journal article·2015-06

Fluorinated liquid crystalline surfactants for dispersion and alignment of carbon nanotubes

Pengcheng Lin, Yuehua Cong, Baoyan Zhang

Journal of Materials Science· Volume 50· Issue 12
Publisher page

Abstract

An effective and promising approach for dispersion and alignment of carbon nanotubes (CNTs) with the help of fluorinated liquid crystalline surfactants (FLCSs), which possess excellent affinity with CNTs and liquid crystals (LCs), is presented here. A binary mode is designed to express the dispersion of CNTs with CNTs joining the nematic matrix of FLCSs. Ultraviolet–visible spectrum and fourier transform infrared (FTIR) spectrum are recorded to figure out the concentration of effectively dispersed CNTs by FLCSs, the concentration in chloroform reaches a maximum 1.481 mg mL−1. The miscibility between FLCSs and CNTs is analyzed by FTIR imaging system with P7 giving rise to the best miscibility. The homogeneously dispersed CNTs decrease the glass transition temperature of FLCSs by increasing the degree of freedom of the segment on FLCS to move, and enhance the thermal stability of FLCSs by increasing the decomposition temperature and the activation energy for thermal decomposition. The optical textures show that P7 increases the compatibility between LC host and CNTs. The chiral stability and electro-optical property of LC host are both optimized by CNT doping.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Fullerene Chemistry and Applications · Nanotechnology research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

Show source-provided references
1. Bachilo SM, Strano MS, Kittrell C, Hauge RH, Smalley RE, Weisman RB (2002) Structure-assigned optical spectra of single-walled carbon nanotubes. Science 298:2361–236610.1126/science.1078727 ↗
2. Osman MA, Srivastava D (2001) Temperature dependence of the thermal conductivity of single-wall carbon nanotubes. Nanotechnology 12:21–2410.1088/0957-4484/12/1/305 ↗
3. Ebbesen TW, Lezec HJ, Hiura H, Bennett JW, Ghaemi HF, Thio T (1996) Electrical conductivity of individual carbon nanotubes. Nature 382:54–5610.1038/382054a0 ↗
4. Sun D, Everett WN, Chu CC, Sue HJ (2009) Single-walled carbon-nanotube dispersion with electrostatically tethered nanoplatelets. Small 5:2692–269710.1002/smll.200900531 ↗
5. Qian D, Wagner GJ, Liu WK (2002) Mechanics of carbon nanotubes. Appl Mech Rev 55:495–53310.1115/1.1490129 ↗
6. Kulkarni MV, Kale BB (2013) Studies of conducting polyaniline (PANI) wrapped-multiwalled carbon nanotubes (MWCNTs) nanocomposite and its application for optical pH sensing. Sens Actuator B 187:407–41210.1016/j.snb.2012.12.106 ↗
7. Khudyakov DV, Lobach AS, Nadtochenko VA (2009) Nonlinear optical absorption of single-wall carbon nanotubes in carboxymethylcellulose thin polymerfilm and its application as a saturable absorber for mode-locking in pulsed Nd: glass laser. Appl Optics 48:1624–162710.1364/AO.48.001624 ↗
8. Li TX, Lee JH, Wang RZ, Kang YT (2013) Enhancement of heat transfer for thermal energy storage application using stearic acid nanocomposite with multi-walled carbon nanotubes. Energy 55:752–76110.1016/j.energy.2013.04.010 ↗
9. Chang HY, Chang HC, Lee KY (2013) Characteristics of NiO coating on carbon nanotubes for electric double layer capacitor application. Vacuum 87:164–16810.1016/j.vacuum.2012.04.027 ↗
10. Khavrus VO, Weiser M, Fritsch M, Ummethala R, Salvaggio MG, Schneider M, Kusnezoff M, Leonhardt A (2012) Application of carbon nanotubes directly grown on aluminum foils as electric double layer capacitor electrodes. Chem Vapor Depos 18:53–6010.1002/cvde.201106942 ↗
11. Coleman JN, Khan U, Gun’ko YK (2006) Mechanical reinforcement of polymers using carbon nanotubes. Adv Mater 18:689–70610.1002/adma.200501851 ↗
12. Coleman JN, Khan U, Blau WJ, Gun’ko YK (2006) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44:1624–165210.1016/j.carbon.2006.02.038 ↗
13. Gupta A, Choudhary V (2013) Thermal and mechanical properties of poly (trimethyelene terephthalate)/acid-treated multiwalled carbon nanotube composites. J Mater Sci 48:7063–7070. doi: 10.1007/s10853-013-7517-010.1007/s10853-013-7517-0 ↗
14. Abbasov ME, Ghosh S, Quach A, Carlisle GO (2010) Hybrid carbon nanotube and dye-doped liquid crystal material for holographic imaging. J Mater Sci Mater Electron 21(8):854–85910.1007/s10854-009-0007-0 ↗
15. Kis A, Csanyi G, Salvetat JP, Lee TN, Couteau E, Kulik AJ, Benoit W, Brugger J, Forro L (2004) Reinforcement of single-walled carbon nanotube bundles by intertube bridging. Nat Mater 3(3):153–15710.1038/nmat1076 ↗
16. Datsyuk V, Landois P, Fitremann J, Peigney A, Galibert AM, Soula B, Flahaut E (2009) Double-walled carbon nanotube dispersion via surfactant substitution. J Mater Chem 19(18):2729–273610.1039/b814122n ↗
17. Wang S, Liang R, Wang B, Zhang C (2009) Dispersion and thermal conductivity of carbon nanotube composites. Carbon 47(1):53–5710.1016/j.carbon.2008.08.024 ↗
18. Li Q, Zaiser M, Koutsos V (2004) Carbon nanotube/epoxy resin composites using a block copolymer as a dispersing agent. Phys Status Solidi A (a) 201(13):R89–R9110.1002/pssa.200409065 ↗
19. Ogihara H, Xie J, Saji T (2014) Spraying carbon nanotube dispersions to prepare superhydrophobic films. J Mater Sci 49:3183–3188. doi: 10.1007/s10853-014-8021-x10.1007/s10853-014-8021-x ↗
20. Zhao Y, Barrera EV (2010) Asymmmetric diamino functionalization of nanotubes assisted by BOC protection and their epoxy nanocomposites. Adv Funct Mater 20:3039–304410.1002/adfm.201000942 ↗
21. Cheng Q, Bao J, Park JG, Liang ZY, Zhang C, Wang B (2009) High mechanical performance composite conductor: multi-walled carbon nanotube sheet/bismaleimide nanocomposites. Adv Funct Mater 19:3219–322510.1002/adfm.200900663 ↗
22. Ajayan PM, Suhr JW, Koratkar N (2006) Utilizing interfaces in carbon nanotube reinforced polymer composites for structural damping. J Mater Sci 41:7824–7829. doi: 10.1007/s10853-006-0693-410.1007/s10853-006-0693-4 ↗
23. Zhang K, Lim JY, Choi HJ, Lee JH, Choi WJ (2013) Ultrasonically prepared polystyrene/multi-walled carbon nanotube nanocomposites. J Mater Sci 48:3088–3096. doi: 10.1007/s10853-012-7083-x10.1007/s10853-012-7083-x ↗
24. Kim S, Lee JW, Hong IK, Lee S (2014) Electrical conductivity enhancement of polycarbonate/poly (styrene-co-acrylonitril)/carbon nanotube composites by high intensity ultrasound. Macromol Res 22(2):154–15910.1007/s13233-014-2029-6 ↗
25. Isayev AI, Kumar R, Lewis TM (2009) Ultrasound assisted twin screw extrusion of polymer-nanocomposites containing carbon nanotubes. Polymer 50(1):250–26010.1016/j.polymer.2008.10.052 ↗
26. Yu H, Hermann S, Schulz SE, Gessner T, Dong Z, Li WJ (2012) Optimizing sonication parameters for dispersion of single-walled carbon nanotubes. Chem Phys 408:11–1610.1016/j.chemphys.2012.08.020 ↗
27. Park JH, Alegaonkar PS, Jeon SY, Yoo JB (2008) Carbon nanotube composite: dispersion routes and field emission parameters. Compos Sci Technol 68(3):753–75910.1016/j.compscitech.2007.08.030 ↗
28. Andrews R, Jacques D, Minot M, Rantell T (2002) Fabrication of carbon multiwall nanotube/polymer composites by shear mixing. Macromol Mater Eng 287(6):395–40310.1002/1439-2054(20020601)287:6<395::AID-MAME395>3.0.CO;2-S ↗
29. Mirjalili V, Yourdkhani M, Hubert P (2012) Dispersion stability in carbon nanotube modified polymers and its effect on the fracture toughness. Nanotechnology 23(31):31570110.1088/0957-4484/23/31/315701 ↗
30. Mun SC, Kim M, Prakashan K, Jung HJ, Son YG, Park OO (2014) A new approach to determine rheological of carbon nanotubes in microstructured polymer matrices. Carbon 67:64–7110.1016/j.carbon.2013.09.056 ↗
31. Lee GW, Jagannathan S, Chae HG, Minus ML, Kumar S (2008) Carbon nanotube dispersion and exfoliation in polypropylene and structure and properties of the resulting composites. Polymer 49(7):1831–184010.1016/j.polymer.2008.02.029 ↗
32. Fornes TD, Baur JW, Sabba Y, Thomas EL (2006) Morphology and properties of melt-spun polycarbonate fibers containing single-and multi-wall carbon nanotubes. Polymer 47(5):1704–171410.1016/j.polymer.2006.01.003 ↗
33. Han MS, Lee YK, Kim WN, Lee HS, Joo JS, Park M, Lee HJ, Park CR (2009) Effect of multi-walled carbon nanotube dispersion on the electrical, morphological and rheological properties of polycarbonate/multi-walled carbon nanotube composites. Macromol Res 17(11):863–86910.1007/BF03218627 ↗
34. Bisoyi HK, Kumar S (2011) Liquid-crystal nanoscience: an emerging avenue of soft self-assembly. Chem Soc Rev 40(1):306–31910.1039/B901793N ↗
35. Basu R, Iannacchione GS (2010) Orientational coupling enhancement in a carbon nanotube dispersed liquid crystal. Phys Rev E 81:05170510.1103/PhysRevE.81.051705 ↗
36. Qi H, Hegmann T (2008) Impact of nanoscale particles and carbon nanotubes on current and future generations of liquid crystal displays. J Mater Chem 18(28):3288–329410.1039/b718920f ↗
37. Malik P, Chaudhary A, Mehra R, Raina KK (2012) Electro-optic, thermo-optic and dielectric responses of multiwalled carbon nanotube doped ferroelectric liquid crystal thin films. J Mol Liq 165:7–1110.1016/j.molliq.2011.09.016 ↗
38. Basu R, Iannacchione GS (2009) Nematic anchoring on carbon nanotubes. Appl Phys Lett 95:17311310.1063/1.3256013 ↗
39. Lin CH (1971) Nitro-and amino-substituted fluorans. US Patent 3624107
40. Wang Y (2005) Synthesis and properties of thermochromic dyes and liquid crystalline polymers. PhD Dissertation, Northeastern University
41. Zhang BY, Meng FB, Cong YH (2007) Optical characterization of polymer liquid crystal cell exhibiting polymer blue phases. Opt Express 15:10175–1018110.1364/OE.15.010175 ↗
42. Lu SX, Melo MM, Zhao JQ, Pearce EM, Kwei TK (1995) Organic-inorganic polymeric hybrids involving novel poly (hydroxymethylsiloxane). Macromolecules 28:4908–491310.1021/ma00118a018 ↗
43. Finkelmann H, Rehage G (1984) Liquid crystal side chain polymers. Springer, Heidelberg, pp 152–153
44. Goh PS, Ng BC, Ismail AF, Aziz M (2010) Surfactant dispersed multi-walled carbon nanotube/polyetherimide nanocomposite membrane. Solid State Sci 12:2155–216210.1016/j.solidstatesciences.2010.09.017 ↗
45. Horowitz HH, Metzger G (1963) A new analysis of thermogravimetric traces. Anal Chem 35:1464–146810.1021/ac60203a013 ↗
46. Matsui T, Ozaki M, Yoshino K (2004) Tunable photonic defect modes in a cholesteric liquid crystal induced by optical deformation of helix. Phys Rev E 69(6):061715–061715-410.1103/PhysRevE.69.061715 ↗
47. Lu SY, Chien LC (2007) A polymer-stabilized single-layer color cholesteric liquid crystal display with anisotropic reflection. Appl Phys Lett 91(13):131119–131119-310.1063/1.2790499 ↗
48. Matsui T, Ozaki R, Funamoto K, Ozaki M, Yoshino K (2002) Flexible mirrorless laser based on a free-standing film of photopolymerized cholesteric liquid crystal. Appl Phys Lett 81(20):3741–374310.1063/1.1522498 ↗
49. Meiboom S, Sammon M (1980) Structure of the blue phase of a cholesteric liquid crystal. Phys Rev Lett 44(13):882–88510.1103/PhysRevLett.44.882 ↗
50. Hong Q, Wu TX, Wu ST (2003) Optical wave propagation in a cholesteric liquid crystal using the finite element method. Liq Cryst 30(3):367–37510.1080/0267829031000083777 ↗
51. Blinov LM, Palto SP (2009) Cholesteric helix: topological problem, photonics and electro-optics. Liq Cryst 36:1037–104710.1080/02678290902761356 ↗
52. Ji Y, Huang YY, Rungsawang R, Terentjev EM (2010) Dispersion and alignment of carbon nanotubes in liquid crystalline polymers and elastomers. Adv Mater 22:3436–344010.1002/adma.200904103 ↗