journal article·2025-10-14Open access

Laser Processing of Ti Contacts for Ohmic Behavior on P-Type 4H-SiC

Roberto Vabres, Gabriele Bellocchi, Corrado Bongiorno, Marilena Vivona, Fabrizio Roccaforte, Paolo Badalà, Paola Mancuso, Valeria Puglisi, Simone Rascunà, Isodiana Crupi

ACS Applied Electronic Materials· Volume 7· Issue 19

Abstract

High Resolution Image Download MS PowerPoint Slide This work explores a key challenge in power device fabrication: the formation of ohmic contacts on p-type 4H-silicon carbide (SiC). We demonstrate a selective, low thermal budget approach using single titanium (Ti) metallization combined with pulsed laser annealing (PLA), as an alternative to both metallic multilayer stacks and conventional high-temperature annealing. By applying PLA with fluences above 3.6 J/cm 2, Ti contacts exhibit linear current–voltage ( I – V ) behavior, indicating effective ohmic contact formation, with over 50% improvement in conduction observed at 3.8 J/cm 2 . Cross-sectional transmission electron microscopy (TEM) and elemental mapping reveal that higher fluences promote deeper SiC consumption, and the formation of a continuous, epitaxially regrown SiC layer, bonded to a uniform titanium carbide (TiC) layer extended deeper into the p-doped region. This structure supports efficient charge transfer and strong interfacial bonding. Furthermore, increasing fluence drives the transient liquid phase composition from Ti-rich toward a more balanced Ti–Si–C composition, promoting the formation of ternary phases enriched in Si and C that enhance interfacial stability and electrical performance. This work demonstrates that PLA offers precise control over interfacial reactions and contact microstructures, offering a scalable, selective, and thermally efficient approach for ohmic contacts on p-type 4H-SiC, advancing the development of high-performance, next-generation SiC-based power electronics.
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Research context

OpenAlex topics: Silicon Carbide Semiconductor Technologies · Semiconductor materials and devices · Semiconductor materials and interfaces

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Engineering Department

University of Palermo

STMicroelectronics

CNR-IMM

Funding

Ministero dell’Istruzione, dell’Università e della Ricerca · Università degli Studi di Palermo

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