journal article·2021-05

Coaxial MWNTs@MnCo2O4 wrapped in conducting graphene for enhanced lithium ion storage

Lan Chen, Yongcong Huang, Yulu Chen, Liqing Zheng, Yi Zhao, Yan Chen, Guiying Zhao, Jiaxin Li, Yingbin Lin, Zhigao Huang

Journal of Materials Science· Volume 56· Issue 15
Publisher page

Abstract

In this report, nanocomposites of MWNTs@MnCo2O4@Gs are synthesized via a wet-chemical approach, in which double layer of MnCo2O4 particles evenly attached on MWNTs and wrapped in graphene. As an anode material for lithium batteries (LIBs), the designed MWNTs@MnCo2O4@Gs delivers LIB performance with superior rate capability and a large reversible capacity of 1094 mAh g−1 after 300 cycles tested at 200 mA g−1, respectively. The MWNTs@MnCo2O4@Gs electrodes deliver reversible capacities of 752 and 520 mAh g−1 after 80 cycles at high current densities of 1.0 and 3.0 A g−1, being much larger than those values of 155 and 125 mAh g−1 without Gs wrapping. The results revealed that the reserved space structure combined with conductive carbon supporting of MWNTs and Gs can effectively provide buffer for the volume expansion of Li+ insertion/extraction process, promote the ion/electron transport, and finally improve their LIB performance. Thus, such structure design supplied a promising route to obtain binary metal oxide-based anode in order to achieve high-performance LIBs.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

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