Structural and spectroscopic effects of Ag–Eu3+ codoping of TeO2–PbO glass ceramics
Source abstract
Abstract
Structural and spectroscopic behavior of TeO2–PbO–Eu2O3 glass ceramics containing small amounts of Ag2O (0.5 mol%) or metallic Ag nanoparticles (AgNPs) (0.33 mol%) have been studied by varying their Eu2O3 content (0–10 mol%). The structural behavior of these samples was investigated by means of X-ray diffraction (XRD), SEM microscopy, and Fourier transform infrared (FTIR) spectroscopy. The average unit-cell parameters, crystallites size, and the quantitative ratio of the crystallographic phases in the samples were evaluated based on XRD data. FTIR spectroscopy data revealed that the TeO3 and TeO4 are the main structural units of these glass ceramics and their ratio, TeO3/TeO4, changes as function of the europium oxide content and the codoping of the samples. Luminescence spectroscopy measurements evidenced the important peaks located at 438, 550, and 722 nm due to the Pb2+ ions and at 589 and 611 nm due to the Eu3+ ions present in the studied samples. The presence of AgNPs in the studied glass ceramics determines a considerable enhancement of the luminescence bands of Eu3+ ions from 589 and 611 nm.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Lanthanide and Transition Metal Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (44)
Show source-provided references
1. Naranjo LP, De Araujo CB, Malta OL, Cruz PAS, Kassab LRP (2005) Enhancement of Pr3+ luminescence in PbO–GeO2 glasses containing silver nanoparticles. Appl Phys Lett 87:24191410.1063/1.2143135 ↗
2. Lourenco SA, Dantas NO, Serqueira EO, Ayta WEF, Andrade AA, Filadelpho MC, Sampaio JA, Bell MJV, Pereira da Silva MA (2011) Eu3+ photoluminescence enhancement due to thermal energy transfer in Eu2O3-doped SiO2–B2O3–PbO2 glasses system. J Lumin 131:850–85510.1016/j.jlumin.2010.11.028 ↗
3. Tian Y, Chen B, Hua R, Sun J, Zhong H, Zheng Y, Yu T, Huang L, Yu H (2011) Optical transition, electron-phonon coupling and fluorescent quenching of La2(MoO4)3: Eu3+ phosphor. J Appl Phys 109:05351110.1063/1.3551584 ↗
4. Rodriquez-Mendoza R, Martin IR, Rodriquez VD (2003) Optical spectroscopy analysis of the Eu3+ ions local structure in calcium diborate glasses. J Non-Cryst Solids 319:200–21610.1016/S0022-3093(02)01914-2 ↗
5. Lavin V, Babu P, Jayasankar CK, Martin IR, Rodriquez VD (2001) On the local structure of Eu3+ ions in oxyfluoride glasses. Comparison with fluoride and oxide glasses. J Chem Phys 115:1093510.1063/1.1420731 ↗
6. Chung W, Heo J (2001) Room temperature persistent spectral hole burning in X-ray irradiated Eu3+-doped borate glasses. Appl Phys Lett 79:32610.1063/1.1385346 ↗
7. Kozuge T, Benino Y, Dimitrov V, Sato R, Komatsu T (1998) Thermal stability and heat capacity changes at the glass transition in K2O–WO3–TeO2 glasses. J Non-Cryst Solids 242:154–16410.1016/S0022-3093(98)00800-X ↗
8. Amorin HT, Vermelho MVD, Gouveia-Neto AS, Cassanjes FC, Ribeiro SJ, Messaddeq YJ (2002) Energy upconversion luminescence in neodymium-doped tellurite glass. J Alloys Compd 346:282–28410.1016/S0925-8388(02)00513-3 ↗
9. Duverger C, Bouazaoui M, Turrell SJ (1997) Raman spectroscopic investigations of the effect of the doping metal on the structure of binary tellurium-oxide glasses. J Non-Cryst Solids 220:169–17710.1016/S0022-3093(97)00317-7 ↗
10. Yachkind AK, Ovcharenko NV (1968) High refractive index and magneto–optical glasses in the systems TeO2–WO3–Bi2O3 and TeO2–WO3–PbO. J Non-Cryst Solids 291:121–126
11. Nasu H, Ibara Y, Kabodera K (1989) Optical third-harmonic generation from some high-index glasses. J Non-Cryst Solids 110:229–23410.1016/0022-3093(89)90263-9 ↗
12. Baia L, Bolboaca M, Kiefer W, Yousef ES, Russel C, Breitbarth FW, Mayerhofer TG, Popp J (2004) Spectroscopic studies on the structure of vanadium tellurite glasses. Phys Chem Glasses 45(3):178–182
13. Silva MAP, Messaddeq Y, Ribeiro SJL, Poulain M, Villain F, Briois V (2001) Structural studies on TeO2–PbO glasses. J Phys Chem Solids 62:1055–106010.1016/S0022-3697(00)00278-X ↗
14. Rada S, Culea E, Rada M, Pascuta P, Maties V (2009) Structural and electronic properties of tellurite glasses.J Mater Sci 44:3235–3240 doi: 10.1007/s10853-011-5637-y10.1007/s10853-009-3433-8 ↗
15. Rada S, Culea M, Rada M, Rusu T, Culea E (2010) Competitive role of the tellurium and gadolinium cations in structural aspects of the gadolinium–phosphate–tellurate glasses. J Alloys Compd 490:270–27610.1016/j.jallcom.2009.09.174 ↗
16. Dehelean A, Rada S, Kacso I, Culea E (2013) UV–Vis spectroscopic and DSC investigations of europium doped tellurite glasses obtained by sol–gel synthesis. J Phys Chem Solids 74:1235–123910.1016/j.jpcs.2013.03.022 ↗
17. Sekiya T, Mochida M, Ohtsuka A, Tonokawa M (1992) Raman spectra of MO1/2–TeO2 (M = Li, Na, K, Rb, Cs and Tl) glasses. J Non-Cryst Solids 144:12810.1016/S0022-3093(05)80393-X ↗
18. Kumar VR, Veeraiah N (1997) Infrared spectral investigations on ZnF2–PbO–TeO2 glasses. J Mater Sci Lett 16:1816–181810.1023/A:1018516718244 ↗
19. Kassab LRP, Bomfim FA, Martinelli JR, Wetter NU, Neto JJ, de Cid Araujo B (2009) Energy transfer and frequency upconversion in Yb 3+–Er3+-doped PbO-GeO2 glass containing silver nanoparticles. Appl Phys B 94:239–24210.1007/s00340-008-3249-2 ↗
20. da Silva DM, Kassab LRP, Martinelli JR, de Cid Araujo B (2010) Production and characterization of RF-sputtered PbO–GeO2 amorphous thin films containing silver and gold nanoparticles. J Non-Cryst Solids 356:2602–260510.1016/j.jnoncrysol.2010.06.079 ↗
21. de Cid Araújo B, Luciana Kassab RP, Renata Kobayashi A, Kobayashi Luz, Luz Patrícia Naranjo, Petrus Santa Cruz A (2006) Luminescence enhancement of Pb2+ ions in TeO2–PbO–GeO2 glasses containing silver nanostructures. J Appl Phys 99:12352210.1063/1.2208288 ↗
22. Guo H, Jing J, Li F, Li H, Zhang J (2011) Origin of white luminescence in Ag–Eu Co-doped oxyfluoride glasses. Electrochem Soc 158(6):165–16810.1149/1.3568950 ↗
23. Pop M, Borodi G, Zolde A, Mocuta M, Simon S (2000) Formation of layered structure on bismuth-borate glass surface. Mater Lett 42:71–7410.1016/S0167-577X(99)00161-5 ↗
24. Borodi G, Bratu I, Simion S (2007) Formation of layered structure on bismuth-borate glass surface. Mater Lett 61:4715–471710.1016/j.matlet.2007.03.015 ↗
25. Klug HP, Alexander LE (1974) X-ray diffraction procedures, 2nd edn. Wiley, Hoboken, pp 687–703
26. Pascuta P, Borodi G, Popa A, Dan V, Culea E (2010) The structural role of manganese ions in some zinc phosphate glasses and glass ceramics. Mater Chem Phys 123:767–77110.1016/j.matchemphys.2010.05.056 ↗
27. Pascuta P, Borodi G, Jumate N, Vida-Simiti I, Dan V, Culea E (2010) The structural role of manganese ions in some zinc phosphate glasses and glass ceramics. J Alloy Compd 504:479–48310.1016/j.jallcom.2010.05.147 ↗
28. Pascuta P, Vladescu A, Borodi G, Culea E, Tetean R (2011) Structural and magnetic properties of zinc ferrite incorporated in amorphous matrix. Ceram Int 37:3343–334910.1016/j.ceramint.2011.05.134 ↗
29. Accelrys Software Inc., Materials Studio, Release 5.5, 2010; see a detailed description at: http://accelrys.com/product/material-studio/index.html . Accessed 12 Dec 2013
30. Mohamed EA, Ahmad F, Aly KA (2012) Effect of lithium addition on thermal and optical properties of zinc–tellurite glass. J Alloys Compd 538:230–23610.1016/j.jallcom.2012.05.044 ↗
31. Bosca M, Pop L, Borodi G, Pascuta P, Culea E (2009) XRD and FTIR structural investigations of erbium-doped bismuth-lead-silver glasses and glass ceramics. J Alloys Compd 479:579–58210.1016/j.jallcom.2009.01.001 ↗
32. Rada S, Dehelean A, Culea E (2011) FTIR and UV–VIS spectroscopy investigations on the structure of the europium-lead-tellurate glasses. J Non-Cryst Solids 357:3070–307310.1016/j.jnoncrysol.2011.04.013 ↗
33. Culea E (2011) Structural and magnetic behaviour of lead-bismuthate glasses containing rare earth ions. J Non-Cryst Solids 357:50–5410.1016/j.jnoncrysol.2010.09.013 ↗
34. Mansour E (2012) FTIR spectra of pseudo-binary sodium borate glasses containing TeO2. J Mol Struct 1014:1–610.1016/j.molstruc.2012.01.034 ↗
35. Çelikbilek M, Ersundu AE, Aydin S (2013) Preparation and characterization of TeO2–WO3–Li2O glasses. J Non-Cryst Solids 378:247–25310.1016/j.jnoncrysol.2013.07.020 ↗
36. Kishimoto Y, Zhang X, Hayakawa T, Nogami M (2009) Blue light emission from Eu2+ ions in sol–gel-derived Al2O3–SiO2 glasses. J Lumin 129:1055–105910.1016/j.jlumin.2009.04.031 ↗
37. Almeida R, da Silva DM, Kassab LRP, Cid Araújo B (2008) Eu3+ luminescence in tellurite glasses with gold nanostructures. Opt Commun 281:108–11210.1016/j.optcom.2007.08.072 ↗
38. Vijaya N, Jayasankar CK (2013) Structural and spectroscopic properties of Eu3+-doped zinc fluorophosphate glasses. J Mol Struct 1036:42–5010.1016/j.molstruc.2012.09.037 ↗
39. Pop L, Ristoiu T, Dempsey N, Culea M, Culea E (2006) Low-temperature study of magnetic behavior of europium in lead-bismuthate glasses. Mod Phys Lett B 20:1957–196210.1142/S0217984906012328 ↗
40. Simon S, Pop R, Simon V, Coldea M (2003) Structural and magnetic properties of lead-bismuthate oxide glasses containing S-state paramagnetic ions. J Non-Cryst Solids 331:1–1010.1016/j.jnoncrysol.2003.08.079 ↗
41. Burzo E, Ardelean I, Ursu I (1996) Magnetic properties of xEu2O3 (1−x) [3B2O3 PbO] glasses. Mater Lett 26:103–10510.1016/0167-577X(95)00194-8 ↗
42. Guo H, Wang XF, Chen J, Li F (2010) UV light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses. Opt Express 18:18900–1890510.1364/OE.18.018900 ↗
43. Eichelbaum M, Rademann K (2009) Plasmonic enhancement or energy transfer? On the luminescence of gold-, gilver-, and lanthanide-doped silicate glasses and its potential for light-emitting device. Adv Funct Mater 19:2045–205210.1002/adfm.200801892 ↗
44. Eichelbaum M, Rademann K, Hoell A, Tatchev DM, Weigel W, Stößer R, Pacchioni G (2008) Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses. Nanotechnology 19:13570110.1088/0957-4484/19/13/135701 ↗