journal article·2017-12

Effect of Al3+ modification on cobalt ferrite and its impact on the magnetoelectric effect in BCZT–CFO multiferroic composites

M. Naveed-Ul-Haq, Vladimir V. Shvartsman, Gabriel Constantinescu, Harsh Trivedi, Soma Salamon, Joachim Landers, Heiko Wende, Doru C. Lupascu

Journal of Materials Science· Volume 52· Issue 23
Publisher page

Abstract

One of the methods to enhance the functional properties of two-phase multiferroic magnetoelectrics is to increase magnetostriction of the ferrite phase. Al3+-modified cobalt ferrite Co(Al0.5Fe1.5)O4 shows better magnetostriction than unmodified cobalt ferrite. It is used in combination with (Ba,Ca)(Zr,Ti)O3 which has very good piezoelectric properties, to form a multiferroic composite. The composite shows good magnetoelectric characteristics, both macroscopically (converse magnetoelectric coefficient of 11 ps/m) and microscopically. Al3+ proves to be the best non-magnetic dopant to enhance magnetostriction in CoFe2O4 and thus the magnetoelectric coefficient.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Lupascu DC, Wende H, Etier M, Nazrabi A, Anusca I, Trivedi H, Shvartsman VV, Landers J, Salamon S, Schmitz-Antoniak C (2015) Measuring the magnetoelectric effect across scales. GAMM-Mitteilungen 38(1):25–7410.1002/gamm.201510003 ↗
2. Bibes M, Barthelemy A (2008) Multiferroics: towards a magnetoelectric memory. Nat Mater 7(6):425–42610.1038/nmat2189 ↗
3. Ma J, Hu J, Li Z, Nan C-W (2011) Recent progress in multiferroic magnetoelectric composites: from bulk to thin films. Adv Mater 23(9):1062–108710.1002/adma.201003636 ↗
4. Zhai J, Xing Z, Dong S, Li J, Viehland D (2006) Detection of pico-Tesla magnetic fields using magneto-electric sensors at room temperature. Appl Phys Lett 88(6):06251010.1063/1.2172706 ↗
5. Dai X, Wen Y, Li P, Yang J, Zhang G (2009) Modeling, characterization and fabrication of vibration energy harvester using Terfenol-D/PZT/Terfenol-D composite transducer. Sens Actuators A Phys 156(2):350–35810.1016/j.sna.2009.10.002 ↗
6. Lou J, Reed D, Liu M, Sun NX (2009) Electrostatically tunable magnetoelectric inductors with large inductance tunability. Appl Phys Lett 94(11):11250810.1063/1.3103273 ↗
7. Dong S, Li JF, Viehland D, Cheng J, Cross LE (2004) A strong magnetoelectric voltage gain effect in magnetostrictive-piezoelectric composite. Appl Phys Lett 85(16):3534–353610.1063/1.1786631 ↗
8. Haertling GH (1999) Ferroelectric ceramics: history and technology. J Am Ceram Soc 82(4):797–81810.1111/j.1151-2916.1999.tb01840.x ↗
9. Liu W, Ren X (2009) Large piezoelectric effect in Pb-free ceramics. Phys Rev Lett 103(25):25760210.1103/PhysRevLett.103.257602 ↗
10. Feng Z, Luo J, Zhang W, Tang X, Cheng Z, Shi D, Dou S (2015) Enhanced piezoelectric properties of solution-modified Ba(Zr0.2Ti0.8)O3–(Ba0.7Ca0.3)TiO3 thick films. J Alloys Compd 632:651–65410.1016/j.jallcom.2015.01.286 ↗
11. Ehmke MC, Ehrlich SN, Blendell JE, Bowman KJ (2012) Phase coexistence and ferroelastic texture in high strain (1 − x)Ba(Zr0.2Ti0.8)O3–x(Ba0.7Ca0.3)TiO3 piezoceramics. J Appl Phys 111(12):12411010.1063/1.4730342 ↗
12. Acosta M, Khakpash N, Someya T, Novak N, Jo W, Nagata H, Rossetti GA, Rödel J (2015) Origin of the large piezoelectric activity in (1-x)Ba(Zr0.2Ti0.8)O3–x(Ba0.7Ca0.3)TiO3 ceramics. Phys Rev B 91(10):10410810.1103/PhysRevB.91.104108 ↗
13. Rödel J, Webber KG, Dittmer R, Jo W, Kimura M, Damjanovic D (2015) Transferring lead-free piezoelectric ceramics into application. J Eur Ceram Soc 35(6):1659–168110.1016/j.jeurceramsoc.2014.12.013 ↗
14. Borhan AI, Iordan AR, Palamaru MN (2013) Correlation between structural, magnetic and electrical properties of nanocrystalline Al3+ substituted zinc ferrite. Mater Res Bull 48(7):2549–255610.1016/j.materresbull.2013.03.012 ↗
15. Ranvah N, Nlebedim IC, Melikhov Y, Snyder JE, Jiles DC, Moses AJ, Williams PI, Anayi F, Song SH (2008) Temperature dependence of magnetostriction of Co1+xGexFe2−2xO4 for magnetostrictive sensor and actuator applications. IEEE Trans Magn 44(11):3013–301610.1109/TMAG.2008.2004535 ↗
16. Chen Y, Snyder JE, Schwichtenberg CR, Dennis KW, McCallum RW, Jiles DC (1999) Metal-bonded Co-ferrite composites for magnetostrictive torque sensor applications. IEEE Trans Magn 35(5):3652–365410.1109/20.800620 ↗
17. Nlebedim IC, Ranvah N, Melikhov Y, Williams PI, Snyder JE, Moses AJ, Jiles DC (2009) Magnetic and magnetomechanical properties of CoAlxFe2−xO4 for stress sensor and actuator applications. IEEE Trans Magn 45(10):4120–412310.1109/TMAG.2009.2021846 ↗
18. Kumar L, Kar M (2011) Influence of Al3+ ion concentration on the crystal structure and magnetic anisotropy of nanocrystalline spinel cobalt ferrite. J Magn Magn Mater 323(15):2042–204810.1016/j.jmmm.2011.03.010 ↗
19. Singhal S, Barthwal SK, Chandra K (2006) XRD, magnetic and Mössbauer spectral studies of nano size aluminum substituted cobalt ferrites (CoAlxFe2−xO4). J Magn Magn Mater 306(2):233–24010.1016/j.jmmm.2006.03.023 ↗
20. Anantharamaiah PN, Joy PA (2015) Magnetic and magnetostrictive properties of aluminium substituted cobalt ferrite synthesized by citrate-gel method. J Mater Sci 50(19):6510–6517. doi: 10.1007/s10853-015-9211-x10.1007/s10853-015-9211-x ↗
21. Jauhar S, Kaur J, Goyal A, Singhal S (2016) Tuning the properties of cobalt ferrite: a road towards diverse applications. RSC Adv 6(100):97694–9771910.1039/C6RA21224G ↗
22. Borisov P, Hochstrat A, Shvartsman VV, Kleemann W (2007) Superconducting quantum interference device setup for magnetoelectric measurements. Rev Sci Instrum 78(10):10610510.1063/1.2793500 ↗
23. Jie L, Huaiwu Z, Yinong L, Yulong L, Guokun M, Hong Y (2015) Co–Ti co-substitution of M-type hexagonal barium ferrite. Mater Res Express 2(4):04610410.1088/2053-1591/2/4/046104 ↗
24. Zhang R-F, Deng C-Y, Ren L, Li Z, Zhou J-P (2014) Ferroelectric, ferromagnetic, and magnetoelectric properties of multiferroic Ni0.5Zn0.5Fe2O4–BaTiO3 composite ceramics. J Electron Mater 43(4):1043–104710.1007/s11664-013-2904-5 ↗
25. Qi X, Zhou J, Li B, Zhang Y, Yue Z, Gui Z, Li L (2004) Preparation and spontaneous polarization–magnetization of a new ceramic ferroelectric–ferromagnetic composite. J Am Ceram Soc 87(10):1848–185210.1111/j.1151-2916.2004.tb06329.x ↗
26. Zhong XL, Wang JB, Liao M, Huang GJ, Xie SH, Zhou YC, Qiao Y, He JP (2007) Multiferroic nanoparticulate Bi3.15Nd0.85Ti3O12–CoFe2O4 composite thin films prepared by a chemical solution deposition technique. Appl Phys Lett 90(15):15290310.1063/1.2709946 ↗
27. Li F, Liu J, Evans DG, Duan X (2004) Stoichiometric synthesis of pure MFe2O4 (M = Mg Co, and Ni) spinel ferrites from tailored layered double hydroxide (hydrotalcite-like) precursors. Chem Mater 16(8):1597–160210.1021/cm035248c ↗
28. Wu L, Shen B, Sun S (2015) Synthesis and assembly of barium-doped iron oxide nanoparticles and nanomagnets. Nanoscale 7(39):16165–1616910.1039/C5NR05291B ↗
29. Hook HJV (1964) Oxygen stoichiometry in the compound BaFeO3−x. J Phys Chem 68(12):3786–378910.1021/j100794a041 ↗
30. Malinofsky WW, Kedesdy H (1954) Barium iron oxide isomorphs of hexagonal and tetragonal BaTiO3. J Am Chem Soc 76(11):3090–309110.1021/ja01640a081 ↗
31. Naveed-Ul-Haq M, Shvartsman VV, Salamon S, Wende H, Trivedi H, Mumtaz A, Lupascu DC (2016) A new (Ba, Ca) (Ti, Zr)O3 based multiferroic composite with large magnetoelectric effect. Sci Rep 6:3216410.1038/srep32164 ↗
32. Evans DM, Schilling A, Kumar A, Sanchez D, Ortega N, Arredondo M, Katiyar RS, Gregg JM, Scott JF (2013) Magnetic switching of ferroelectric domains at room temperature in multiferroic PZTFT. Nat Commun 4:153410.1038/ncomms2548 ↗
33. Wan JG, Wang XW, Wu YJ, Zeng M, Wang Y, Jiang H, Zhou WQ, Wang GH, Liu J-M (2005) Magnetoelectric CoFe2O4–Pb(Zr, Ti)O3 composite thin films derived by a sol–gel process. Appl Phys Lett 86(12):12250110.1063/1.1889237 ↗
34. Srinivasan G, Rasmussen ET, Gallegos J, Srinivasan R, Bokhan YI, Laletin VM (2001) Magnetoelectric bilayer and multilayer structures of magnetostrictive and piezoelectric oxides. Phys Rev B 64(21):21440810.1103/PhysRevB.64.214408 ↗
35. Zeng M, Wan JG, Wang Y, Yu H, Liu J-M, Jiang XP, Nan CW (2004) Resonance magnetoelectric effect in bulk composites of lead zirconate titanate and nickel ferrite. J Appl Phys 95(12):8069–807310.1063/1.1739531 ↗
36. Shvartsman VV, Alawneh F, Borisov P, Kozodaev D, Lupascu DC (2011) Converse magnetoelectric effect in CoFe2O4–BaTiO3 composites with a core–shell structure. Smart Mater Struct 20(7):07500610.1088/0964-1726/20/7/075006 ↗
37. Lee SJ, Lo CCH, Matlage PN, Song SH, Melikhov Y, Snyder JE, Jiles DC (2007) Magnetic and magnetoelastic properties of Cr-substituted cobalt ferrite. J Appl Phys 102(7):07391010.1063/1.2794711 ↗
38. Bozorth RM, Tilden EF, Williams AJ (1955) Anisotropy and magnetostriction of some ferrites. Phys Rev 99(6):1788–179810.1103/PhysRev.99.1788 ↗
39. Cullity BD, Graham CD (2011) Introduction to magnetic materials, 2nd edn. Wiley, New York
40. Lacheisserie EDTD, Gignoux D, Schlenker M (2005) Magnetism: fundamentals. Springer-Verlag, New York, p 50710.1007/978-0-387-23063-4 ↗
41. Song SH, Lo CCH, Lee SJ, Aldini ST, Snyder JE, Jiles DC (2007) Magnetic and magnetoelastic properties of Ga-substituted cobalt ferrite. J Appl Phys 101(9):09C51710.1063/1.2712941 ↗
42. Melikhov Y, Snyder JE, Lo CCH, Matlage PN, Song SH, Dennis KW, Jiles DC (2006) The effect of Cr-substitution on the magnetic anisotropy and its temperature dependence in Cr-substituted cobalt ferrite. IEEE Trans Magn 42(10):2861–286310.1109/TMAG.2006.879888 ↗
43. Lupascu D, Rödel J (2005) Fatigue in bulk lead zirconate titanate actuator materials. Adv Eng Mater 7(10):882–89810.1002/adem.200500117 ↗
44. Balke N, Maksymovych P, Jesse S, Herklotz A, Tselev A, Eom C-B, Kravchenko II, Yu P, Kalinin SV (2015) Differentiating ferroelectric and nonferroelectric electromechanical effects with scanning probe microscopy. ACS Nano 9(6):6484–649210.1021/acsnano.5b02227 ↗
45. Trivedi H, Shvartsman VV, Lupascu DC, Medeiros MSA, Pullar RC, Kholkin AL, Zelenovskiy P, Sosnovskikh A, Shur VY (2015) Local manifestations of a static magnetoelectric effect in nanostructured BaTiO3–BaFe12O9 composite multiferroics. Nanoscale 7(10):4489–449610.1039/C4NR05657D ↗