Two barbituric acid–polyoxometalate hybrids with morphology-tunable supramolecular self-assemblies for the degradation of organic dyes
Source abstract
Abstract
Supramolecular hybrid materials based on polyoxometalates (POMs) have attracted intense attention, due to their wide range of unique properties and potential applications. However, the relationships between supramolecular structures and influencing factors are challenging to determine. To provide a deeper understanding, this work discusses how molecular structures and solution components affect the self-assembly process of two barbituric acid–POM hybrids. We have designed and synthesized two barbituric acid–POM hybrids with similar molecular structures. The morphologies of the hybrids in the supramolecular self-assembly were closely investigated under various solvent conditions. The correlation between supramolecular structures and molecular structures and solution components was examined. The barbituric acid–POM hybrids, prepared in methanol/chloroform mixed solution at a volume ratio of 1:3, could be potentially used as effective catalysts for the degradation of organic dyes. This study provides a protocol for preparing supramolecular hybrid materials with controlled supramolecular structures or peculiar properties.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polyoxometalates: Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications · Chemical Synthesis and Reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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