Preparation, characterization, conductivity and thermal expansion studies of Ca0.5SbMP3O12 (M = Al, Fe, Cr)
Source abstract
Abstract
Nasicon type compounds of general formula Ca0.5SbMP3O12 (M = Al, Fe, Cr) are prepared by solid-state method. All the compounds crystallize in hexagonal lattice with $$ R \,\bar 3\,c $$ space group. The IR spectra show characteristic PO4 vibrations. Conductivity studies indicate the presence of charged defects. The Cole-Cole plots of impedance are semicircles between 150 and 350 °C. The thermal expansion of these samples is studied in the temperature range 25–500 °C.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nuclear materials and radiation effects · Microwave Dielectric Ceramics Synthesis · Ferroelectric and Piezoelectric Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (23)
Show source-provided references
1. Goodenough JB, Hong HYP, Kafalas JA (1976) Mater Res Bull 11:303
2. Hong HY-P (1976) Mater Res Bull 11:17310.1016/0025-5408(76)90073-8 ↗
3. Alamo J, Roy R (1984) J Am Ceram Soc 67:C7810.1111/j.1151-2916.1984.tb19516.x ↗
4. Roy R, Agarwal DK, Roy RA (1984) Mater Res Bull 19:47110.1016/0025-5408(84)90108-9 ↗
5. Hagman LO, Kierkegaard P (1968) Acta Chem Scand 22:182210.3891/acta.chem.scand.22-1822 ↗
6. Sljukic M, Matkovic B, Prodic B (1969) Ziet Kistal 130:148
7. Agarwal DK, Stubican VS (1985) Mater Res Bull 20:9910.1016/0025-5408(85)90035-2 ↗
8. Lenain GE, McKinstry HA, Limaye SY, Woodword A (1984) Mater Res Bull 19:145110.1016/0025-5408(84)90258-7 ↗
9. Oota T, Yamai I (1986) J Am Ceram Soc 69:110.1111/j.1151-2916.1986.tb04682.x ↗
10. Limaye SY, Agarwal DK, McKinstry HA (1987) J Am Ceram Soc 70:C23210.1111/j.1151-2916.1987.tb04884.x ↗
11. Roy R, Vance ER, Alamo J (1982) Mater Res Bull 17:58510.1016/0025-5408(82)90040-X ↗
12. Agarwal DK, Adair JH (1990) J Am Chem Soc 71:2153
13. Brik Y, Kachimi M, Verduraz FB, Ziyad M (2001) Microporous Mesoporous Mater 43:10310.1016/S1387-1811(00)00353-X ↗
14. Srinivasulu B, Vithal M (1999) J Mater Sci Lett 18:177110.1023/A:1006683312303 ↗
15. Barj M, Perthius H, Colombon Ph (1983) Solid State Ionics 11:15710.1016/0167-2738(83)90053-X ↗
16. Mbandza A, Bordes E, Courtine P (1985) Mater Res Bull 20:25110.1016/0025-5408(85)90180-1 ↗
17. Barg M, Lucazeau G, Delmas C (1992) J Solid State Chem 100:14110.1016/0022-4596(92)90164-Q ↗
18. Le Polles G, Videau JJ, Olazcuaga R, Couzi M (1996) J Solid State Chem 127:34110.1006/jssc.1996.0392 ↗
19. Koteswara Rao K, Rambabu G, Raghavender M, Prasad G, Kumar GS, Vithal M (2005) Solid State Ionics 176:270110.1016/j.ssi.2005.07.016 ↗
20. Kasturi Rangan K, Gopalakrishnan J (1995) Inorg Chem 34:969
21. Jonscher AK (1980) Phys Thin Films 11:232
22. Losilla ER, Aranda MAG, Bruque S, Paris MA, Sanz J, West AR (1998) Chem Mater 10:66510.1021/cm970648j ↗
23. Alamo J (1993) Solid State Ionics 63–65:54710.1016/0167-2738(93)90158-Y ↗