One-pot synthesis of Ni-SSZ-13 zeolite using a nickel-amine complex as an efficient organic template
Source abstract
Abstract
We show that a nickel-amine complex (nickel-diethylenetriamine, Ni-DETA) is an efficient organic template for the one-pot synthesis of Ni-SSZ-13 zeolite. The effects of the reaction compositions, including the molar ratios of SiO2/Al2O3, H2O/Al2O3, Ni-DETA/Al2O3, and Na2O/Al2O3, on the synthesis of the pure product were investigated using different temperatures and synthesis times. Physicochemical characterizations, including XRD, SEM, and 27Al NMR, show that the zeolitic product has good crystallinity, uniform crystals, and contains a tetrahedral Al3+ species. The N2 sorption isotherms, TG–DTA curves, IR spectra, and UV–Vis spectra show that Ni-DETA acts as a template in the product obtained. Interestingly, Ni-SSZ-13 zeolite is obtained by the conversion of Ni-Y zeolite produced in the crystallization process.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Zeolite Catalysis and Synthesis · Catalytic Processes in Materials Science · Mesoporous Materials and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (35)
Show source-provided references
1. Cundy CS, Cox PA (2003) The hydrothermal synthesis of zeolites: history and development from the earliest days to the present time. Chem Rev 103:663–70210.1021/cr020060i ↗
2. Davis ME (2014) Zeolites from a materials chemistry perspective. Chem Mater 26:239–24510.1021/cm401914u ↗
3. Meng XJ, Xiao FS (2014) Green routes for synthesis of zeolites. Chem Rev 114:1521–154310.1021/cr4001513 ↗
4. Moliner M, Martinez C, Corma A (2015) Multipore zeolites: synthesis and catalytic applications. Angew Chem Int Ed 54:3560–357910.1002/anie.201406344 ↗
5. Hong SB, Min HK, Shin CH, Cox PA, Warrender SJ, Wright PA (2007) Synthesis, crystal structure, characterization, and catalytic properties of TNU-9. J Am Chem Soc 129:10870–1088510.1021/ja073109g ↗
6. Li YP, Sun CJ, Fan WB, Wang YY, Lan AD, Han PD, Li XF, Dou T (2015) One-pot synthesis of hierarchical mordenite and its performance in the benzylation of benzene with benzyl alcohol. J Mater Sci 50:5059–5067. doi: 10.1007/s10853-015-9055-410.1007/s10853-015-9055-4 ↗
7. Gonzalez MR, Pereyra AM, Bosch P, Fetter G, Lara VH, Basaldella EI (2016) Structural and morphological evolutions of spent FCC catalyst pellets toward NaA zeolite. J Mater Sci 51:5061–5072. doi: 10.1007/s10853-016-9809-710.1007/s10853-016-9809-7 ↗
8. Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger RJ, Chmelka BF, Ryoo R (2011) Directing zeolite structures into hierarchically nanoporous architectures. Science 333:328–33210.1126/science.1204452 ↗
9. Zhang XY, Liu DX, Xu DD, Asahina S, Cychosz KA, Agrawal KV, Al Wahedi Y, Bhan A, Al Hashimi S, Terasaki O, Thommes M, Tsapatsis M (2012) Synthesis of self-pillared zeolite nanosheets by repetitive branching. Science 336:1684–168710.1126/science.1221111 ↗
10. Wu QM, Wang X, Meng XJ, Yang CG, Liu Y, Jin YY, Yang Q, Xiao FS (2014) Organotemplate-free, seed-directed, and rapid synthesis of Al-rich zeolite MTT with improved catalytic performance in isomerization of m-xylene. Microporous Mesoporous Mater 186:106–11210.1016/j.micromeso.2013.11.043 ↗
11. Wang Q, Cui ZM, Cao CY, Song WG (2011) 0.3 Å makes the difference: dramatic changes in methanol-to-olefin activities between H-ZSM-12 and H-ZSM-22 zeolites. J Phys Chem C 115:24987–2499210.1021/jp209182u ↗
12. Corma A, Diaz-Cabanas M, Martinez-Triguero J, Rey F, Rius J (2002) A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst. Nature 418:514–51710.1038/nature00924 ↗
13. Wu QM, Liu XL, Zhu LF, Ding LH, Gao P, Wang X, Pan SX, Bian CQ, Meng XJ, Xu J, Deng F, Maurer S, Müller U, Xiao FS (2015) Solvent-free synthesis of zeolites from anhydrous starting raw solids. J Am Chem Soc 137:1052–105510.1021/ja5124013 ↗
14. Wang B, Tian Z, Li P, Wang L, Xu Y, Qu W, He Y, Ma H, Xu Z, Lin L (2010) A novel approach to synthesize ZSM-23 zeolite involving N, N-dimethylformamide. Microporous Mesoporous Mater 134:203–20910.1016/j.micromeso.2010.06.001 ↗
15. Li Z, Marler B, Gies H (2008) A new layered silicate with structural motives of silicate zeolites: synthesis, crystals structure, and properties. Chem Mater 20:1896–190110.1021/cm702880p ↗
16. Kang JH, Xie D, Zones SI, Smeets S, McCusker LB, Davis ME (2016) Synthesis and characterization of CIT-13, a germanosilicate molecular sieve with extra-large pore openings. Chem Mater 28:6250–625910.1021/acs.chemmater.6b02468 ↗
17. Smeets S, McCusker LB, Baerlocher C, Xie D, Chen CY, Zones SI (2015) SSZ-87: a borosilicate zeolite with unusually flexible 10-ring pore openings. J Am Chem Soc 137:2015–202010.1021/ja512411b ↗
18. Lee H, Zones SI, Davis ME (2003) A combustion-free methodology for synthesizing zeolites and zeolite-like materials. Nature 425:385–38810.1038/nature01980 ↗
19. Dorset DL, Strohmaier KG, Kliewer CE, Corma A, Díaz-Cabañas MJ, Rey F, Gilmore CJ (2008) Crystal structure of ITQ-26, a 3D framework with extra-large pores. Chem Mater 20:5325–533110.1021/cm801126t ↗
20. Dorset DL, Kennedy GJ, Strohmaier KG, Diaz-Cabañas MJ, Rey F, Corma A (2006) P-derived organic cations as structure-directing agents: synthesis of a high-silica zeolite (ITQ-27) with a two-dimensional 12-ring channel system. J Am Chem Soc 128:8862–886710.1021/ja061206o ↗
21. Corma A, Diaz-Cabanas MJ, Jorda JL, Rey F, Sastre G, Strohmaier KG (2008) A zeolitic structure (ITQ-34) with connected 9-and 10-ring channels obtained with phosphonium cations as structure directing agents. J Am Chem Soc 130:16482–1648310.1021/ja806903c ↗
22. Hernández-Rodríguez M, Jordá JL, Rey F, Corma A (2012) Synthesis and structure determination of a new microporous zeolite with large cavities connected by small pores. J Am Chem Soc 134:13232–1323510.1021/ja306013k ↗
23. Jo C, Lee S, Cho SJ, Ryoo R (2015) Synthesis of silicate zeolite analogues using organic sulfonium compounds as structure-directing agents. Angew Chem Int Ed 54:12805–1280810.1002/anie.201506678 ↗
24. Wheatley PS, Love CJ, Morrison JJ, Shannon IJ, Morris RE (2002) Synthesis of two new aluminophosphate based layered materials using Tet-A as a structure-directing agent. J Mater Chem 12:477–48210.1039/b106005h ↗
25. Garcia R, Shannon IJ, Slawin AM, Zhou W, Cox PA, Wright PA (2003) Synthesis, structure and thermal transformations of aluminophosphates containing the nickel complex [Ni (diethylenetriamine) 2] 2+ as a structure directing agent. Microporous Mesoporous Mater 58:91–10410.1016/S1387-1811(02)00608-X ↗
26. Garcia R, Philp EF, Slawin AM, Wright PA, Cox PA (2001) Nickel complexed within an azamacrocycle as a structure directing agent in the crystallization of the framework metalloaluminophosphates STA-6 and STA-7. J Mater Chem 11:1421–142710.1039/b009813m ↗
27. Picone AL, Warrender SJ, Slawin AM, Dawson DM, Ashbrook SE, Wright PA, Thompson SP, Gaberova L, Llewellyn PL, Moulin B, Vimont A, Daturi M, Park MB, Sung SK, Nam IS, Hong SB (2011) A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NO. Microporous Mesoporous Mater 146:36–4710.1016/j.micromeso.2011.04.039 ↗
28. Freyhardt CC, Tsapatsis M, Lobo RF, Balkus KJ, Davis ME (1996) A high-silica zeolite with a 14-tetrahedral-atom pore opening. Nature 381:295–29810.1038/381295a0 ↗
29. Lobo RF, Tsapatsis M, Freyhardt CC, Khodabandeh S, Wagner P, Chen CY, Jr Balkus K J, Zones SI, Davis ME (1997) Characterization of the extra-large-pore zeolite UTD-1. J Am Chem Soc 119:8474–848410.1021/ja9708528 ↗
30. Ren L, Zhu L, Yang C, Chen Y, Sun Q, Zhang H, Li C, Nawaz F, Meng X, Xiao F-S (2011) Designed copper-amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NOx by NH3. Chem Commun 47:9789–979110.1039/c1cc12469b ↗
31. Li Z, Navarro M, Martinez-Triguero J, Yu J, Corma A (2016) Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins. Catal Sci Technol 6:5856–586310.1039/C6CY00433D ↗
32. Wang X, Wu Q, Chen C, Pan S, Zhang W, Meng X, Maurer S, Feyen M, Muller U, Xiao F-S (2015) Atom-economical synthesis of a high silica CHA zeolite using a solvent-free route. Chem Commun 51:16920–1692310.1039/C5CC05980A ↗
33. Chen B, Xu R, Zhang R, Liu N (2014) Economical Way to Synthesize SSZ-13 with Abundant Ion-Exchanged Cu+ for an Extraordinary Performance in Selective Catalytic Reduction (SCR) of NOx by Ammonia. Environ Sci Technol 48:13909–1391610.1021/es503707c ↗
34. Xu R, Zhang R, Liu N, Chen B, Qiao S (2015) Template Design and Economical Strategy for the Synthesis of SSZ-13 (CHA-Type) Zeolite as an Excellent Catalyst for the Selective Catalytic Reduction of NOx by Ammonia. ChemCatChem 7:3842–384710.1002/cctc.201500771 ↗
35. Martin N, Moliner M, Corma A (2015) High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium: SCR of NOx. Chem Commun 51:9965–996810.1039/C5CC02670A ↗