Study of air oxidation of amorphous Zr65Cu17.5Ni10Al7.5 by X-ray photoelectron spectroscopy (XPS)
Source abstract
Abstract
The oxidation of the bulk amorphous alloy Zr65Cu17.5Ni10Al7.5 in air in its amorphous and the supercooled liquid states was studied in the temperature range 573–663 K using X-ray photoelectron spectroscopy (XPS). The oxide film mainly consisted of the oxides of Zr (as ZrO2) and Al (as Al2O3). No Cu or Ni was found in the oxide film formed on the amorphous state of the alloy while significant Cu (as CuO) was present in the oxide film formed on the alloy in its supercooled liquid state. The role of the various alloying elements during oxidation at high temperatures in air is discussed in the paper. The XPS data from oxide film support the previously suggested mechanism for oxidation of this alloy, i.e. the rate controlling process during oxidation of the alloy at low temperatures (in the amorphous state) is the back-diffusion of Ni and Cu, while the oxidation at high temperatures (in the supercooled liquid state) is dominated by the inward diffusion of oxygen.
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Research context
OpenAlex topics: Metallic Glasses and Amorphous Alloys · Cultural Heritage Materials Analysis · Material Dynamics and Properties
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References (31)
Show source-provided references
1. Zhang T, Inoue A, Masumoto T (1991) Mater Trans JIM 32:100510.2320/matertrans1989.32.1005 ↗
2. Johnson WL (1996) Curr Opin Solid State Mater Sci 1:38310.1016/S1359-0286(96)80029-5 ↗
3. Peker A, Johnson WL (1993) Appl Phys Lett 63:234210.1063/1.110520 ↗
4. Hashimoto K (1983) Amorphous metallic alloys. In: Luborsky FE (ed) Butterworths, London, p 471
5. Naka M, Hashimoto K, Masumoto T (1976) Corrosion 32:14610.5006/0010-9312-32.4.146 ↗
6. Dey GK, Savalia RT, Sharma SK, Kulkarni SK (1989) Corros Sci 29:82310.1016/0010-938X(89)90055-3 ↗
7. Asami K, Kimura HM, Hashimoto K, Masumoto T (1995) Mat Trans JIM 36:98810.2320/matertrans1989.36.988 ↗
8. Kiene M, Strunskus T, Hasse G, Faupel F (1999) Mater Res Soc Symp Proc. Materials Research Society, Pittsburgh, PA, USA, 554:167
9. Sharma SK, Strunskus T, Ladebusch H, Faupel F (2001) Mater Sci Eng A 304–306:74710.1016/S0921-5093(00)01586-0 ↗
10. Dhawan A, Raetzke K, Faupel F, Sharma SK (2001) Bull Mater Sci 24:28110.1007/BF02704922 ↗
11. Sun X, Schneider S, Geyer U, Johnson WL, Nicolet M-A (1996) J Mater Res 11:273810.1557/JMR.1996.0347 ↗
12. Triwikantoro, Toma D, Meuris M, Koster U (1999) J Non-Cryst Solids 250–252:71910.1016/S0022-3093(99)00167-2 ↗
13. Koester U, Triwikantoro D (2001) Mater Sci Forum 360–362:2910.4028/www.scientific.net/MSF.360-362.29 ↗
14. Dhawan A, Raetzke K, Faupel F, Sharma SK, Phys Stat Sol (a) 199 No. 3 (2003) 431–43810.1002/pssa.200306688 ↗
15. Tam CY, Shek CH (2005) J Mater Res 20:139610.1557/JMR.2005.0182 ↗
16. Kai W, Hsieh HH, Nieh TG, Kawamura Y (2002) Intermetallics 10:126510.1016/S0966-9795(02)00163-2 ↗
17. Busch R (Private Communication)
18. Knorr K (1999) In: “Selbstdiffusion in Metallischen Massivglaesern”. Ph. D Thesis, University of Muenster, Muenster, Germany
19. Wanger CD, Riggs WM, Davies LE, Moulder JF, Muilenberg GE (1979) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer, Eden Prairie, MN
20. Walz B, Oelhafen P, Guentherodt H-J, Baiker A (1989) Appl Surf Sci 37:33710.1016/0169-4332(89)90495-9 ↗
21. Satoh H, Nakane H, Adachi H (1996) Appl Surf Sci 94/95:24710.1016/0169-4332(95)00382-7 ↗
22. Betz G, Wehner GK (1983) Sputtering by particle bombardment II, vol 52. In: Behriech R (ed) Springer Verlag, Berlin, p 11
23. Malherbe JB, Hofmann S, Sanz JM (1986) Appl Surf Sci 27:35510.1016/0169-4332(86)90139-X ↗
24. Brundle CR, Chuang TJ, Wandelt K (1977) Surf Sci 68:45910.1016/0039-6028(77)90239-4 ↗
25. Wandelt K (1982) Surf Sci Rep 2:7510.1016/0167-5729(82)90003-6 ↗
26. “CRC handbook of chemistry and physics” (1995–96) 76th edn. Lide DR (ed) CRC Press, Boca Raton, pp 34–47
27. Knorr K, Macht M-P, Mehrer H (1999) Bulk metallic glasses. In: Johnson WL, Liu CT, Inoue A (ed) MRS symposia proceedings No. 554. Materials Research Society, Pittsburgh, p 269
28. Faupel F, Frank W, Macht M-P, Mehrer H, Naundorf V, Raetzke K, Schober HR, Sharma SK, Teichler H (2003) Revi Modern Phys 75:23710.1103/RevModPhys.75.237 ↗
29. Hahn H, Averback RS, Shyu H-M (1988) J Less-Common Met 140:34510.1016/0022-5088(88)90395-5 ↗
30. Sharma SK, Banerjee S, Kuldeep, Jain AK (1989) J Mater Res 4:60310.1557/JMR.1989.0603 ↗
31. Bradford SA (1990) In: ASM handbook, vol 13. ASM International, Materials Park, OH, p 64