journal article·2021-07

Experimental and computational investigation of Ti-Nb-Fe-Zr alloys with limited Fe contents for biomedical applications

Camilo A. F. Salvador, Mariana R. Dal Bo, Dalton D. Lima, Caetano R. Miranda, Rubens Caram

Journal of Materials Science· Volume 56· Issue 19
Publisher page

Abstract

Among many β-metastable alloys explored for biomedical applications, alloys from the Ti-Nb-Fe-Zr system present great potential regarding cost and mechanical strength. In this article, we take a new look at the possibility of using Fe as a minor alloying element in the Ti-Nb-Fe-Zr system, with additions up to 2.0 wt% Fe. Additional compositions fixing the Nb/Fe ratio and changing Zr content from 7–13 wt% were also explored, resulting in a total of five different alloys. The samples were solution-treated and then subjected to three different conditions: water-quenched, furnace-cooled, and step-quenched to 450 oC for 12 h. Resultant microstructures were analyzed using X-ray diffraction, differential scanning calorimetry, scanning, and transmission electron microscopy. DSC experiments indicate that Zr might alter the phase transformations that occur during heating and cooling cycles. First-principles calculations confirmed that Zr's addition is crucial to reduce the elastic modulus of the β matrix and increase the ω-phase formation energy relative to β. All alloys presented mechanical properties suitable for biomedical applications; however, Ti-23Nb-2.0Fe-10Zr (wt %) stands out with the best combination of mechanical strength and elastic modulus after aging.
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Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Orthopaedic implants and arthroplasty · Advanced materials and composites

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