Synthesis and structural characterization of α-MoO3 from molybdic acid wastewater
Source abstract
Abstract
The study investigated the use of ethylene glycol to form α-MoO3 from molybdic acid wastewater by thermal treatment at 300 °C for 1 h. The color change, pH values, and residual molybdenum concentration in the wastewater were dependent on the reaction times that were used. The results of UV–visible and Fourier transform infrared (FTIR) spectroscopy were used to explain the reaction process. During the treatment process, the morphologies of the constituents were observed using scanning electron microscopy. In this work, X-ray photoelectron spectroscopy and transmission electron microscopy demonstrated that when the molybdenum oxide powder was treated thermally at 300 °C, the material exhibited crystallinity, and the peaks were indexed to correspond with the (002) and (200) crystallographic planes, which were identified as orthorhombic molybdenum trioxide (α-MoO3). In addition, the FTIR and X-ray photoelectron spectroscopy confirmed that α-MoO3 powder had been synthesized.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Transition Metal Oxide Nanomaterials · Catalysis and Oxidation Reactions · Catalytic Processes in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
Show source-provided references
1. Kar BB, Datta P, Misra VN (2004) Hydrometallurgy 72:87. doi: 10.1016/S0304-386X(03)00122-110.1016/S0304-386X(03)00122-1 ↗
2. Moulijn JA, van Diepen AE, Kapteijn F (2001) Appl Catal A-Gen 212:3. doi: 10.1016/S0926-860X(00)00842-510.1016/S0926-860X(00)00842-5 ↗
3. Chen Y, Feng QM, Shao YH, Zhang GF, Ou LM, Lu YP (2006) Int J Miner Process 79:42. doi: 10.1016/j.minpro.2005.11.00910.1016/j.minpro.2005.11.009 ↗
4. Li S, Lee JS, Hyeon T, Suslick KS (1999) Appl Catal A-Gen 184:1. doi: 10.1016/S0926-860X(99)00044-710.1016/S0926-860X(99)00044-7 ↗
5. Ramirez de Agudelo MM, Galarraga CE (1987) Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks and process for preparing the catalyst, US 4729980
6. Topsøe H, Clausen BS, Topsoe NY, Zeuthen P (1989) Stud Surf Sci Catal 53:77. doi: 10.1016/S0167-2991(08)61061-710.1016/S0167-2991(08)61061-7 ↗
7. Dufresne P (2007) Appl Catal A-Gen 322:67. doi: 10.1016/j.apcata.2007.01.01310.1016/j.apcata.2007.01.013 ↗
8. Jan RJ, Montgomery AH (1983) Process for the separation and recovery of molybdenum and uranium from leach solution using ion exchange, US Patent 4375452
9. Mendez-Vivar J, Campero A, Livage J, Sanchez C (1990) J Non-Cryst Solids 121:26. doi: 10.1016/0022-3093(90)90098-710.1016/0022-3093(90)90098-7 ↗
10. Medvedev AS, Aleksandrov PV (2009) Russ J Non-Ferr Met 50:353. doi: 10.3103/S106782120904008710.3103/S1067821209040087 ↗
11. Olson GJ, Clark TR (2008) Hydrometallurgy 93:10. doi: 0.1016/j.hydromet.2008.02.01310.1016/j.hydromet.2008.02.013 ↗
12. Huang JH, Kargl-Simard C, Oliazadeh M, Alfantazi AM (2004) Hydrometallurgy 75:77. doi: 10.1016/j.hydromet.2004.06.00810.1016/j.hydromet.2004.06.008 ↗
13. Pinto ISS, Soares HMVM (2013) J Clean Prod 1. doi: 10.1016/j.jclepro.2013.03.02110.1016/j.jclepro.2013.03.021 ↗
14. Pinto ISS, Soares HMVM (2012) Hydrometallurgy 129–130:19. doi: 10.1016/j.hydromet.2012.08.00810.1016/j.hydromet.2012.08.008 ↗
15. Joo SH, Kim YU, Kang JG, Yoon HS, Kim DS, Shin SM (2012) Mater Trans 53:2038. doi: 10.2320/matertrans10.2320/matertrans.M2012209 ↗
16. Cifuentes L, RamíRez C, Crisóstomo G, Casas JM (2011) Chem Eng Commun 198:805. doi: 10.1080/00986445.2011.53401510.1080/00986445.2011.534015 ↗
17. Stoyanova A, Iordanova R, Mancheva M, Dimitriev Y (2009) J Optoelectron Adv Mater 11:1127
18. He T, Yao J (2003) J Photochem Photobiol C-Photochem Rev 4:125. doi: 10.1016/S1389-5567(03)00025-X10.1016/S1389-5567(03)00025-X ↗
19. McCarron EM (1986) J Chem Soc Chem Commun 4:336. doi: 10.1039/C3986000033610.1039/C39860000336 ↗
20. Song J, Ni X, Gao L, Zheng H (2007) Mater Chem Phys 102:245. doi: 10.1016/j.matchemphys.2006.12.01110.1016/j.matchemphys.2006.12.011 ↗
21. Chen Y, Lu C, Xu L, Ma Y, Hou W, Zhu JJ (2010) CrystEngComm 12:3740. doi: 10.1039/c000744g10.1039/c000744g ↗
22. Li YB, Bando Y, Goldberg D, Kurashima K (2002) Appl Phys Lett 81:5048. doi: 10.1063/1.153210410.1063/1.1532104 ↗
23. Caillat T, Fleurial JP, Synder GJ (1999) Solid State Sci 1:535. doi: 10.1016/S1293-2558(00)80105-310.1016/S1293-2558(00)80105-3 ↗
24. Queeney KT, Friend CM (2000) J Phys Chem B 104:409. doi: 10.1021/jp991994m10.1021/jp991994m ↗
25. Comini E, Yubao L, Brando Y, Sberveglieri G (2005) Chem Phys Lett 407:368. doi: 10.1016/j.cplett.2005.03.11610.1016/j.cplett.2005.03.116 ↗
26. Tenne R, Margulis L, Genut M, Hodes G (1992) Nature 360:444. doi: 10.1038/360444a010.1038/360444a0 ↗
27. Hussain Z (2001) J Mater Res 16:2695. doi: 10.1557/JMR.2001.036910.1557/JMR.2001.0369 ↗
28. Watanabe T, Miyauchi M, Nakajima A, Hashimoto K (2002) Chem Mater 14:2812. doi: 10.1021/cm020076p10.1021/cm0115362 ↗
29. Price JA, Neblett RF, Plainfield NJ (1996) Preparation of glycol molybdate complexes. US Patent 3285942
30. Fiévet F, Brayner R (2013) The polyol process. In Fiévet F, Brayner R, Coradin T (Eds). Nanomaterials: a danger or a promise? a chemical and biological perspective. Springer, London, p 1. doi: 10.1007/978-1-4471-4213-3_110.1007/978-1-4471-4213-3_1 ↗
31. Epifani M, Imperatori P, Mirenghi L, Schioppa M, Siciliano P (2004) Chem Mat 16:5495. doi: 10.1021/cm048997i10.1021/cm048997i ↗
32. Mitchell PCH (1990) In: Arpe HJ (ed) Ullmann’s Encyclopedia of Industrial Chemistry, 5th edn. Wiley-VCH, Weinheim, p 675
33. Duncan DC, Hill CL (1996) Inorg Chem 35:5828. doi: 10.1021/ic960226w10.1021/ic960226w ↗
34. Morris HE (1932) Chem Rev 10:465. doi: 10.1021/cr60037a00310.1021/cr60037a003 ↗
35. Roe JH, Irish OJ, Boyd JI (1926) J Biol Chem 67: 579. http://www.jbc.org/content/67/3/579.full.pdf+html?sid=0812a7b2-7a52-4e6b-8959-c2b27e4fff5c
36. Pak JJ, Jo JO, Park CH, Kang JG, Shin DH (2008) Mater Trans 49:202. doi: 10.2320/matertrans.MER200719310.2320/matertrans.MER2007193 ↗
37. Chen D, Liu M, Yin L, Li T, Yang Z, Li X, Fan B, Wang H, Zhang R, Li Z, Xu H, Lu H, Yang D, Sune J, Gao L (2011) J Mater Chem 21:9332. doi: 10.1039/C1JM11447F10.1039/c1jm11447f ↗
38. Mizushima T, Fukushima K, Ohkita H, Kakuta N (2007) Appl Catal A-Gen 326:106. doi: 10.1016/j.apcata.2007.04.00610.1016/j.apcata.2007.04.006 ↗
39. Navgire ME, Lande MK, Gambhire AB, Rathod SB, Aware DV, Bhitre SR (2011) Bull Mater Sci 34:535. doi: 10.1007/s12034-011-0108-210.1007/s12034-011-0108-2 ↗
40. Weber T, Muijsers JC, van Wolput JHMC, Verhagen CPJ, Niemantsverdriet JW (1996) J Phys Chem 100:14144. doi: 10.1021/jp961204y10.1021/jp961204y ↗
41. Dong W, Dunn B (1998) J Mater Chem 8:665. doi: 10.1039/A706537J10.1039/a706537j ↗
42. Chen M, Waghmare UV, Friend CM, Kaxiras E (1998) J Chem Phys 109:6854. doi: 10.1063/1.47725210.1063/1.477252 ↗
43. Li J, Kwong FL, Ng DHL (2008) J Am Ceram Soc 91:1350. doi: 10.1111/j.1551-2916.2008.02276.x10.1111/j.1551-2916.2008.02276.x ↗
44. Frost RL, Čjka J, Dickfos MJ (2008) J Raman Spectrosc 39:779. doi: 10.1002/jrs.189710.1002/jrs.1897 ↗
45. Zakharova GS, Täschner C, Volkov VL, Hellmann I, Klingeler R, Leonhardt A, Buchner B (2007) Solid State Sci 9:1028. doi: 10.1016/j.solidstatesciences.2007.07.02210.1016/j.solidstatesciences.2007.07.022 ↗
46. Deng X, Quek SY, Biener MM, Biener J, Kang DH, Schalek R, Kaxiras E, Friend CM (2008) Surf Sci 602:1166. doi: 10.1016/j.susc.2008.01.01410.1016/j.susc.2008.01.014 ↗
47. Barr TL (1978) J Phys Chem 82:1801. doi: 10.1021/j100505a00610.1021/j100505a006 ↗
48. Ramgir NS, Late DJ, Bhise AB, More MA, Mulla IS, Joag DS, Vijayamohanan K (2006) J Phys Chem B 110:18236. doi: 10.1021/jp062813110.1021/jp0628131 ↗