The equilibrium orientation relationship between Pt and SrTiO3 and its implication on Pt films deposited by physical vapor phase deposition
Source abstract
Abstract
The equilibrium orientation of Pt in contact with (100)-SrTiO3, at 1050 °C and in an Ar/2 % O2 environment, was determined by solid-state dewetting of continuous Pt films on single crystal SrTiO3 substrates. Given the similar lattice parameters between Pt and SrTiO3, a simple cube-on-cube orientation relationship was expected to form at equilibrium. However, only a preferred orientation of Pt {111} parallel to the SrTiO3 (100) surface formed, without a low-index orientation relationship. It was found that reconstruction of the SrTiO3 surface (a complexion) was responsible for the Pt particle texture. The equilibrium crystal shape of the Pt particles was analyzed and it was found to contain the following facets: {111}, {100}, {110}, and {113}.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electronic and Structural Properties of Oxides · Semiconductor materials and devices · Ferroelectric and Piezoelectric Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (59)
Show source-provided references
1. Yasuda K, Masui T, Miyamoto T, Imanaka N (2011) Catalytic combustion of methane over Pt and PdO-supported CeO2–ZrO2–Bi2O3/γ–Al2O3 catalysts. J Mater Sci 46:4046. doi: 10.1007/s10853-011-5333-y10.1007/s10853-011-5333-y ↗
2. Topalidis A, Petrakis DE, Ladavos A, Loukatzikou L, Pomonis PJ (2007) A kinetic study of methane and carbon dioxide interconversion over 0.5 % Pt/SrTiO3 catalysts. Catal Today 127:238. doi: 10.1016/j.cattod.2007.04.01510.1016/j.cattod.2007.04.015 ↗
3. Liu H, Song C, Zhang L, Zhang J, Wang H, Wilkinson DP (2006) A review of anode catalysis in the direct methanol fuel cell. J Power Sources 155:95. doi: 10.1016/j.jpowsour.2006.01.03010.1016/j.jpowsour.2006.01.030 ↗
4. Jiang X, Huang H, Prinz FB, Bent SF (2008) Application of atomic layer deposition of platinum to solid oxide fuel cells. Chem Mater 20:3897. doi: 10.1021/cm703318910.1021/cm7033189 ↗
5. Yoshida H, Yazawa Y, Hattori T (2003) Effects of support and additive on oxidation state and activity of Pt catalyst in propane combustion. Catal Today 87:19. doi: 10.1016/j.cattod.2003.10.00110.1016/j.cattod.2003.10.001 ↗
6. Meixner H, Lampe U (1996) Metal oxide sensors. Sens Actuat B 33:198. doi: 10.1016/0925-4005(96)80098-010.1016/0925-4005(96)80098-0 ↗
7. Meixner H, Gerblinger J, Lampe U, Fleischer M (1995) Thin-film gas sensors based on semiconducting metal oxides. Sens Actuat B 23:119. doi: 10.1016/0925-4005(94)01266-K10.1016/0925-4005(94)01266-K ↗
8. Hren PD, Rou SH, Al-Shareef HN, Ameen MS, Auciello O, Kingon AI (1992) Bottom electrodes for integrated Pb(Zr, Ti)O3 films. Integr Ferroelectr 2:311. doi: 10.1080/1058458920821575110.1080/10584589208215751 ↗
9. Moran O, Hott R, Schneider R, Halbritter J (2003) Transport properties of ultrathin SrTiO3 barriers for high-temperature superconductor electronics applications. J Appl Phys 94:6717. doi: 10.1063/1.162037510.1063/1.1620375 ↗
10. Rodriguez Contreras J, Kohlstedt H, Poppe U, Waser R, Buchal C, Pertsev NA (2003) Resistive switching in metal-ferroelectric-metal junctions. Appl Phys Lett 83:459510.1063/1.1627944 ↗
11. Mikhelashvili V, Shneider Y, Meyler B et al (2012) Non-volatile memory transistor based on Pt nanocrystals with negative differencial resistance. J Appl Phys 112:02431910.1063/1.4739714 ↗
12. Mikhelashvili V, Meyler B, Shneider Y et al (2013) Ultraviolet to near infrared response of optically sensitive nonvolatile memories based on platinum nano-particles and high-k dielectrics on a silicon on insulator substrate. J Appl Phys 113:07450310.1063/1.4791761 ↗
13. Liang YC (2010) Effect of conductive oxide buffering on structural and nanoscale electrical properties of ultrathin SrTiO3 films on Pt electrodes. J Cryst Growth 312:161010.1016/j.jcrysgro.2010.01.021 ↗
14. Kan D, Ito K, Shimakawa Y (2010) Local conduction in junctions composed of Pt and single-crystalline Nb-doped SrTiO3. Thin Solid Films 518:324610.1016/j.tsf.2009.10.165 ↗
15. Cho S-S, Kim H-G (1996) Pt deposition effect for the catalyst of the semiconducting oxygen sensor. IEEE International Symposium on Applications of Ferroelectrics 2: 98310.1109/ISAF.1996.598193 ↗
16. Yan XB, Li K, Yin J et al (2010) The resistive switching mechanism of Ag/SrTiO3/Pt memory cells. Electrochem Solid-State Lett 13:H8710.1149/1.3279689 ↗
17. Sim H, Seong DJ, Chang M, Hwang H (2006) In: 21st IEEE Non-Volatile Semiconductor Memory Workshop 2006, NVSMW 2006. 10.1109/.2006.1629507
18. Francis AJ, Salvador PA (2007) Crystal orientation and surface morphology of face-centered-cubic metal thin films deposited upon single-crystal ceramic substrates using pulsed laser deposition. J Mater Res 22:89. doi: 10.1557/jmr.2007.001410.1557/jmr.2007.0014 ↗
19. Son J, Cagnon J, Stemmer S (2009) Strain relaxation in epitaxial Pt films on (001) SrTiO3. J Appl Phys 106:043525. doi: 10.1063/1.320779510.1063/1.3207795 ↗
20. Chen X, Garrent T, Liu SW et al (2003) Scanning tunnelling microscopy studies of growth morphology in highly epitaxial c-axis oriented Pt thin film on (001) SrTiO3. Surf Sci 542:L655. doi: 10.1016/S0039-6028(03)00954-310.1016/S0039-6028(03)00954-3 ↗
21. Xu XM, Liu J, Yuan Z et al (2008) Single crystalline highly epitaxial Pt thin films on (001) SrTiO3. Appl Phys Lett 92:102102. doi: 10.1063/1.289084410.1063/1.2890844 ↗
22. Goto T, Vargas JR, Hirai T (1999) Effect of oxygen gas addition on preparation of iridium and platinum films by metal-organic chemical vapor deposition. Mater Trans, JIM 40:20910.2320/matertrans1989.40.209 ↗
23. Heifets E, Kotomin EA, Maier J (2000) Semi-empirical simulations of surface relaxation for perovskite titanates. Surf Sci 462:19. doi: 10.1016/S0039-6028(00)00603-810.1016/S0039-6028(00)00603-8 ↗
24. Padilla J, Vanderbilt D (1998) Ab initio study of SrTiO3 surfaces. Surf Sci 418:64. doi: 10.1016/S0039-6028(98)00670-010.1016/S0039-6028(98)00670-0 ↗
25. Johnston K, Castell MR, Paxton AT, Finnis MW (2004) SrTiO3(001)(2 × 1) reconstructions: first-principles calculations of surface energy and atomic structure compared with scanning tunneling microscopy images. Phys Rev B 70:08541510.1103/PhysRevB.70.085415 ↗
26. Iddir H, Komanicky V, Öǧüt S, You H, Zapol P (2007) Shape of platinum nanoparticles supported on SrTiO3: experiment and theory. J Phys Chem C 111:14782. doi: 10.1021/jp073041r10.1021/jp073041r ↗
27. Asthagiri A, Sholl DS (2002) First principles study of Pt adhesion and growth on SrO- and TiO2-terminated SrTiO3(100). J Chem Phys 116:991410.1063/1.1476322 ↗
28. Polli AD, Wagner T, Gemming T, Rühle M (2000) Growth of platinum on TiO2- and SrO-terminated SrTiO3(100). Surf Sci 448:279. doi: 10.1016/S0039-6028(99)01233-910.1016/S0039-6028(99)01233-9 ↗
29. Kawasaki M, Takahashi K, Takahashi K, Maeda T, Tsuchiya R et al (1994) Atomic control of the SrTiO3 crystal surface. Science 266:1540. doi: 10.1126/science.266.5190.154010.1126/science.266.5190.1540 ↗
30. Kawasaki M, Ohtomo A, Arakane T, Takahashi K, Yoshimoto M, Koinuma H (1996) Atomic control of SrTiO3 surface for perfect epitaxy of perovskite oxides. Appl Surf Sci 107:102. doi: 10.1016/S0169-4332(96)00512-010.1016/S0169-4332(96)00512-0 ↗
31. Koster G, Rijnders G, Blank DHA, Rogalla H (2000) Surface morphology determined by (001) singel-crystal SrTiO3 termination. Physica C 339:21510.1016/S0921-4534(00)00363-4 ↗
32. Atiya G, Mikhelashvili V, Eisenstein G, Kaplan WD (2013) Solid-state dewetting of Pt on (100) SrTiO3. J Mater Sci. doi: 10.1007/s10853-013-7966-510.1007/s10853-013-7966-5 ↗
33. Thangadurai P, Lumelsky Y, Silverstein MS, Kaplan WD (2008) TEM specimen preparation of semiconductor-PMMA-metal interfaces. Mater Charact 59:162310.1016/j.matchar.2008.02.007 ↗
34. Baram M, Kaplan WD (2008) Quantitative HRTEM analysis of FIB prepared specimens. J Microsc 232:39510.1111/j.1365-2818.2008.02134.x ↗
35. Stadelmann P (1987) EMS—a software package for electron diffraction analysis and HREM image simulation in materials science. Ultramicroscopy 21:131. doi: 10.1016/0304-3991(87)90080-510.1016/0304-3991(87)90080-5 ↗
36. Garcia RE, Blendell J (2012) Equilibrium Wulff Shape Generator doi: https://nanohub.org/resources/wulffman . 10.4231/D3VM42W8Z
37. Ghetta V, Chatain D (2002) Morphologies adopted by Al2O3 single-crystal surfaces in contact with Cu droplets. J Am Ceram Soc 85:961. doi: 10.1111/j.1151-2916.2002.tb00199.x10.1111/j.1151-2916.2002.tb00199.x ↗
38. Akiva R, Berner A, Kaplan WD (2013) The solubility limit of CaO in α-alumina at 1600 °C. J Am Ceram Soc. doi: 10.1111/jace.1244210.1111/jace.12442 ↗
39. Winterbottom WL (1967) Equilibrium shape of a small particle in contact with a foreign substrate. Acta Metall 15:303. doi: 10.1016/0001-6160(67)90206-410.1016/0001-6160(67)90206-4 ↗
40. Kumikov VK, Khokonov KB (1983) On the measurement of surface free energy and surface tension of solid metals. J Appl Phys 54:134610.1063/1.332209 ↗
41. Kauffmann Y, Recnik A, Kaplan WD (2005) The accuracy of quantitative image matching for HRTEM applications. Mater Charact 54:19410.1016/j.matchar.2004.11.012 ↗
42. Wynblatt P, Chatain D (2009) Surface segregation anisotropy and the equilibrium shape of alloy crystals. Rev Adv Mater Sci 21:44
43. McLean M, Mykura H (1966) The temperature dependence of the surface energy anisotropy of platinum. Surf Sci 5:466. doi: 10.1016/0039-6028(66)90042-210.1016/0039-6028(66)90042-2 ↗
44. Wang T, Lee C, Schmidt LD (1985) Shape and orientation of supported Pt particles. Surf Sci 163:181. doi: 10.1016/0039-6028(85)90857-X10.1016/0039-6028(85)90857-X ↗
45. Lee WH, Vanloon KR, Petrova V, Woodhouse JB, Loxton CM, Masel RI (1990) The equilibrium shape and surface energy anisotropy of clean platinum. J Catal 126:658. doi: 10.1016/0021-9517(90)90028-I10.1016/0021-9517(90)90028-I ↗
46. Ramachandran AS, Anderson SL, Datye AK (1993) The effect of adsorbate and pretreatment on the shape and reactivity of silica-supported platinum particles. Ultramicroscopy 51:282. doi: 10.1016/0304-3991(93)90154-P10.1016/0304-3991(93)90154-P ↗
47. Rupprechter G, Freund H-J (2000) Adsorbate-induced restructuring and pressure-dependent adsorption on metal nanoparticles studied by electron microscopy and sum frequency generation spectroscopy. Top Catal 14:3. doi: 10.1023/a:100909461385010.1023/A:1009094613850 ↗
48. Cabié M, Giorgio S, Henry CR, Axet MR, Philippot K, Chaudret B (2010) Direct observation of the reversible changes of the morphology of Pt nanoparticles under gas environment. J Phys Chem C 114:2160. doi: 10.1021/jp906721g10.1021/jp906721g ↗
49. Vitos L, Ruban AV, Skriver HL, Kollár J (1998) The surface energy of metals. Surf Sci 411:186. doi: 10.1016/S0039-6028(98)00363-X10.1016/S0039-6028(98)00363-X ↗
50. Skriver HL, Rosengaard NM (1992) Surface energy and work function of elemental metals. Phys Rev B 46:715710.1103/PhysRevB.46.7157 ↗
51. Ning T, Yu Q, Ye Y (1988) Multilayer relaxation at the surface of fcc metals: Cu, Ag, Au, Ni, Pd, Pt, Al. Surf Sci 206:L857. doi: 10.1016/0039-6028(88)90008-810.1016/0039-6028(88)90008-8 ↗
52. Foiles SM, Baskes MI, Daw MS (1986) Embedded-atom-method functions for the fcc metals Cu, Ag, Au, Ni, Pd, Pt, and their alloys. Phys Rev B 33:798310.1103/PhysRevB.33.7983 ↗
53. Rodríguez AM, Bozzolo G, Ferrante J (1993) Multilayer relaxation and surface energies of fcc and bcc metals using equivalent crystal theory. Surf Sci 289:100. doi: 10.1016/0039-6028(93)90891-M10.1016/0039-6028(93)90891-M ↗
54. Erdman N, Marks LD (2003) SrTiO3(001) surface structures under oxidizing conditions. Surf Sci 526:107. doi: 10.1016/s0039-6028(02)02573-610.1016/S0039-6028(02)02573-6 ↗
55. Castell MR (2002) Scanning tunneling microscopy of reconstructions on the SrTiO3(001) surface. Surf Sci 505:1. doi: 10.1016/S0039-6028(02)01393-610.1016/S0039-6028(02)01393-6 ↗
56. Jiang QD, Zegenhagen J (1999) c(6 × 2) and c(4 × 2) reconstruction of SrTiO3(001). Surf Sci 425:343. doi: 10.1016/S0039-6028(99)00223-X10.1016/S0039-6028(99)00223-X ↗
57. Nishimura T, Ikeda A, Namba H, Morishita T, Kido Y (1999) Structure change of TiO2-terminated SrTiO3(001) surfaces by annealing in O2 atmosphere and ultrahigh vacuum. Surf Sci 421:273. doi: 10.1016/S0039-6028(98)00840-110.1016/S0039-6028(98)00840-1 ↗
58. Martín González MS, Aguirre MH, Morán E et al (2000) In situ reduction of (100) SrTiO3. Solid State Sci 2:519. doi: 10.1016/S1293-2558(00)01068-210.1016/S1293-2558(00)01068-2 ↗
59. Kaplan WD, Chatain D, Wynblatt P, Carter WC (2013) A review of wetting versus adsorption, complexions, and related phenomena: the rosetta stone of wetting. J Mater Sci 48:5681. doi: 10.1007/s10853-013-7462-y10.1007/s10853-013-7462-y ↗