journal article·2019-05-28

Synthesis of Single Lithium-Ion Conducting Polymer Electrolyte Membrane for Solid-State Lithium Metal Batteries

Guangmei Luo, Bing Yuan, Tianyun Guan, Fangyi Cheng, Wangqing Zhang, Jun Chen

ACS Applied Energy Materials· Volume 2· Issue 5
Publisher page

Abstract

Synthesis of single lithium-ion conducting polymer electrolyte membrane (SLIC-PEM) composed of polymerized lithium 4-styrenesulfonyl(trifluoromethylsulfonyl)imide (PLiSTFSI), poly(ethylene glycol) methyl ether methacrylate (PEGM), poly(ethylene glycol) dimethacrylate (PEGDMA), and ethylene carbonate (EC) is reported. SLIC-PEM combines the advantages of single lithium-ion conducting polymer electrolytes, cross-linked flexible polymer electrolytes, and the liquid electrolyte of carbonate. The synthesized SLIC-PEMs have superior thermostability, high ionic conductivity, a wide electrochemical window, and high lithium-ion transference number. The corresponding LiFePO4|SLIC-PEM|Li cell delivers high Coulombic efficiency and excellent discharge capacity and cycling performance, demonstrating that SLIC-PEMs will have promising application in next-generation safe lithium metal batteries.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Functional Polymer Materials of the Ministry of Education, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Key Laboratory of Advanced Energy Materials Chemistry of the Ministry of Education, College of Chemistry, Nankai University, Tianjin 300071, China

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Science and Technology Commission Foundation of Tianjin

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