journal article·2022-04

Insights on boron impact on structural characteristics in epitaxially grown BGaN

Ewelina B. Możdżyńska, Sebastian Złotnik, Paweł Ciepielewski, Jarosław Gaca, Marek Wójcik, Paweł P. Michałowski, Krzysztof Rosiński, Karolina Piętak, Mariusz Rudziński, Elżbieta Jezierska, Jacek M. Baranowski

Journal of Materials Science· Volume 57· Issue 14
Publisher page

Abstract

It is shown that MOCVD growth allows to obtain BGaN epitaxial layers at growth temperature (Tgr) between 840 and 1090 °C. It is found that morphology of the epitaxial layers and amount of B replacing Ga strongly dependent on growth temperature. The SIMS determined that the total amount of B was constant for all growth temperatures. On the other hand, the X-ray measurements shown that amount of boron incorporated into gallium sites decreased from 2.5 to 0.73%, for Tgr changed from 840 to 1090 °C, respectively. That indicated that increase of growth temperature leads to transfer of B atoms from Ga substitutional sites to the interstitial positions. It was also shown that the c(x) lattice parameter for ternary BGaN alloys is well described by the standard interpolation formula. On the other hand, energy shifts observed in photoluminescence suggest that the layers are under dilatation strain.
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Research context

OpenAlex topics: GaN-based semiconductor devices and materials · Metal and Thin Film Mechanics · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. Nakamura S, Pearton S, Fasol G (2000) The blue laser diode. Springer, Berlin10.1007/978-3-662-04156-7 ↗
2. Ougazzaden A, Gautier S, Moudakir T et al (2008) Bandgap bowing in BGaN thin films. Appl Phys Lett 93:083118. https://doi.org/10.1063/1.297758810.1063/1.2977588 ↗
3. Park SH, Ahn D (2017) Dip-shaped AlGaN/AlN light-emitting diodes with delta-layer containing boron. IEEE Photonics Technol Lett 29:1042–1045. https://doi.org/10.1109/LPT.2017.270261010.1109/LPT.2017.2702610 ↗
4. Lymperakis L (2018) Ab-initio study of boron incorporation and compositional limits at GaN and AlN (0001) surfaces. AIP Adv 8:65301. https://doi.org/10.1063/1.502933910.1063/1.5029339 ↗
5. Shen J-X, Turiansky ME, Wickramaratne D, Van de Walle CG (2021) Thermodynamics of boron incorporation in BGaN. Phys Rev Mater 5:L030401. https://doi.org/10.1103/physrevmaterials.5.l03040110.1103/physrevmaterials.5.l030401 ↗
6. Kurimoto M, Takano T, Yamamoto J et al (2000) Growth of BGaN/AlGaN multi-quantum-well structure by metalorganic vapor phase epitaxy. J Cryst Growth 221:378–381. https://doi.org/10.1016/S0022-0248(00)00717-X10.1016/S0022-0248(00)00717-X ↗
7. Honda T, Kurimoto M, Shibata M, Kawanishi H (2000) Excitonic emission of BGaN grown on (0001) 6H–SiC by metal-organic vapor-phase epitaxy. J Lumin 87–89:1274–1276. https://doi.org/10.1016/S0022-2313(99)00565-710.1016/S0022-2313(99)00565-7 ↗
8. Honda T, Shibata M, Kurimoto M et al (2000) Band-gap energy and effective mass of BGaN. Jpn J Appl Phys Part 1 39:2389–2393. https://doi.org/10.1143/jjap.39.238910.1143/jjap.39.2389 ↗
9. Baghdadli T, Hamady SOS, Gautier S et al (2009) Electrical and structural characterizations of BGaN thin films grown by metal-organic vapor-phase epitaxy. Phys Status Solidi 6:S1029–S1032. https://doi.org/10.1002/pssc.20088089610.1002/pssc.200880896 ↗
10. Polyakov AY, Shin M, Skowronski M et al (1997) Growth of GaBN ternary solutions by organometallic vapor phase epitaxy. J Electron Mater 26:237–242. https://doi.org/10.1007/s11664-997-0157-x10.1007/s11664-997-0157-x ↗
11. Ebara K, Mochizuki K, Inoue Y et al (2019) Impact of growth temperature on the structural properties of BGaN films grown by metal-organic vapor phase epitaxy using trimethylboron. Jpn J Appl Phys 58:SC1042. https://doi.org/10.7567/1347-4065/ab139510.7567/1347-4065/ab1395 ↗
12. Kadys A, Mickevičius J, Malinauskas T et al (2015) Optical and structural properties of BGaN layers grown on different substrates. J Phys D Appl Phys 48:465307. https://doi.org/10.1088/0022-3727/48/46/46530710.1088/0022-3727/48/46/465307 ↗
13. Williamson TL, Weisse-Bernstein NR, Hoffbauer MA (2014) Growth of ternary wurtzite BAlN and BGaN by ENABLE-MBE. Phys Status Solidi Curr Top Solid State Phys 11:462–465. https://doi.org/10.1002/pssc.20130074110.1002/pssc.201300741 ↗
14. Gupta VK, Wamsley CC, Koch MW, Wicks GW (1999) Molecular beam epitaxy growth of boron-containing nitrides. J Vac Sci Technol B Microelectron Nanom Struct Process Meas Phenom 17:1246–1248. https://doi.org/10.1116/1.59073110.1116/1.590731 ↗
15. Wei CH, Xie ZY, Edgar JH et al (2000) MOCVD growth of GaBN on 6H-SiC (0001) substrates. J Electron Mater 29:452–456. https://doi.org/10.1007/s11664-000-0160-y10.1007/s11664-000-0160-y ↗
16. Mickevicius J, Andrulevicius M, Ligor O et al (2019) Type-II band alignment of low-boron- content BGaN/GaN heterostructures. J Phys D: Appl Phys 52:325105. https://doi.org/10.1088/1361-6463/ab233710.1088/1361-6463/ab2337 ↗
17. Vezin V, Yatagai S, Shiraki H, Satoshi U (1997) Growth of Ga1-xBxN by Molecular Beam Epitaxy. Jpn J Appl Phys 36:L1483–L1485. https://doi.org/10.1143/JJAP.36.L148310.1143/JJAP.36.L1483 ↗
18. Harrison WA (2004) Elementary electronic structure, Revised. World Scientific, Singapore10.1142/5432 ↗
19. Teles LK, Scolfaro LMR, Leite JR et al (2002) Spinodal decomposition in BxGa1-xN and BxAl1-xN alloys. Appl Phys Lett 80:1177–1179. https://doi.org/10.1063/1.145026110.1063/1.1450261 ↗
20. Malinauskas T, Kadys A, Stanionyte S et al (2015) Growth of BGaN epitaxial layers using close-coupled showerhead MOCVD. Phys Status Solidi Basic Res 252:1138–1141. https://doi.org/10.1002/pssb.20145156010.1002/pssb.201451560 ↗
21. Teles LK, Furthmüller J, Scolfaro LMR et al (2002) Phase separation and gap bowing in zinc-blende InGaN, InAlN, BGaN, and BAlN alloy layers. Phys E Low-Dimens Syst Nanostruct 13:1086–1089. https://doi.org/10.1016/S1386-9477(02)00309-010.1016/S1386-9477(02)00309-0 ↗
22. Orsal G, Maloufi N, Gautier S et al (2008) Effect of boron incorporation on growth behavior of BGaN/GaN by MOVPE. J Cryst Growth 310:5058–5062. https://doi.org/10.1016/j.jcrysgro.2008.08.02410.1016/j.jcrysgro.2008.08.024 ↗
23. Gunning BP, Moseley MW, Koleske DD et al (2017) Phase degradation in BxGa1−xN films grown at low temperature by metalorganic vapor phase epitaxy. J Cryst Growth 464:190–196. https://doi.org/10.1016/j.jcrysgro.2016.10.05410.1016/j.jcrysgro.2016.10.054 ↗
24. Jurkevičius J, Mickevičius J, Kadys A et al (2016) Photoluminescence efficiency of BGaN epitaxial layers with high boron content. Phys B Condens Matter 492:23–26. https://doi.org/10.1016/j.physb.2016.03.03310.1016/j.physb.2016.03.033 ↗
25. Gautier S, Patriarche G, Moudakir T et al (2011) Deep structural analysis of novel BGaN material layers grown by MOVPE. J Cryst Growth 315:288–291. https://doi.org/10.1016/j.jcrysgro.2010.08.04210.1016/j.jcrysgro.2010.08.042 ↗
26. Ueyama K, Mimura H, Inoue Y et al (2016) Effect of substrate offcut angle on BGaN epitaxial growth. Jpn J Appl Phys 55:05FD05. https://doi.org/10.7567/JJAP.55.05FD0510.7567/JJAP.55.05FD05 ↗
27. Gautier S, Abid M, Moudakir T et al (2011) Application of dilute boron B(Al,In,Ga)N alloys for UV light sources. In: Proceedings of SPIE, Oxide-based Materials and Devices II, vol 7940, p 79400X. https://doi.org/10.1117/12.88452410.1117/12.884524 ↗
28. Ougazzaden A, Gautier S, Sartel C et al (2007) BGaN materials on GaN/sapphire substrate by MOVPE using N2 carrier gas. J Cryst Growth 298:316–319. https://doi.org/10.1016/j.jcrysgro.2006.10.07210.1016/j.jcrysgro.2006.10.072 ↗
29. Zdanowicz E, Iida D, Pawlaczyk L et al (2020) Boron influence on bandgap and photoluminescence in BGaN grown on AlN. J App Phys 127:165703. https://doi.org/10.1063/1.514041310.1063/1.5140413 ↗
30. Durbin SM, Follis GC (1995) Darwin theory of heterostructure diffraction. Phys Rev B Condens Matter 51:10127–10133. https://doi.org/10.1103/physrevb.51.1012710.1103/physrevb.51.10127 ↗
31. Gaca J, Wójcik M, Jasik A et al (2008) Effects of composition grading at heterointefaces and layer thickness variations on Bragg mirror quality. Opto-Electron Rev 16:12–17. https://doi.org/10.2478/s11772-007-0023-710.2478/s11772-007-0023-7 ↗
32. Gaca J, Wójcik M, Bugajski M, Kosiel K (2011) The determination of the chemical composition profile of the GaAs/AlGaAs heterostructures designed for quantum cascade lasers by means of synchrotron radiation. Radiat Phys Chem 80:1112–1118. https://doi.org/10.1016/j.radphyschem.2011.03.00710.1016/j.radphyschem.2011.03.007 ↗
33. Cramer RC, Bonef B, English J et al (2017) Growth of coherent BGaN films using BBr 3 gas as a boron source in plasma assisted molecular beam epitaxy. J Vac Sci Technol A 35:041509. https://doi.org/10.1116/1.498618510.1116/1.4986185 ↗
34. Bonef B, Cramer R, Speck JS (2017) Nanometer scale composition study of MBE grown BGaN performed by atom probe tomography. J Appl Phys 121:225701. https://doi.org/10.1063/1.498408710.1063/1.4984087 ↗
35. Davydov YV, Goncharuk IN, Smirnov AN et al (2002) Composition dependence of optical phonon energies and Raman line broadening in hexagonal (formula presented) alloys. Phys Rev B 65:125203. https://doi.org/10.1103/PhysRevB.65.12520310.1103/PhysRevB.65.125203 ↗
36. Azuhata T, Sota T, Suzuki K, Nakamura S (1995) Polarized Raman spectra in GaN. J Phys Condens Matter 7:L129–L133. https://doi.org/10.1088/0953-8984/7/10/00210.1088/0953-8984/7/10/002 ↗
37. Cuscó R, Alarcón-Lladó E, Ibáñez J et al (2008) Phonons in BxGa1-xN/GaN epilayers studied by means of UV Raman scattering. Phys Status Solidi B 245:731–734. https://doi.org/10.1002/pssb.20074339810.1002/pssb.200743398 ↗
38. Abstreiter G, Bauser E, Fischer A, Ploog K (1978) Raman spectroscopy-A versatile tool for characterization of thin films and heterostructures of GaAs and AlxGa1−xAs. Appl Phys 16:345–352. https://doi.org/10.1007/BF0088585810.1007/BF00885858 ↗
39. Leszczynski M, Suski T, Perlin P, Teisseyre H, Grzegory I, Bockowski M, Jun J, Porowski S, Major J (1995) Lattice constants, thermal expansion and compressibility of gallium nitride. J Phys D 28:A14910.1088/0022-3727/28/4A/029 ↗
40. Kim C, Robinson IK, Myoung J, Shim K, Yoo M-C, Kim K (1996) Critical thickness of GaN thin films on sapphire (0001). Appl Phys Lett 69:235810.1063/1.117524 ↗
41. Heying B, Wu XH, Keller S, Li Y, Kapolnek D, Keller BP, DenBaars SP, Speck JS (1996) Role of threading dislocation structure on the x‐ray diffraction peak widths in epitaxial GaN films. Appl Phys Lett 68:64310.1063/1.116495 ↗
42. Kudrawiec R, Hommel D (2020) Bandgap engineering in III-nitrides with boron and group v elements: toward applications in ultraviolet emitters. Appl Phys Rev 7:041314. https://doi.org/10.1063/5.002537110.1063/5.0025371 ↗
43. Zhang M, Li X (2017) Structural and electronic properties of wurtzite BxAl1–xN from first-principles calculations. Phys Status Solidi B 254:1600749. https://doi.org/10.1002/pssb.20160074910.1002/pssb.201600749 ↗
44. Alemu A, Gil B, Julier M, Nakamura S (1998) Optical properties of wurtzite GaN epilayers grown on A-plane sapphire. Phys Rev B 57:3761–3764. https://doi.org/10.1103/PhysRevB.57.376110.1103/PhysRevB.57.3761 ↗
45. Chichibu S, Azuhata T, Sota T et al (1997) Optical properties of tensile-strained wurtzite GaN epitaxial layers. Appl Phys Lett 70:2085–2087. https://doi.org/10.1063/1.11895810.1063/1.118958 ↗
46. Baranowski JM (1984) Bond lengths, force constants and local impurity distortions in semiconductors. J Phys C Solid State Phys 17:6287–6301. https://doi.org/10.1088/0022-3719/17/35/00510.1088/0022-3719/17/35/005 ↗