journal article·2025-07

Impact of Ti4O7 conductive additive in NCM111 cathode for high-performance lithium-ion batteries

Huacheng Wang, Biao Guo, Ziqi Xiong, Xian Jian, Xinghua Zhu

Journal of Materials Science· Volume 60· Issue 25
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Extraction and Separation Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Blecua De Pedro M, Ponce CH, De Meatza I et al (2023) Environmental and economic assessment of a higher energy density and safer operation lithium-ion cell for stationary applications. Sustain Mater Technol 37:e00704. https://doi.org/10.1016/j.susmat.2023.e0070410.1016/j.susmat.2023.e00704 ↗
2. Lu Y (2024) Study on the performance of lithium iron phosphate battery based on its application in transportation field. J Phys: Conf Ser 2798:012019. https://doi.org/10.1088/1742-6596/2798/1/01201910.1088/1742-6596/2798/1/012019 ↗
3. Chen Y, Kang Y, Zhao Y et al (2021) A review of lithium-ion battery safety concerns: the issues, strategies, and testing standards. J Energy Chem 59:83–99. https://doi.org/10.1016/j.jechem.2020.10.01710.1016/j.jechem.2020.10.017 ↗
4. Guan P, Zhou L, Yu Z et al (2020) Recent progress of surface coating on cathode materials for high-performance lithium-ion batteries. J Energy Chem 43:220–235. https://doi.org/10.1016/j.jechem.2019.08.02210.1016/j.jechem.2019.08.022 ↗
5. Jung C-H, Shim H, Eum D, Hong S-H (2021) Challenges and recent progress in LiNixCoyMn1−x−yO2 (NCM) cathodes for lithium ion batteries. J Korean Ceram Soc 58:1–27. https://doi.org/10.1007/s43207-020-00098-x10.1007/s43207-020-00098-x ↗
6. Wang Y, Zhao D, Zhang K et al (2020) Enhancing the rate performance of high-capacity LiNi0.8Co01.5Al0.05O2 cathode materials by using Ti4O7 as a conductive additive. J Energy Storage 28:101182. https://doi.org/10.1016/j.est.2019.10118210.1016/j.est.2019.101182 ↗
7. Liu J, Zou Z, Zhang S, Zhang H (2021) Structure, modification, and commercialization of high nickel ternary material (LiNi0.8Co0.1Mn0.1O2 and LiNi0.8Co0.15Al0.05O2) for lithium ion batteries. J Solid State Electrochem 25:387–410. https://doi.org/10.1007/s10008-020-04818-510.1007/s10008-020-04818-5 ↗
8. Zhang X, Li S, Wang S et al (2021) An amorphous hierarchical MnO2/acetylene black composite with boosted rate performance as an anode for lithium-ion batteries. Dalton Trans 50:10749–10757. https://doi.org/10.15223/policy-02910.15223/policy-029 ↗
9. Yang X, Wu L, Hou J et al (2022) Symmetrical growth of carbon nanotube arrays on FeSiAl micro-flake for enhancement of lithium-ion battery capacity. Carbon 189:93–103. https://doi.org/10.1007/s42823-022-00449-010.1007/s42823-022-00449-0 ↗
10. Zhang H, Zhang J (2021) An overview of modification strategies to improve LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode performance for automotive lithium-ion batteries. ETransportation 7:100105. https://doi.org/10.1016/j.etran.2021.10010510.1016/j.etran.2021.100105 ↗
11. Wang F, Lin S, Lu X et al (2022) Poly-dopamine carbon-coated stable silicon/graphene/CNT com-posite as anode for lithium ion batteries. Electrochim Acta 404:139708. https://doi.org/10.1016/j.electacta.2021.13970810.1016/j.electacta.2021.139708 ↗
12. Li L, Zhang D, Deng J et al (2021) Carbon-based materials for fast charging lithium-ion batteries. Carbon 183:721–734. https://doi.org/10.1016/j.carbon.2021.07.05310.1016/j.carbon.2021.07.053 ↗
13. Guo J, Ma G, Hu K et al (2022) Effect of acetylene black and carbon nanotube interlayer on polyethylene glycol–coated sulfur composite cathode. Ionics 28:619–627. https://doi.org/10.1007/s11581-021-04357-710.1007/s11581-021-04357-7 ↗
14. Jiang X, Chen Y, Meng X et al (2022) The impact of electrode with carbon materials on safety performance of lithium-ion batteries: a review. Carbon 191:448–470. https://doi.org/10.1016/j.carbon.2022.02.01110.1016/j.carbon.2022.02.011 ↗
15. Kang MS, Park SK, Nakhanivej P et al (2021) Mesoporous VO2(B) nanorods deposited onto graphene architectures for enhanced rate capability and cycle life of Li ion battery cathodes. J Alloy Compd 855:157361. https://doi.org/10.1016/j.jallcom.2020.15736110.1016/j.jallcom.2020.157361 ↗
16. Tu S, Su H, Sui D et al (2021) Mesoporous carbon nanomaterials with tunable geometries and porous structures fabricated by a surface-induced assembly strategy. Energy Storage Mater 35:602–609. https://doi.org/10.1016/j.ensm.2020.11.04210.1016/j.ensm.2020.11.042 ↗
17. Tu S, Chen Z, Zhang B et al (2022) Realizing high utilization of high-mass-loading sulfur cathode via electrode nanopore regulation. Nano Lett 22:5982–5989. https://doi.org/10.1021/acs.nanolett.2c0225810.1021/acs.nanolett.2c02258 ↗
18. Li J, Liu Z, Wang Y, Wang R (2020) Investigation of facial B2O3 surface modification effect on the cycling stability and high-rate capacity of LiNi1/3Co1/3Mn1/3O2 cathode. J Alloy Compd 834:155150. https://doi.org/10.1016/j.jallcom.2020.15515010.1016/j.jallcom.2020.155150 ↗
19. Ma L, Yu L-J, Liu J et al (2022) Construction of Ti4O7/TiN/carbon microdisk sulfur host with strong polar N-Ti–O bond for ultralong life lithium–sulfur battery. Energy Storage Mater 44:180–189. https://doi.org/10.1016/j.ensm.2021.09.02410.1016/j.ensm.2021.09.024 ↗
20. Kumar A, Barbhuiya NH, Singh SP (2022) Magnéli phase titanium sub-oxides synthesis, fabrication and its application for environmental remediation: Current status and prospect. Chemosphere 307:135878. https://doi.org/10.1016/j.chemosphere.2022.13587810.1016/j.chemosphere.2022.135878 ↗
21. Liu HJ, Luo MQ, Yang LX et al (2022) A high strength and conductivity bulk Magnéli phase Ti4O7 with superior electrochemical performance. Ceram Int. https://doi.org/10.1016/j.ceramint.2022.05.23310.1016/j.ceramint.2022.05.233 ↗
22. Lee S, Lee G-H, Kim J-C, Kim D-W (2018) Magnéli-Phase Ti4O7 Nanosphere Electrocatalyst Support for Carbon-Free Oxygen Electrodes in Lithium-Oxygen Batteries. ACS Catal 8:2601–2610. https://doi.org/10.1021/acscatal.7b0374110.1021/acscatal.7b03741 ↗
23. Wei W, Yuan T, Ye J (2023) Recent progress in electrochemical application of Magnéli phase Ti4O7-based materials: a review. J Mater Sci 58:14911–14944. https://doi.org/10.1007/s10853-023-08929-y10.1007/s10853-023-08929-y ↗
24. Zhang W, Gui S, Li W et al (2022) Functionally gradient silicon/graphite composite electrodes enabling stable cycling and high capacity for lithium-ion batteries. ACS Appl Mater Interfaces 14:51954–51964. https://doi.org/10.1021/acsami.2c1535510.1021/acsami.2c15355 ↗
25. Kim M, Choi J, Lee W et al (2023) Performance of Magnéli phase Ti4O7 and Ti3+ self-doped TiO2 as oxygen vacancy-rich titanium oxide anodes: comparison in terms of treatment efficiency, anodic degradative pathways, and long-term stability. Appl Catal B 337:122993. https://doi.org/10.1016/j.apcatb.2023.12299310.1016/j.apcatb.2023.122993 ↗
26. Wang G, Liu Y, He W, Ye J (2023) Conduction and sintering mechanism of high electrical conductivity Magnéli phase Ti4O7. Ceram Int 49:27117–27125. https://doi.org/10.1016/j.ceramint.2023.05.25610.1016/j.ceramint.2023.05.256 ↗
27. Aghil S, Lam LYF, Chen G, Hu X (2023) Magneli Ti4O7 nanotube arrays as a free-standing efficient interlayer for fast-delivery and high-energy density lithium-sulfur batteries. J Alloys Comp 960:170874. https://doi.org/10.1016/j.jallcom.2023.17087410.1016/j.jallcom.2023.170874 ↗
28. Cao X, Wei C, Zheng X et al (2022) Ru clusters anchored on Magnéli phase Ti4O7 nanofibers enables flexible and highly efficient Li–O2 batteries. Energy Storage Mater 50:355–364. https://doi.org/10.1016/j.ensm.2022.05.02810.1016/j.ensm.2022.05.028 ↗
29. Ju X, Hou X, Liu Z et al (2023) Revealing the effect of high Ni content in Li-rich cathode materials: mitigating voltage decay or increasing intrinsic reactivity. Small 19:2207328. https://doi.org/10.1002/smll.20220732810.1002/smll.202207328 ↗
30. Yamada H, Yoshii K, Asahi M et al (2022) Cyclic voltammetry part 1: fundamentals. Electrochemistry 90:102005–102005. https://doi.org/10.5796/electrochemistry.22-6608210.5796/electrochemistry.22-66082 ↗
31. Zhang B, Zhu H, Ren Y et al (2023) An Innovative insight into performance degradation of NCM111 cathode induced by suspension of operation. ACS Appl Mater Interfaces 15:6612–6620. https://doi.org/10.1021/acsami.2c1741910.1021/acsami.2c17419 ↗
32. Tanaka Y, Kawase T, Matsuda K et al (2024) Electrode potential effect on the structures, properties, and formation process of SEI Film in lithium-ion batteries: red moon analysis. J Phys Chem C 128:13529–13538. https://doi.org/10.1021/acs.jpcc.4c0009910.1021/acs.jpcc.4c00099 ↗
33. Jha V, Krishnamurthy B (2022) Modeling the SEI layer formation and its growth in lithium-ion batteries (LiB) during charge–discharge cycling. Ionics 28:3661–3670. https://doi.org/10.1007/s11581-022-04617-010.1007/s11581-022-04617-0 ↗
34. Källquist I, Lindgren F, Lee M-T et al (2021) Probing electrochemical potential differences over the solid/liquid interface in Li-ion battery model systems. ACS Appl Mater Interfaces 13:32989–32996. https://doi.org/10.1021/acsami.1c0742410.1021/acsami.1c07424 ↗