/ja204321y ↗
25. 10.1021/acs.chemmater.5b0209210.1021/acs.chemmater.5b02092 ↗