Magnetism and white-light-emission bifunctionality simultaneously assembled into flexible Janus nanofiber via electrospinning
Source abstract
Abstract
New-typed magnetic and color-tunable bifunctional Janus nanofibers have been successfully fabricated by electrospinning technology using a specially designed parallel spinneret. The Janus nanofiber consists of two strands of nanofibers assembled side-by-side, one strand nanofiber has tuned magnetism and the other one possesses color-tunable photoluminescence. The Janus nanofibers possess superior magnetic and luminescent properties due to their special nanostructure. Tunable colors from bluish green to orange can be realized in the flexible Janus nanofibers by varying the content of Eu(BA)3phen complex, and furthermore, white-light-emitting flexible Janus nanofibers are achieved using rare-earth complexes as luminescent centers. In particular, it is the first time to report the influence of Fe3O4 nanoparticles on the fluorescent color of the magnetic-fluorescent nanomaterials. The synthesized products have potential applications in color displays, nano-bio-label materials, and anti-counterfeit materials.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Quantum Dots Synthesis And Properties · Nanocluster Synthesis and Applications · Advanced Nanomaterials in Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Xie RJ, Hirosaki N, Suehiro T, Xu FF, Mitomo M (2006) A simple, efficient synthetic route to Sr2Si5N8:Eu2+-based red phosphors for white light-emitting diodes. Chem Mater 18:5578–558310.1021/cm061010n ↗
2. Lorenzi R, Paleari A, Golubev NV, Ignat’eva ES, Sigaev VN, Niederberger M, Lauria A (2015) Non-aqueous sol–gel synthesis of hybrid rare-earth-doped γ-Ga2O3 nanoparticles with multiple organic–inorganic-ionic light-emission features. J Mater Chem C 3:41–4510.1039/C4TC02118E ↗
3. Das S, Yang CY, Lin HC, Lu CH (2014) Structural and luminescence properties of tunable white-emitting Sr0.5Ca0.5Al2O4: Eu2+, Dy3+ for UV-excited white-LEDs. RSC Adv 4:64956–6496610.1039/C4RA09618E ↗
4. Guan HX, Liu GX, Wang JX, Dong XT, Yu WS (2014) Multicolor tunable luminescence and paramagnetic properties of NaGdF4:Tb3+/Sm3+ multifunctional nanomaterials. Dalton Trans 43:10801–1080810.1039/c4dt00158c ↗
5. Yun YJ, Lim HJ, Park JS, Wu M, Jung HK, Choi S (2015) Temperature variable luminescence and color tuning of Eu2+/Mn2+-codoped strontium magnesium phosphates as promising red-emitting phosphors for light emitting diodes. Dalton Trans 44:338–34410.1039/C4DT02457E ↗
6. Yang DM, Li GG, Kang XJ, Cheng ZY, Ma PA, Peng C, Lian HZ, Li CX, Lin J (2012) Room temperature synthesis of hydrophilic Ln3+-doped KGdF4 (Ln = Ce, Eu, Tb, Dy) nanoparticles with controllable size: energy transfer, size-dependent and color-tunable luminescence properties. Nanoscale 4:3450–345910.1039/c2nr30338h ↗
7. Li RQ, Li LL, Zi WW, Zhang JJ, Liu L, Zou LC, Gan SC (2015) Morphology control and multicolor-tunable luminescence of YOF:Ln3+ (Ln = Eu, Tb, Dy, Tm) nano-/microcrystals. N J Chem. 39:115–12110.1039/C4NJ01136H ↗
8. Liu Y, Liu GX, Wang JX, Dong XT, Yu WS (2014) Single-component and warm-white-emitting phosphor NaGd(WO4)2:Tm3+, Dy3+, Eu3+: synthesis, luminescence, energy transfer, and tunable color. Inorg Chem 53:11457–1146610.1021/ic501284y ↗
9. Zhou XJ, Ma QL, Dong XT, Wang JX, Yu WS, Liu GX (2015) Dy3+ and Eu3+ complexes co-doped flexible composite nanofibers to achieve tunable fluorescent color. J Mater Sci: Mater Electron. 26:3112–3118
10. Hou ZY, Yang PP, Lian HZ, Wang LL, Zhang CM, Li CX, Chai RT, Cheng ZY (2009) Multifunctional hydroxyapatite nanofibers and microbelts as drug carriers. Chem Eur J 15:6973–698210.1002/chem.200900269 ↗
11. Guo C, Zhang D, Wang FS, Jin GX (2005) Nanofibers of polyethylene produced by SBA-15 supported zirconium catalyst [N-(3-tert-butylsalicylidene)-4′-allyloxylanilinato]2Zr(IV)Cl2. J Catal 234:356–36310.1016/j.jcat.2005.06.002 ↗
12. Chen Y, Chen HR, Zhang SJ, Chen F, Zhang LX, Zhang JM, Zhu M, Wu HX, Guo LM, Feng JW, Shi JL (2011) Multifunctional mesoporous nanoellipsoids for biological bimodal imaging and magnetically targeted delivery of anticancer drugs. Adv Funct Mater 21:270–27810.1002/adfm.201001495 ↗
13. Medintz IL, Uyeda HT, Goldman ER, Mattoussi H (2005) Quantum dot bioconjugates for imaging, labelling and sensing. Nat Mater 4:435–44610.1038/nmat1390 ↗
14. Ma QL, Wang JX, Dong XT, Yu WS, Liu GX, Xu J (2012) Electrospinning preparation and properties of magnetic-photoluminescent bifunctional coaxial nanofibers. J Mater Chem 22:14438–1444210.1039/c2jm32043f ↗
15. Ma QL, Wang JX, Dong XT, Yu WS, Liu GX (2014) Fabrication of magnetic-fluorescent bifunctional flexible coaxial nanobelts by electrospinning using a modified coaxial spinneret. ChemPlusChem 79:290–29710.1002/cplu.201300262 ↗
16. Sahu S, Sinha N, Bhutia SK, Majhic M, Mohapatra S (2014) Luminescent magnetic hollow mesoporous silica nanotheranostics for camptothecin delivery and multimodal imaging. J Mater Chem B 2:3799–380810.1039/C3TB21669A ↗
17. Gai SL, Yang PP, Li CX, Wang WX, Dai YL, Niu N, Lin J (2010) Synthesis of magnetic, up-conversion luminescent, and mesoporous core–shell-structured nanocomposites as drug carriers. Adv Funct Mater 20:1166–117210.1002/adfm.200902274 ↗
18. Wang W, Zou M, Chen K (2010) Novel Fe3O4@YPO4: Re (Re = Tb, Eu) multifunctional magnetic-fluorescent hybrid spheres for biomedical applications. Chem Commun 46:5100–510210.1039/c0cc00262c ↗
19. Feng J, Song SY, Deng RP, Fan WQ, Zhang HJ (2010) Novel multifunctional nanocomposites: magnetic mesoporous silica nanospheres covalently bonded with near-infrared luminescent lanthanide complexes. Langmuir 26:3596–360010.1021/la903008z ↗
20. Yan K, Li H, Wang X, Yi CF, Zhang QY, Xu ZS, Xu HB, Whittaker AK (2014) Self-assembled magnetic luminescent hybrid micelles containing rare earth Eu for dual-modality MR and optical imaging. J Mater Chem B 2:546–55510.1039/C3TB21381A ↗
21. Wang HG, Li YX, Sun L, Li YC, Wang W, Wang S, Xu SF, Yang QB (2010) Electrospun novel bifunctional magnetic-photoluminescent nanofibers based on Fe2O3 nanoparticles and europium complex. J Colloid Interface Sci 350:396–40110.1016/j.jcis.2010.06.068 ↗
22. Ma QL, Yu WS, Dong XT, Wang JX, Liu GX, Xu J (2013) Electrospinning fabrication and properties of Fe3O4/Eu(BA)3phen/PMMA magnetic–photoluminescent bifunctional composite nanoribbons. Opt Mater 35:526–53010.1016/j.optmat.2012.10.004 ↗
23. Moghani MM, Khomami B (2013) Self-assembly of spherical Janus particles in electrolytes. Soft Matter 9:4815–482110.1039/c3sm27345h ↗
24. Lv N, Ma QL, Dong XT, Wang JX, Yu WS, Liu GX (2014) Flexible Janus nanofibers: facile electrospinning construction and enhanced luminescent–electrical–magnetic trifunctionality. ChemPlusChem 79:690–69710.1002/cplu.201300404 ↗
25. Xi X, Wang JX, Dong XT, Ma QL, Yu WS, Liu GX (2014) Flexible Janus nanofiber: a new tactics to realize tunable and enhanced magnetic-luminescent bifunction. Chem Eng J 254:259–26710.1016/j.cej.2014.05.142 ↗
26. Bi F, Dong XT, Wang JX, Liu GX (2015) Tuned magnetism–luminescence bifunctionality simultaneously assembled into flexible Janus nanofiber. RSC Adv 5:12571–1257710.1039/C4RA10022K ↗
27. Nam SH, Shim HS, Kim YS, Dar MA, Kim JG, Kim WB (2010) Ag or Au nanoparticle-embedded one-dimensional composite TiO2 nanofibers prepared via electrospinning for use in lithium-ion batteries. ACS Appl Mater Interfaces 2:2046–205210.1021/am100319u ↗
28. Teh PF, Sharma Y, Pramana SS, Srinivasan M (2011) Nanoweb anodes composed of one-dimensional, high aspect ratio, size tunable electrospun ZnFe2O4 nanofibers for lithium ion batteries. J Mater Chem 21:14999–1500810.1039/c1jm12088c ↗
29. Choi SJ, Choi CY, Kim SJ, Cho HJ, Jeon S, Kim ID (2015) Facile synthesis of hierarchical porous WO3 nanofibers having 1D nanoneedles and their functionalization with non-oxidized graphene flakes for selective detection of acetone molecules. RSC Adv 5:7584–758810.1039/C4RA13791D ↗
30. Hou ZY, Li GG, Lian HZ, Lin J (2012) One-dimensional luminescent materials derived from the electrospinning process: preparation, characteristics and application. J Mater Chem 22:5254–527610.1039/c2jm15638e ↗
31. Strain IN, Wu Q, Pourrahimi AM, Hedenqvist MS, Olsson RT, Andersson RL (2015) Electrospinning of recycled PET to generate tough mesomorphic fibre membranes for smoke filtration. J Mater Chem A 3:1632–164010.1039/C4TA06191H ↗
32. Wang XY, Drew C, Lee SH, Senecal KJ, Kumar J, Samuelson LA (2002) Electrospun nanofibrous membranes for highly sensitive optical sensors. Nano Lett 2:1273–127510.1021/nl020216u ↗
33. Baker SC, Atkin N, Gunning PA, Granville N, Wilson K, Wilson D, Southgate J (2006) Characterisation of electrospun polystyrene scaffolds for three-dimensional in vitro biological studies. Biomaterials 27:3136–314610.1016/j.biomaterials.2006.01.026 ↗
34. Chen SL, Hou HQ, Harnisch F, Patil SA, Martinez AAC, Agarwal S, Zhang YY, Ray SS, Yarin AL, Greiner A, Schroder U (2011) Electrospun and solution blown three-dimensional carbon fiber nonwovens for application as electrodes in microbial fuel cells. Energy Environ Sci 4:1417–142110.1039/c0ee00446d ↗
35. Sridhar R, Lakshminarayanan R, Madhaiyan K, Barathi VA, Lim KHC, Ramakrishna S (2015) Electrosprayed nanoparticles and electrospun nanofibers based on natural materials: applications in tissue regeneration, drug delivery and pharmaceuticals. Chem Soc Rev 44:790–81410.1039/C4CS00226A ↗
36. Kumar PS, Sundaramurthy J, Sundarrajan S, Babu VJ, Singh G, Allakhverdiev SI, Ramakrishna S (2014) Hierarchical electrospun nanofibers for energy harvesting, production and environmental remediation. Energy Environ Sci. 7:3192–322210.1039/C4EE00612G ↗
37. Panthi G, Park SJ, Kim TW, Chung HJ, Hong ST, Park M, Kim HY (2015) Electrospun composite nanofibers of polyacrylonitrile and Ag2CO3 nanoparticles for visible light photocatalysis and antibacterial applications. J Mater Sci 50:4477–4485. doi: 10.1007/s10853-015-8995-z10.1007/s10853-015-8995-z ↗