journal article·2022-10-24

High-Performance Lithium-Ion Battery and Supercapacitors Using Covalent Organic Frameworks (COFs)/Graphitic Carbon Nitride (g-C3N4)-Derived Hierarchical N-Doped Carbon

Mervat Ibrahim, Moataz G. Fayed, Saad G. Mohamed, Zhen Wen, Xuhui Sun, Hani Nasser Abdelhamid

ACS Applied Energy Materials· Volume 5· Issue 10
Publisher page

Abstract

Energy storage materials have advanced renewable energy technologies. Herein, we described the one-pot synthesis of covalent organic frameworks (COFs)/graphitic carbon nitride (g-C3N4) nanocomposite. The condensation of melamine and benzene-1,3,5-tricarboxyaldehyde with and without g-C3N4 offered the synthesis of COF and COF/g-C3N4. Furthermore, N-doped carbon and N-doped carbon/g-C3N4 were synthesized via the carbonization of COF and COF/g-C3N4, respectively. The materials i.e., before and after carbonization were used as electrode materials for supercapacitors and lithium-ion batteries (LIBs). They showed specific capacitance of 211, 257.5, 450, and 835.2 F·g–1 for COF, COF/g-C3N4, N-doped carbon, and N-doped carbon/g-C3N4, respectively. Asymmetric supercapacitor device using N-doped carbon/g-C3N4 exhibited good energy (45.97 Wh·kg–1) with high power (659.3 W·kg–1). The N-doped C/g-C3N4 electrode was also applied for LIBs, offering a discharge capacity of 390 mAh·g–1 (at 50 mA·g–1).
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Covalent Organic Framework Applications · Supercapacitor Materials and Fabrication · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Functional Nano and Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, China

Chemistry Department, Faculty of Science, New Valley University, El-Kharja 72511, Egypt

Mining and Metallurgy Engineering Department, Tabbin Institute for Metallurgical Studies (TIMS), Tabbin 109, Helwan 11421, Cairo, Egypt

Advanced Multifunctional Materials Laboratory, Department of Chemistry, Assiut University, Assiut 71516, Egypt

Proteomics Laboratory for Clinical Research and Materials Science, Department of Chemistry, Assiut University, Assiut 71516, Egypt

Nanotechnology Research Centre (NTRC), The British University in Egypt (BUE), Suez Desert Road, El-Sherouk City 11837, Cairo, Egypt

Funding

Science and Technology Development Fund · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Priority Academic Program Development of Jiangsu Higher Education Institutions · Higher Education Discipline Innovation Project · International Research Laboratory of Carbon-Based Functional Materials and Devices

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