The influence of solvent quality on the mechanical properties of thin cast isotactic poly(methyl methacrylate) coatings

Thin coatings of isotactic poly(methyl methacrylate) were cast on glass from solvents of different quality, which was expected to result in different molecular morphologies. The elastic moduli and hardness of the coatings were measured using a nanoindenter. The aim was to examine the viability of this technique for assessing the influence of the morphology on the mechanical properties. The interpretation of the data was complicated by both the influence of the hard substrate and possibly by the plasticising effect of retained solvent in the bulk. Nevertheless, it was reasonable to conclude that a coating cast from a good solvent was stiffer and harder than that from a poor solvent. This is consistent with previous frictional and spectroscopic studies.