journal article·2017-04

Effects of FLiNaK infiltration on thermal expansion behavior of graphite

Wei Qi, Zhoutong He, Hui Tang, Baoliang Zhang, Can Zhang, Lina Gao, Jinliang Song, Dongsheng Zhang, Xue Wang, Xianlong Du, Guanhong Lei, Huihao Xia, Jianqiang Wang, Ping Huai, Xingtai Zhou

Journal of Materials Science· Volume 52· Issue 8
Publisher page

Abstract

The changes in both the crystallographic coefficient of thermal expansion (CCTE) and the coefficient of thermal expansion (CTE) of FLiNaK-infiltrated nuclear graphite were studied using in situ-heating X-ray diffraction analysis and horizontal push-rod dilatometry. It was found that, at temperatures lower than the melting point of FLiNaK, the CCTE of the d(002) spacing of graphite decreases with an increase in the weight of the graphite sample because of FLiNaK infiltration. On the other hand, the CTE of bulk graphite increases after molten salt infiltration. The CCTEs of the as-prepared FLiNaK salt, and the salt in the graphite pores were compared. The decrease in the CCTE of the FLiNaK salt after it had infiltrated into the graphite pores confirmed that interactions occur between the graphite and the salt. These interactions are probably induced by the difference in the CTEs of graphite and the solidified salt. Further, it is likely that the crystallization pressure also plays an important role here. Thus, both the causes need to be considered when using nuclear graphite in molten salt reactors.
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Research context

OpenAlex topics: Graphite, nuclear technology, radiation studies · Nuclear and radioactivity studies · Nuclear materials and radiation effects

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References (53)

Show source-provided references
1. Abram T, Ion S (2008) Generation-IV nuclear power: a review of the state of the science. Energy Policy 36:4323. doi: 10.1016/j.enpol.2008.09.05910.1016/j.enpol.2008.09.059 ↗
2. He Z, Gao L, Qi W et al (2015) Molten FLiNaK salt infiltration into degassed nuclear graphite under inert gas pressure. Carbon 84:511–518. doi: 10.1016/j.carbon.2014.12.04410.1016/j.carbon.2014.12.044 ↗
3. He Z, Gao L, Wang X et al (2014) Improvement of stacking order in graphite by molten fluoride salt infiltration. Carbon 72:304–311. doi: 10.1016/j.carbon.2014.02.01010.1016/j.carbon.2014.02.010 ↗
4. Etter T, Papakyriacou M, Schulz P, Uggowitzer PJ (2003) Physical properties of graphite/aluminium composites produced by gas pressure infiltration method. Carbon 41:1017–1024. doi: 10.1016/S0008-6223(02)00448-710.1016/S0008-6223(02)00448-7 ↗
5. Etter T, Kuebler J, Frey T, Schulz P, Löffler JF, Uggowitzer PJ (2004) Strength and fracture toughness of interpenetrating graphite/aluminium composites produced by the indirect squeeze casting process. Mater Sci Eng A 386:61–67. doi: 10.1016/j.msea.2004.06.06610.1016/j.msea.2004.06.066 ↗
6. Kelly BT (1981) Physics of graphite. Applied Science, London
7. Wen K, Marrow J, Marsden B (2008) Microcracks in nuclear graphite and highly oriented pyrolytic graphite (HOPG). J Nucl Mater 381:199–203. doi: 10.1016/j.jnucmat.2008.07.01210.1016/j.jnucmat.2008.07.012 ↗
8. Kane J, Karthik C, Butt DP, Windes WE, Ubic R (2011) Microstructural characterization and pore structure analysis of nuclear graphite. J Nucl Mater 415:189–197. doi: 10.1016/j.jnucmat.2011.05.05310.1016/j.jnucmat.2011.05.053 ↗
9. Berre C, Fok SL, Marsden BJ et al (2006) Numerical modelling of the effects of porosity changes on the mechanical properties of nuclear graphite. J Nucl Mater 352:1–5. doi: 10.1016/j.jnucmat.2006.02.03710.1016/j.jnucmat.2006.02.037 ↗
10. Berre C, Fok SL, Mummery PM et al (2008) Failure analysis of the effects of porosity in thermally oxidised nuclear graphite using finite element modelling. J Nucl Mater 381:1–8. doi: 10.1016/j.jnucmat.2008.07.02110.1016/j.jnucmat.2008.07.021 ↗
11. Chung DDL (2002) Review graphite. J Mater Sci 37:1475–1489. doi: 10.1023/A:101491530773810.1023/A:1014915307738 ↗
12. Boucher EA (1976) Review Porous materials structure, properties and capillary phenomena. J Mater Sci 11:1734–1750. doi: 10.1007/BF0073752910.1007/BF00737529 ↗
13. Israel R, Voytovych R, Protsenko P, Drevet B, Camel D, Eustathopoulos N (2009) Capillary interactions between molten silicon and porous graphite. J Mater Sci 45:2210–2217. doi: 10.1007/s10853-009-3889-610.1007/s10853-009-3889-6 ↗
14. Hall G, Marsden BJ, Fok SL, Smart J (2003) The relationship between irradiation induced dimensional change and the coefficient of thermal expansion: a modified Simmons relationship. Nucl Eng Des 222:319–330. doi: 10.1016/S0029-5493(03)00035-910.1016/S0029-5493(03)00035-9 ↗
15. Hall G, Marsden BJ, Fok SL (2006) The microstructural modelling of nuclear grade graphite. J Nucl Mater 353:12–18. doi: 10.1016/j.jnucmat.2006.02.08210.1016/j.jnucmat.2006.02.082 ↗
16. Bradford MR, Steer AG (2008) A structurally-based model of irradiated graphite properties. J Nucl Mater 381:137–144. doi: 10.1016/j.jnucmat.2008.07.04010.1016/j.jnucmat.2008.07.040 ↗
17. Kamali AR, Fray DJ (2014) Towards large scale preparation of carbon nanostructures in molten LiCl. Carbon 77:835–845. doi: 10.1016/j.carbon.2014.05.08910.1016/j.carbon.2014.05.089 ↗
18. Kamali AR, Divitini G, Schwandt C, Fray DJ (2012) Correlation between microstructure and thermokinetic characteristics of electrolytic carbon nanomaterials. Corros Sci 64:90–97. doi: 10.1016/j.corsci.2012.07.00710.1016/j.corsci.2012.07.007 ↗
19. Sure J, Ravi Shankar A, Ramya S, Kamachi Mudali U (2012) Molten salt corrosion of high density graphite and partially stabilized zirconia coated high density graphite in molten LiCl–KCl salt. Ceram Int 38:2803–2812. doi: 10.1016/j.ceramint.2011.11.05110.1016/j.ceramint.2011.11.051 ↗
20. Jacquier C, Chaussende D, Ferro G, Viala JC, Cauwet F, Monteil Y (2002) Study of the interaction between graphite and Al-Si melts for the growth of crystalline silicon carbide. J Mater Sci 37:3299–3306. doi: 10.1023/A:101614742027210.1023/A:1016147420272 ↗
21. M Steiger (2013) Crystal Growth and Phase Equilibriain Porous Materials. In: NATO Science for Peace and Security Series C: Environmental Security, 187. doi: 10.1007/978-94-007-7534-3_1610.1007/978-94-007-7534-3_16 ↗
22. Dei L, Mauro M, Baglioni P, Del Fa CM, Fratini F (1999) Growth of crystal phases in porous media. Langmuir 15:8915–8922. doi: 10.1021/la981074f10.1021/la981074f ↗
23. Scherer GW (1999) Crystallization in pores. Cem Concr Res 29:1347–1358. doi: 10.1016/S0008-8846(99)00002-210.1016/S0008-8846(99)00002-2 ↗
24. Scherer GW (2004) Stress from crystallization of salt. Cem Concr Res 34:1613–1624. doi: 10.1016/j.cemconres.2003.12.03410.1016/j.cemconres.2003.12.034 ↗
25. Steiger M (2005) Crystal growth in porous materials—I: the crystallization pressure of large crystals. J Cryst Growth 282:455–469. doi: 10.1016/j.jcrysgro.2005.05.00710.1016/j.jcrysgro.2005.05.007 ↗
26. Zhao J-G, Li K-Z, Li H-J, Wang C, Zhai Y-Q (2006) The thermal expansion of carbon/carbon composites from room temperature to 1400 °C. J Mater Sci 41:8356–8358. doi: 10.1007/s10853-006-1073-910.1007/s10853-006-1073-9 ↗
27. Shiraishi M, Kobayashi K, Toyoda S (1972) Thermal expansion of interlayer spacing and thermal vibrational displacement of carbon atoms in petroleum coke. J Mater Sci 7:1229–1232. doi: 10.1007/BF0055068610.1007/BF00550686 ↗
28. A E228-11 (2011) ASTM International, West Conshohocken
29. Chi S-H, Kim G-C (2008) Comparison of the oxidation rate and degree of graphitization of selected IG and NBG nuclear graphite grades. J Nucl Mater 381:9–14. doi: 10.1016/j.jnucmat.2008.07.02710.1016/j.jnucmat.2008.07.027 ↗
30. Tsang DKL, Marsden BJ, Fok SL, Hall G (2005) Graphite thermal expansion relationship for different temperature ranges. Carbon 43:2902–2906. doi: 10.1016/j.carbon.2005.06.00910.1016/j.carbon.2005.06.009 ↗
31. Morgan WC (1972) Thermal expansion coefficients of graphite crystals. Carbon 10:73–79. doi: 10.1016/0008-6223(72)90011-510.1016/0008-6223(72)90011-5 ↗
32. Schelling PK, Keblinski P (2003) Thermal expansion of carbon structures. Phys Rev B 68:035425. doi: 10.1103/PhysRevB.68.03542510.1103/PhysRevB.68.035425 ↗
33. Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385–388. doi: 10.1126/science.115799610.1126/science.1157996 ↗
34. Jiang J-W, Wang J-S, Li B (2009) Young’s modulus of graphene: a molecular dynamics study. Phys Rev B 80:113405. doi: 10.1103/PhysRevB.80.11340510.1103/PhysRevB.80.113405 ↗
35. Heintz EA (1990) The measurement of the coefficient of thermal expansion of graphite artefacts. Carbon 28:233. doi: 10.1016/0008-6223(90)90119-J10.1016/0008-6223(90)90119-J ↗
36. Nelson J, Riley D (1945) The thermal expansion of graphite from 15 °c. to 800 °c.: part I. Experimental. Proc Phys Soc 57:477. doi: 10.1088/0959-5309/57/6/30310.1088/0959-5309/57/6/303 ↗
37. Kellett E, Richards B (1964) The thermal expansion of graphite within the layer planes. J Nucl Mater 12:184. doi: 10.1016/0022-3115(64)90139-410.1016/0022-3115(64)90139-4 ↗
38. Mason I, Knibbs R (1964) The thermal expansion of polycrystalline carbon and graphite form—196 °C to 2000 °C. J Nucl Energy Parts A/B. React Sci Technol 18:311. doi: 10.1016/0368-3230(64)90064-310.1016/0368-3230(64)90064-3 ↗
39. Hacker PJ, Neighbour GB, McEnaney B (2000) The coefficient of thermal expansion of nuclear graphite with increasing thermal oxidation. J Phys D Appl Phys 33:991. doi: 10.1088/0022-3727/33/8/31610.1088/0022-3727/33/8/316 ↗
40. Wang T-C, Fan T-X, Zhang D, Zhang G-D (2006) Thermal Expansions and Mechanical Properties of AlC and Al(SiC + C) Composites Based on Wood Templates. Mater Trans 47:2576. doi: 10.2320/matertrans.47.257610.2320/matertrans.47.2576 ↗
41. Tianchi W, Tongxiang F, Di Z, Tianle Z, Guoding Z, Dangsheng X (2010) Microstructures and thermal properties of aluminum matrix composites based on wood templates. J Porous Mater 17:289. doi: 10.1007/s10934-009-9291-610.1007/s10934-009-9291-6 ↗
42. Zhang Q, Wu G, Chen G, Jiang L, Luan B (2003) The thermal expansion and mechanical properties of high reinforcement content SiCp/Al composites fabricated by squeeze casting technology. Compos A Appl Sci Manuf 34:1023. doi: 10.1016/S1359-835X(03)00253-710.1016/S1359-835X(03)00253-7 ↗
43. Fei WD, Wang LD (2004) Thermal expansion behavior and thermal mismatch stress of aluminum matrix composite reinforced by β-eucryptite particle and aluminum borate whisker. Mater Chem Phys 85:450. doi: 10.1016/j.matchemphys.2004.02.00410.1016/j.matchemphys.2004.02.004 ↗
44. Elomari S, Skibo MD, Sundarrajan A, Richards H (1998) Thermal expansion behavior of particulate metal-matrix composites. Compos Sci Technol 58:369–376. doi: 10.1016/S0266-3538(97)00124-310.1016/S0266-3538(97)00124-3 ↗
45. Wassell JFMW (1995) Thermal expansion of composites. J Mater Sci 6:624–629. doi: 10.1007/BF0012344110.1007/BF00123441 ↗
46. Zhao B, Pei Y, Zhang L, Gong S, Zhao L-D (2016) Thermal and mechanical properties of Yb&Mg co-doped InFeZnO4. J Alloy Compd 684:34. doi: 10.1016/j.jallcom.2016.05.06410.1016/j.jallcom.2016.05.064 ↗
47. Ruan Y, Li L, Gu Q, Zhou K, Yan N, Wei B (2016) Thermal expansion and thermal diffusivity properties of Co-Si solid solutions and intermetallic compounds. J Chem Thermodyn 102:1–8. doi: 10.1016/j.jct.2016.06.02910.1016/j.jct.2016.06.029 ↗
48. Withers PJ, Preuss M, Steuwer A, Pang JWL (2007) Methods for obtaining the strain-free lattice parameter when using diffraction to determine residual stress. J Appl Crystallogr 40:891. doi: 10.1107/s002188980703026910.1107/s0021889807030269 ↗
49. Carcia PF, McLean RS, Reilly MH, Nunes G (2003) Transparent ZnO thin-film transistor fabricated by rf magnetron sputtering. Appl Phys Lett 82:1117. doi: 10.1063/1.155399710.1063/1.1553997 ↗
50. Windisch D, Becker P (1988) Lattice distortions induced by carbon in silicon. Philos Mag A 58:435. doi: 10.1080/0141861880820993610.1080/01418618808209936 ↗
51. Holloway H (1990) X-ray interferometry and its application to determination of layer thickness and strain in quantum-well structures. J Appl Phys 67:6229–6236. doi: 10.1063/1.34518910.1063/1.345189 ↗
52. Mounet N, Marzari N (2005) First-principles determination of the structural, vibrational and thermodynamic properties of diamond, graphite, and derivatives. Phys Rev B 71:205214. doi: 10.1103/PhysRevB.71.20521410.1103/PhysRevB.71.205214 ↗
53. Delhaes P (2000) Graphite and precursors. CRC Press, Boca Raton10.1201/9781482296921 ↗