journal article·2019-09-24

Significantly Improved Breakdown Strength and Energy Density in Polymer Composites with High Filler Loading by Constructing Isoelectronic Traps

Shanjun Ding, Yingming Kong

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Abstract

High-performance dielectric polymer materials consisting of ZnS:O nanoparticles (ZSO NPs) with isoelectronic traps and polyvinylidene fluoride (PVDF) were prepared by a solution-casting method. Compared with pure PVDF and PVDF/ZnS composites, the energy density and breakdown strength for polymer nanocomposites with high filler loading are obviously enhanced. By analyzing the physical model we built, we propose that the density and movement of charges are regulated by isoelectronic traps, resulting in increased insulation and a changed mircoelectric field distribution. In addition, this filling strategy also solves the problem of charge accumulation in polymer nanocomposites.
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Research context

OpenAlex topics: Dielectric materials and actuators · Advanced Sensor and Energy Harvesting Materials · High voltage insulation and dielectric phenomena

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Affiliations

School of Mechatronical Engineering, Beijing Institute of Technology, Beijing 100081, China

Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

State Key Laboratory of Supramolecular Structures and Materials, Jilin University, Changchun 130012, China

Funding

National Natural Science Foundation of China · Shenzhen Key Fundamental Research Program

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