journal article·2025-05

P2-type Na0.67Mn0.6Ni0.3Ti0.1O2 as cathode material for sodium-ion batteries: solid electrolyte versus liquid electrolyte

Shiyin Bai, Qing Ni, Shuaishuai Yang, Debao Fang, Jingxin He, Lai Chen, Yuefeng Su, Haibo Jin, Chengzhi Wang

Journal of Materials Science· Volume 60· Issue 20
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Li Y, Vasileiadis A, Zhou Q, Lu Y, Meng Q, Li Y, Ombrini P, Zhao J, Chen Z, Niu Y, Qi X, Xie F, van der Jagt R, Ganapathy S, Titirici M-M, Li H, Chen L, Wagemaker M, Hu Y-S (2024) Origin of fast charging in hard carbon anodes. Nat Energy 9:134–14210.1038/s41560-023-01414-5 ↗
2. Jin Y, Le PML, Gao P, Xu Y, Xiao B, Engelhard MH, Cao X, Vo TD, Hu J, Zhong L, Matthews BE, Yi R, Wang C, Li X, Liu J, Zhang J-G (2022) Low-solvation electrolytes for high-voltage sodium-ion batteries. Nat Energy 7:718–72510.1038/s41560-022-01055-0 ↗
3. Zhao C, Wang Q, Yao Z, Wang J, Sánchez-Lengeling B, Ding F, Qi X, Yaxiang Lu, Bai X, Li B, Li H, Aspuru-Guzik A, Huang X, Delmas C, Wagemaker M, Liquan Chen Y-S (2020) Rational design of layered oxide materials for sodium-ion batteries. Science 370:708–71110.1126/science.aay9972 ↗
4. Yang Y, Wang Z, Du C, Wang B, Li X, Wu S, Li X, Zhang X, Wang X, Niu Y, Ding F, Rong X, Lu Y, Zhang N, Xu J, Xiao R, Zhang Q, Wang X, Yin W, Zhao J, Chen L, Huang J, Hu Y-S (2024) Decoupling the air sensitivity of Na-layered oxides. Science 385:744–75210.1126/science.adm9223 ↗
5. Delmas C, Fouassier C, Hagenmuller P (1980) Structural classification and properties of the layered oxides. Phys B & C 99:81–8510.1016/0378-4363(80)90214-4 ↗
6. Risthaus T, Zhou D, Cao X, He X, Qiu B, Wang J, Zhang L, Liu Z, Paillard E, Schumacher G, Winter M, Li J (2018) A high-capacity P2 Na2/3Ni1/3Mn2/3O2 cathode material for sodium ion batteries with oxygen activity. J Power Sour 395:16–2410.1016/j.jpowsour.2018.05.026 ↗
7. Lee SY, Kim JH, Kang YC (2017) Electrochemical properties of P2-type Na2/3Ni1/3Mn2/3O2 plates synthesized by spray pyrolysis process for sodium-ion batteries. Electrochim Acta 225:86–9210.1016/j.electacta.2016.11.141 ↗
8. Pei Q, Lu M, Liu Z, Li D, Rao X, Liu X, Zhong S (2022) Improving the Na0.67Ni0.33Mn0.67O2 cathode material for high-voltage cyclability via Ti/Cu codoping for sodium-ion batteries. ACS Appl Energy Mater 5:1953–196210.1021/acsaem.1c03466 ↗
9. Ma XH, Li LL, Cheng L, Qiao F, Ye YY, Li N, Sha ML, Zi ZF, Dai JM (2020) P2-type Na0.8(Li0.33Mn0.67-xTix)O2 doped by Ti as cathode materials for high performance sodium-ion batteries. J Alloys Compds. 815:15240210.1016/j.jallcom.2019.152402 ↗
10. Huang Y, Yan Z, Luo W, Hu Z, Liu G, Zhang L, Yang X, Ou M, Liu W, Huang L, Lin H, Chen C-T, Luo J, Li S, Han J, Chou S, Huang Y (2020) Vitalization of P2–Na2/3Ni1/3Mn2/3O2 at high-voltage cyclability via combined structural modulation for sodium-ion batteries. Energy Storage Mater 29:182–18910.1016/j.ensm.2020.04.012 ↗
11. Feng J, Luo S-H, Sun M, Cong J, Yan S, Wang Q, Zhang Y, Liu X, Mu W, Hou P-Q (2022) Investigation of Ti-substitution and MnPO4 coating effects on structural and electrochemical properties of P2-Na0.67TixNi0.33Mn0.67-xO2 cathode materials. Appl. Surface Sci. 600:15414710.1016/j.apsusc.2022.154147 ↗
12. Tao S, Zhou W, Wu D, Wang Z, Qian B, Chu W, Marcelli A, Song L (2021) Insights into the Ti4+ doping in P2-type Na0.67Ni0.33Mn0.52Ti0.15O2 for enhanced performance of sodium-ion batteries. J Mater Sci Tech 74:230–23610.1016/j.jmst.2020.06.055 ↗
13. Zarrabeitia M, Gonzalo E, Pasqualini M, Ciambezi M, Lakuntza O, Nobili F, Trapananti A, Di Cicco A, Aquilanti G, Katcho NA, López del Amo JM, Carrasco J, Muñoz-Márquez MÁ, Rojo T (2019) Unraveling the role of Ti in the stability of positive layered oxide electrodes for rechargeable Na-ion batteries. J Mater Chem A 7:14169–1417910.1039/C9TA02710F ↗
14. Milewska A, Świerczek K, Zając W, Molenda J (2018) Overcoming transport and electrochemical limitations in the high-voltage Na0.67Ni0.33Mn0.67-yTiyO2 (0 ≤ y ≤ 0.33) cathode materials by Ti-doping. J Power Sour 404:39–4610.1016/j.jpowsour.2018.09.103 ↗
15. Zuo C, Dong D, Wang H, Sun Y, Lu Y-C (2024) Bromide-based nonflammable electrolyte for safe and long-life sodium metal batteries. Energy Environ Sci 17:791–79910.1039/D3EE03332E ↗
16. Zhong S, Yu Y, Yang Y, Yao Y, Wang L, He S, Yang Y, Liu L, Sun W, Feng Y, Pan H, Rui X, Yu Y (2023) Molecular engineering on solvation structure of carbonate electrolyte toward durable sodium metal battery at − 40 °C. Angew Chem Inter Ed 62:e20230116910.1002/anie.202301169 ↗
17. Tian W, Li Z, Miao L, Sun Z, Wang Q, Jiao L (2023) Composite quasi-solid-state electrolytes with organic-inorganic interface engineering for fast ion transport in dendrite-free sodium metal batteries. Adv Mater 36:230858610.1002/adma.202308586 ↗
18. Rynearson L, Antolini C, Jayawardana C, Yeddala M, Hayes D, Lucht BL (2023) Speciation of transition metal dissolution in electrolyte from common cathode materials. Angew Chem Inter Ed 63:e20231710910.1002/anie.202317109 ↗
19. Pan J, Zhang Y, Sun F, Osenberg M, Hilger A, Manke I, Cao R, Dou S, Fan H (2023) Designing solvated double-layer polymer electrolytes with molecular interactions mediated stable interfaces for sodium ion batteries. Angew Chem Int Ed Engl 135:e20221900010.1002/ange.202219000 ↗
20. He J, Bhargav A, Su L, Lamb J, Okasinski J, Shin W, Manthiram A (2024) Tuning the solvation structure with salts for stable sodium-metal batteries. Nat Energy 9:446–45610.1038/s41560-024-01469-y ↗
21. Gao H, Xin S, Xue L, Goodenough JB (2018) Stabilizing a high-energy-density rechargeable sodium battery with a solid electrolyte. Chem 4:833–84410.1016/j.chempr.2018.01.007 ↗
22. Wei B, Huang S, Wang X, Liu M, Huang C, Liu R, Jin H (2025) Intermediate phase induced in situ self-reconstruction of amorphous NASICON for long-life solid-state sodium metal batteries. Energy Environ Sci 18:831–84010.1039/D4EE01743A ↗
23. Jaschin PW, Tang CR, Wachsman ED (2024) High-rate cycling in 3D dual-doped NASICON architectures toward room-temperature sodium-metal-anode solid-state batteries. Energy Environ Sci 17:727–73710.1039/D3EE03879C ↗
24. Chen C, Chen W, Gong F, Li Y (2024) Mg/Ti co-substituted P2-Na0.67Ni0.23Mg0.05Ti0.05Mn0.67O2 cathode with outstanding performance for Na-ion batteries. Mater Lett 377:13742410.1016/j.matlet.2024.137424 ↗
25. Kalyoncuoglu B, Ozgul M, Altundag S, Harfouche M, Oz E, Avci S, Ji X, Altin S, Ates MN (2024) Unveiling the outstanding full-cell performance of P2-type Na0.67(Mn0.44Ni0.06Fe0.43Ti0.07)O2 cathode active material for Na-ion batteries. J Power Sour 591:23377510.1016/j.jpowsour.2023.233775 ↗
26. Wang Y, Xiao R, Hu Y-S, Avdeev M, Chen L (2015) P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries. Nat Commun 6:695410.1038/ncomms7954 ↗
27. Zou L, Zhong J, Wei Q, Lin Y, Zhou Y, Fu Y, Yu R, Gao P, Shu H, Liu L, Yang W, Yang X, Wang X (2024) Enabling rapid and stable sodium storage via a P2-type layered cathode with high-voltage zero-phase transition behavior. Small 20:240031510.1002/smll.202400315 ↗
28. Kim H-J, Voronina N, Köster K, Kim AY, Jung H-G, Kim H, Yazawa K, Yashiro H, Kaghazchi P, Myung S-T (2024) Synergetic impact of dual substitution on anionic–cationic activity of P2-type sodium manganese oxide. Energy Storage Mater 66:10322410.1016/j.ensm.2024.103224 ↗
29. Li X, Wang J, Duan F, Tao L, Xu T, Chen L, Yuan A, Wang X (2021) Improved cycling stability of P2-type Na0.71Co0.96O2 cathode material by optimizing Ti doping. J Solid State Electrochem 26:269–28010.1007/s10008-021-05067-w ↗
30. Deng J, Wang Y, Wang Z, Li J, Luo Y (2021) Ti and V co-doped P2-Na0.59Co0.10Mn0.90O2 cathode with excellent sodium storage performance. Chem Phys Lett 783:13905010.1016/j.cplett.2021.139050 ↗
31. Yan L, Li X, Pan H (2024) Modulating valence electrons and Na occupancy in layered cathodes for high-performance Na-ion batteries. ACS Appl Mater Interfaces 16:26280–2628710.1021/acsami.4c04256 ↗
32. Huang J, Xu L, Ye D, Wu W, Qiu S, Tang Z, Wu X (2024) Suppressing the P2–O2 phase transition of P2-type Ni/Mn-based layered oxide by synergistic effect of Zn/Ti co-doping for advanced sodium-ion batteries. J Alloys Compds 976:17339710.1016/j.jallcom.2023.173397 ↗
33. Huang R, Luo S, Li P, Sun Q, Sun K, Zhao W, Wang J, Yan S (2024) Enhanced structural stability of P2-Na0.75Ni0.25Mn0.75-xTixO2 cathodes with high-voltage non-phase transitions property by Mn-sites manipulation strategy. J. Alloys Compds. 1005:17616810.1016/j.jallcom.2024.176168 ↗
34. Dogan E, Altundag S, Altin E, Oz E, Altin S (2024) P2-type Na0.67Mn0.5-xVxFe0.43Ti0.07O2 powders for Na-ion cathodes: ex-situ structural analysis and full-cell study. Electrochim Acta 473:14347010.1016/j.electacta.2023.143470 ↗
35. Yan M, Xu K, Chang Y-X, Xie Z-Y, Xu S (2023) Cu/Ti co-doping boosting P2-type Fe/Mn-based layered oxide cathodes for high-performance sodium storage. J Coll Interface Sci 651:696–70410.1016/j.jcis.2023.07.195 ↗
36. Ma S, Zou P, Xin HL (2023) Extending phase-variation voltage zones in P2-type sodium cathodes through high-entropy doping for enhanced cycling stability and rate capability. Mater Today Energy 38:10144610.1016/j.mtener.2023.101446 ↗
37. Wang J-Z, Teng Y-X, Su G-Q, Bao S, Lu J-L (2022) A dual-modification strategy for P2-type layered oxide via bulk Mg/Ti co-substitution and MgO surface coating for sodium ion batteries. J Coll Interface Sci 608:3013–302110.1016/j.jcis.2021.11.028 ↗
38. Jiao J, Wu K, Li N, Zhao E, Yin W, Hu Z, Wang F, Zhao J, Xiao X (2022) Tuning anionic redox activity to boost high-performance sodium-storage in low-cost Na0.67Fe0.5Mn0.5O2 cathode. J Energy Chem 73:214–22210.1016/j.jechem.2022.04.042 ↗
39. Han H, Guo S, Chen Y, Guo S, Hong N, Fan J, Long Z, Qiu X (2022) Stable electrochemical properties of titanium doped layered P2-type Na0.67Ni0.15Mn0.85O2 cathode material for sodium ion batteries. J Electrochem Soc 169:08052310.1149/1945-7111/ac8a20 ↗
40. Li D, Sun C, Wang C, Li J, Wang Z, Jin H (2023) Regulating Na/NASCION electrolyte interface chemistry for stable solid-state Na metal batteries at room temperature. Energy Storage Mater 54:403–40910.1016/j.ensm.2022.10.056 ↗
41. Jin H, Xiao X, Chen L, Ni Q, Sun C, Miao R, Li J, Su Y, Wang C (2023) Rechargeable solid-state Na-metal battery operating at − 20 °C. Adv Sci 10:230277410.1002/advs.202302774 ↗
42. Samiee M, Radhakrishnan B, Rice Z, Deng Z, Meng YS, Ong SP, Luo J (2017) Divalent-doped Na3Zr2Si2PO12 natrium superionic conductor: improving the ionic conductivity via simultaneously optimizing the phase and chemistry of the primary and secondary phases. J Power Sour 347:229–23710.1016/j.jpowsour.2017.02.042 ↗
43. He J, Yang S, Xiao X, Fang D, Miao R, Wang C, Chen L, Li N, Li J, Su Y, Jin H (2025) Aliovalent cation substitution in Na3Zr2Si2PO12 for practical solid-state sodium metal batteries. Energy Storage Mater 75:10403710.1016/j.ensm.2025.104037 ↗
44. Fang D, Li Y, Wang C, Miao R, Yang S, Zhao Y, Ding Y, He J, Chen L, Li N, Li J, Su Y, Jin H (2025) Wide-temperature solid-state sodium metal batteries using Na+ superionic conductor-type solid electrolytes. Energy Storage Mater 74:10397310.1016/j.ensm.2024.103973 ↗
45. Zhao Y, Wang C, Dai Y, Jin H (2021) Homogeneous Na+ transfer dynamic at Na/Na3Zr2Si2PO12 interface for all solid-state sodium metal batteries. Nano Energy 88:10629310.1016/j.nanoen.2021.106293 ↗
46. Wang C, Sun Z, Zhao Y, Wang B, Shao C, Sun C, Zhao Y, Li J, Jin H, Qu L (2021) Grain boundary design of solid electrolyte actualizing stable all-solid-state sodium batteries. Small 17:210381910.1002/smll.202103819 ↗
47. Wang C, Sun C, Sun Z, Wang B, Song T, Zhao Y, Li J, Jin H (2022) Optimizing the Na metal/solid electrolyte interface through a grain boundary design. J Mater Chem A 10:5280–528610.1039/D1TA10816F ↗
48. Wang C, Jin H, Zhao Y (2021) Surface potential regulation realizing stable sodium/Na3Zr2Si2PO12 interface for room-temperature sodium metal batteries. Small 17:210097410.1002/smll.202100974 ↗
49. Wang C, Gao J, Gao X, Zhao Y (2021) Stabilizing the Na/Na3Zr2Si2PO12 interface through intrinsic feature regulation of Na3Zr2Si2PO12. Cell Rep Phys Sci 2:10047810.1016/j.xcrp.2021.100478 ↗
50. Yang S, Liang J, He J, Fang D, Zhao Y, Ding Y, Yin A, Li Y, Wang C, Li J, Jin H (2024) Regulating the interfacial performance of all-solid-state sodium batteries using lanthanum substitution in a Na3Zr2Si2PO12 solid electrolyte. ACS Appl Energy Mater 7:9863–987110.1021/acsaem.4c01837 ↗
51. Miao R, Wang C, Li D, Sun C, Li J, Jin H (2022) Uniform Na metal plating/stripping design for highly reversible solid-state Na metal batteries at room temperature. Small 18:220448710.1002/smll.202204487 ↗
52. Habibi M, Habibi-Yangjeh A, Khataee A (2023) Oxygen vacancy-rich CeO2 decorated with Cu3BiS3 nanoparticles: outstanding visible-light photocatalytic performance towards tetracycline degradation. J. Chemosph 340:139828.1-139828.1410.1016/j.chemosphere.2023.139828 ↗
53. Wu H, Li M, Zhao Y, Zhou Z, Hua S, Zhang J (2022) Mxene-based composite forward osmosis (FO) membrane intercalated by halloysite nanotubes with superior water permeance and dye desalination performance. Chem Eng Res Des 180:55–6610.1016/j.cherd.2022.02.007 ↗