journal article·2026-07-28

Three-Dimensional Porous Sheet-like rGO/NiCo2O4 Composite Films for Triethylamine Gas Sensors with Excellent Flexibility and Ultrafast Response

Yalou Lv, Yuhan Shen, Xiaoyang Guo, Qiqi Zhuo

ACS Applied Electronic Materials· Volume 8· Issue 14
Publisher page

Abstract

Abstract The development of efficient and quick-response gas sensors for triethylamine (TEA) detection is crucial for human safety and environmental protection. In this study, reduced graphene oxide (rGO)/NiCo2O4 composite films were fabricated by a hydrothermal method to construct flexible gas sensors for the detection of TEA. The rGO/NiCo2O4 sensor demonstrated a linear response to 1–200 ppm TEA, with ultrafast response/recovery times (4/9 s) at 50 ppm as well as excellent stability and sensitivity under cyclic and humidity tests. The response efficiencies were 91.56%, 87.19%, and 85.71% after 60 bending cycles at 30°, 60°, and 90°, respectively, which indicated good flexibility and stability. This study provided a viable strategy for wearable flexible gas sensors in environmental monitoring and health protection.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Electrical and Thermal Properties of Materials · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Jiangsu University of Science and Technology , , 666 Chang-Hui Road , , ,

Funding

Postgraduate Research & Practice Innovation Program of Jiangsu Province

References (58)

Show source-provided references
1. Synthesis of porous nanosheets-assembled ZnO/ZnCo2O4 hierarchical structure for TEA detection10.1016/j.snb.2019.02.055 ↗
2. Triethylamine gas sensor based on Pt-functionalized hierarchical ZnO microspheres10.1016/j.snb.2020.129425 ↗
3. Unique Pd/PdO−In2O3 heterostructures for the highly efficient detection of triethylamine10.1039/D3TA02405A ↗
4. Fast recovery triethylamine gas sensor with low detection limit based on NiTiO3−In2O310.1016/j.ceramint.2023.10.334 ↗
5. Highly responsive and swift recovery triethylamine gas sensor based on NiCo2O4-ZnO p-n heterojunction10.1016/j.snb.2024.135666 ↗
6. NiO/BiVO4 p-n heterojunction microspheres for conductometric triethylamine gas sensors10.1016/j.snb.2023.133625 ↗
7. Ppb-Level Triethylamine Gas Sensors Based on Palladium Nanoparticles Modified Flower-Like In2O3 Grown on rGO Nanosheets Operating at Low Temperature10.1109/TIM.2022.3189731 ↗
8. Sn doping effect on NiO hollow nanofibers based gas sensors about the humidity dependence for triethylamine detection10.1016/j.snb.2021.129971 ↗
9. Room temperature triethylamine gas sensor with excellent performances based on novel porous CuO foam via a simple and facile route10.1016/j.snb.2023.133934 ↗
10. Modulation of ZnFe2O4/ZnO heterostructure for enhanced triethylamine sensing performance10.1016/j.snb.2024.135580 ↗
11. Rational design of ZnO-SnO2 Janus nanofibers for highly sensitive triethylamine detection10.1016/j.snb.2024.136805 ↗
12. Epitaxial growth of Co3O4/In2O3 p-n heterostructure with rich oxygen vacancies for ultrahigh triethylamine sensing10.1016/j.snb.2023.134881 ↗
13. Dual enhancement in response and anti-humidity properties of a triethylamine sensor based on trimethoxypropylsilane self-assembled functionalized In2O310.1016/j.snb.2024.136120 ↗
14. ZrO2-CeO2/WO3 heterostructure films prepared by magnetron sputtering for humidity-tolerant triethylamine sensing10.1016/j.snb.2024.136334 ↗
15. Cobalt-doping-induced energy level and oxygen vacancy dual modulation in tin dioxide for efficient triethylamine detection10.1016/j.snb.2024.135998 ↗
16. UV-triggered carrier transport regulation of fibrous NiO/SnO2 heterostructures for triethylamine detection10.1016/j.cej.2023.146687 ↗
17. Nitrogen-doped ZnO microspheres with a yolk-shell structure for high sensing response of triethylamine10.1016/j.snb.2023.133882 ↗
18. UV-triggered and temperature-control carrier transport regulation of ZnO/Ti3C2Tx MXene heterostructures for dual selective HCHO and triethylamine detection10.1016/j.snb.2024.136158 ↗
19. Tailoring the triethylamine vapor sensing on Co-Fe bimetallic oxide nanosheets assemblies by crystal structure and doping sites10.1016/j.snb.2024.135477 ↗
20. Interface-engineering in MOF-derived In2O3 for highly sensitive and dual-functional gas sensor towards NO2 and triethylamine10.1016/j.snb.2023.134491 ↗
21. Efficient triethylamine sensing achieved by in-situ Zn2+ doping regulated Mo-MOFs derived MoO3/ZnMoO4 heterostructures10.1016/j.snb.2024.136479 ↗
22. One-step synthesis of Pt-CNTs/rGO electrocatalyst for wearable methanol sensing: Effect of supports on gas-sensitive property10.1016/j.cej.2023.147441 ↗
23. Ultra-high response and selectivity of triethylamine sensor based on NiO/Pd/SnO2 multiple heterojunctions composite10.1016/j.snb.2025.137652 ↗
24. An ultra-sensitive triethylamine sensor based on WO3 modified ErVO4 nanoparticles10.1016/j.vacuum.2025.114440 ↗
25. Rational design of NiCo2O4/ZnO hierarchical heterostructures with enhanced triethylamine sensing performance10.1016/j.microc.2026.117783 ↗
26. Extremely Flexible Methanol Sensor Based on CNFs/ NiCo2O4 Nanocomposite10.1021/acsanm.4c03925 ↗
27. Controllable Synthesis of a Hybrid Carbon Nanofiber/NiCo2O4 Composite for Supercapacitors10.1021/acsaem.5c02154 ↗
28. Synthesis of Double-Layered NiCo2O4-Nanosheet-Loaded PAN/Lignin-Based Hollow Carbon Nanofibers for High-Performance Supercapacitor10.1002/slct.201904546 ↗
29. Sensing properties of CdS-doped tin oxide thick film gas sensor10.1016/j.snb.2009.10.013 ↗
30. In2S3-Gr and In2S3-CNT nanocomposite thin films as gas sensors10.1016/j.diamond.2022.109215 ↗
31. Design and Synthesis of Parallel Bicomponent Heterojunction Nanofibers as Flexible Room-Temperature Sensors for Ppb-Level NO2 Detection10.1021/acsanm.3c05737 ↗
32. Smart Sensor Systems for Wearable Electronic Devices10.3390/polym9080303 ↗
33. Integrated technologies for continuous monitoring of organs-on-chips: Current challenges and potential solutions10.1016/j.bios.2022.115057 ↗
34. Proteomic Study on Multi-Organ Metastases of Human Ovarian Clear Cell Carcinoma Cell Line in a Xenograft Mouse Model Based on a Novel Sequence-Specific Analysis Strategy10.31083/j.fbl2803053 ↗
35. In Situ-Polymerized PANI/WS2 Nanocomposites for Highly Sensitive Flexible Ammonia Gas Sensors and Respiration Monitoring Devices10.1021/acsanm.3c05965 ↗
36. Phase transition and electrical conversion properties of Ge/Sb nano-multilayer films on flexible substrates10.1038/s41528-024-00296-1 ↗
37. Recent advances in two-dimensional nanomaterials for sustainable wearable electronic devices10.1186/s12951-023-02274-7 ↗
38. A high performance triboelectric nanogenerator using assembled sugar naphthalimides for self-powered electronics and sensors10.1016/j.cej.2024.151800 ↗
39. Mesopores NiCo2O4 nano-needles directly grown on Ni foam as high-performance electrodes for supercapacitors10.1016/j.matlet.2020.128523 ↗
40. Vertically Aligned NiCo2O4 Nanosheet-Encapsulated Carbon Fibers as a Self-Supported Electrode for Superior Li+ Storage Performance10.3390/nano9091336 ↗
41. High performance supercapacitor electrode materials based on porous NiCo2O4 hexagonal nanoplates/reduced graphene oxide composites10.1016/j.cej.2014.10.079 ↗
42. Al-doped ZnO thin films as methanol sensors10.1016/j.snb.2008.06.006 ↗
43. A stable and highly-sensitive flexible gas sensor based on Ceria (CeO2) nano-cube decorated rGO nanosheets for selective detection of NO2 at room temperature10.1016/j.synthmet.2023.117411 ↗
44. Ligand-assisted deposition of ultra-small Au nanodots on Fe(2)O(3)/reduced graphene oxide for flexible gas sensors10.1039/D1NA00734C ↗
45. Hydrothermally grown α-MnO2 interlocked mesoporous micro-cubes of several nanocrystals as selective and sensitive nitrogen dioxide chemoresistive gas sensors10.1016/j.apsusc.2018.02.144 ↗
46. Utilizing Data Mining for the Synthesis of Functionalized Tungsten Oxide with Enhanced Oxygen Vacancies for Highly Sensitive Detection of Triethylamine10.1021/acsami.3c16021 ↗
47. PVA/Ti3C2Tx/CoFe2O4 nanocomposite hydrogel for TENG-powered and flexible gas sensor: towards highly selective room temperature triethylamine gas detection with fast response and recovery10.1016/j.talanta.2025.128962 ↗
48. A flexible sensor based on polyaniline hybrid using ZnO as template and sensing properties to triethylamine at room temperature10.1016/j.apsusc.2016.12.133 ↗
49. Highly selective low-temperature triethylamine sensor based on Ag/Cr2O3 mesoporous microspheres10.1016/j.snb.2015.06.023 ↗
50. Plasma-induced oxygen vacancies enabled ultrathin ZnO films for highly sensitive detection of triethylamine10.1016/j.jhazmat.2021.125757 ↗
51. Tunable resistance of MOFs films via an anion exchange strategy for advanced gas sensing10.1016/j.jhazmat.2021.125906 ↗
52. Triboelectric Nanogenerator Based on CPDs-WO3/MXene Bilayer Film for Triethylamine Sensing and Fish Meat Spoilage Detection10.1021/acs.langmuir.4c04247 ↗
53. Constructing bilayer sensors with Co-MOF-derived Co3O4 porous sensing films and SnO2 catalytic overlayers to enhance room-temperature triethylamine sensing performance10.1016/j.ceramint.2023.03.276 ↗
54. Heterogeneous Co3O4/AgO nanorods for conductometric triethylamine sensing at 90 °C10.1016/j.snb.2021.131005 ↗
55. Porous CeO2 nanospheres for a room temperature triethylamine sensor under high humidity conditions10.1039/c8nj03300e ↗
56. p−p Heterojunction of Nickel Oxide-Decorated Cobalt Oxide Nanorods for Enhanced Sensitivity and Selectivity toward Volatile Organic Compounds10.1021/acsami.7b14545 ↗
57. The Impact of Functionalization on the Stability, Work Function, and Photoluminescence of Reduced Graphene Oxide10.1021/nn305507p ↗
58. Ag-Doped Sea Urchin-Like NiCo2O4 for High-Performance Triethylamine Gas Sensing10.1007/s11837-025-07422-y ↗