Fabrication and characterization of PVA–cellulose and PVA–clay composites: structural, mechanical, and in vitro degradation studies
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Natural Fiber Reinforced Composites · Advanced Cellulose Research Studies · Nanocomposite Films for Food Packaging
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (75)
Show source-provided references
1. Ye M, Mohanty P, Ghosh G (2014) Morphology and properties of poly vinyl alcohol (PVA) scaffolds: impact of process variables. Mater Sci Eng C 42:289–294. https://doi.org/10.1016/j.msec.2014.05.02910.1016/j.msec.2014.05.029 ↗
2. Echeverria Molina MI, Malollari KG, Komvopoulos K (2021) Design challenges in polymeric scaffolds for tissue engineering. Front Bioeng Biotechnol. https://doi.org/10.3389/fbioe.2021.61714110.3389/fbioe.2021.617141 ↗
3. Teixeira MA, Amorim MTP, Felgueiras HP (2020) Poly(vinyl alcohol)-based nanofibrous electrospun scaffolds for tissue engineering applications. Polymers. https://doi.org/10.3390/polym1201000710.3390/polym12010007 ↗
4. Bitaraf P, Asefnejad A, Nemati NH (2022) Fabrication of polyvinyl alcohol-graphene nanosheet nanocomposite loading of omega-3 fatty acids for ceramic engineering. Iran J Basic Med Sci 25:330–340. https://doi.org/10.22038/ijbms.2022.62366.1379610.22038/ijbms.2022.62366.13796 ↗
5. Nathan KG, Genasan K, Kamarul T (2023) Polyvinyl alcohol-chitosan scaffold for tissue engineering and regenerative medicine application: a review. Mar Drugs. https://doi.org/10.3390/md2105030410.3390/md21050304 ↗
6. Shuai C, Feng P, Gao C et al (2015) Graphene oxide reinforced poly(vinyl alcohol): nanocomposite scaffolds for tissue engineering applications. RSC Adv 5:25416–25423. https://doi.org/10.1039/c4ra16702c10.1039/c4ra16702c ↗
7. Wang C, Huang W, Zhou Y et al (2020) 3D printing of bone tissue engineering scaffolds. Bioact Mater 5:82–91. https://doi.org/10.1016/j.bioactmat.2020.01.00410.1016/j.bioactmat.2020.01.004 ↗
8. Hu Q, Lu R, Liu S et al (2022) 3D printing GelMA/PVA interpenetrating polymer networks scaffolds mediated with CuO nanoparticles for angiogenesis. Macromol Biosci. https://doi.org/10.1002/mabi.20220020810.1002/mabi.202200208 ↗
9. Paul AK, Chakraborty G, Borkotoky SS, Prasad A (2025) Degradation studies of bioabsorbable polymeric composites. Bioabsorbable Polym Drug Carriers Fixation Devices. pp 105–12810.1201/9781003569817-5 ↗
10. Wang X, Su M, Liu C et al (2020) Poly (Vinyl alcohol)/graphene nanocomposite hydrogel scaffolds for control of cell adhesion. J Renew Mater 8:89–99. https://doi.org/10.32604/jrm.2020.0849310.32604/jrm.2020.08493 ↗
11. Jadbabaei S, Kolahdoozan M, Naeimi F, Ebadi-Dehaghani H (2021) Preparation and characterization of sodium alginate-PVA polymeric scaffolds by electrospinning method for skin tissue engineering applications. RSC Adv 11:30674–30688. https://doi.org/10.1039/d1ra04176b10.1039/d1ra04176b ↗
12. Sharma VK, Chakraborty G, Narendren S, Katiyar V (2023) Fabrication and characterization of conductive electrospun nanofiber mats of carbon nanofiber/poly(vinyl alcohol)/poly(lactic acid) ternary nanocomposites for flexible electronics applications. Mater Adv 4:6294–6303. https://doi.org/10.1039/d3ma00670k10.1039/d3ma00670k ↗
13. Girish B, Rakshith GR, Paul AK et al (2024) Hydrolytic and soil degradation of cellulosic material (paper): optimization of parameters using ANN and RSM. Polym Bull 81:12893–12920. https://doi.org/10.1007/s00289-024-05319-510.1007/s00289-024-05319-5 ↗
14. Wan Ishak WH, Rosli NA, Ahmad I (2020) Influence of amorphous cellulose on mechanical, thermal, and hydrolytic degradation of poly(lactic acid) biocomposites. Sci Rep. https://doi.org/10.1038/s41598-020-68274-x10.1038/s41598-020-68274-x ↗
15. Chakraborty G, Pugazhenthi G, Katiyar V (2019) Exfoliated graphene-dispersed poly (lactic acid)-based nanocomposite sensors for ethanol detection. Polym Bull 76:2367–2386. https://doi.org/10.1007/s00289-018-2494-810.1007/s00289-018-2494-8 ↗
16. Liang X, Li Q, Fang Y (2023) Preparation and characterization of modified Kaolin by a mechanochemical method. Materials. https://doi.org/10.3390/ma1608309910.3390/ma16083099 ↗
17. Yuan Y, Tang X, Sun H et al (2024) Surface modification of calcined kaolinite for enhanced solvent dispersion and mechanical properties in polybutylene adipate/terephthalate composites. Molecules. https://doi.org/10.3390/molecules2916389710.3390/molecules29163897 ↗
18. Kwaśniewska A, Chocyk D, Gładyszewski G et al (2020) The influence of kaolin clay on the mechanical properties and structure of thermoplastic starch films. Polymers. https://doi.org/10.3390/polym1201007310.3390/polym12010073 ↗
19. Inc. AATB (2025) PBS (Phosphate Buffered Saline) (1X, pH 7.4) Preparation and Recipe. https://www.aatbio.com/resources/buffer-preparations-and-recipes/pbs-phosphate-buffered-saline. Accessed 6 Aug 2025
20. Kohli D, Garg S, Jana AK (2021) Physical, mechanical, optical and biodegradability properties of polyvinyl alcohol/cellulose nanofibrils/kaolinite clay-based hybrid composite films. Indian Chem Eng 63:62–74. https://doi.org/10.1080/00194506.2019.169987110.1080/00194506.2019.1699871 ↗
21. Chandio AD, Channa IA, Rizwan M et al (2021) Polyvinyl alcohol and nano-clay based solution processed packaging coatings. Coatings. https://doi.org/10.3390/coatings1108094210.3390/coatings11080942 ↗
22. Mousa M, Dong Y (2020) The role of nanoparticle shapes and structures in material characterisation of polyvinyl alcohol (PVA) bionanocomposite films. Polymers. https://doi.org/10.3390/polym1202026410.3390/polym12020264 ↗
23. Brown K, Mendoza M, Tinsley T et al (2021) Polyvinyl alcohol-montmorillonite composites for water purification: analysis of clay mineral cation exchange and composite particle synthesis. Polyhedron. https://doi.org/10.1016/j.poly.2021.11529710.1016/j.poly.2021.115297 ↗
24. Lee S, Kim M, Song HY, Hyun K (2019) Characterization of the effect of clay on morphological evaluations of PLA/biodegradable polymer blends by FT-rheology. Macromolecules 52:7904–7919. https://doi.org/10.1021/acs.macromol.9b0080010.1021/acs.macromol.9b00800 ↗
25. Aziz SB, Nofal MM, Ghareeb HO et al (2021) Characteristics of poly(Vinyl alcohol) (PVA) based composites integrated with green synthesized Al3+-metal complex: structural, optical, and localized density of state analysis. Polymers. https://doi.org/10.3390/polym1308131610.3390/polym13081316 ↗
26. Hasan MZ, Arafat Y, Bashar MM et al (2022) Poly-(vinyl alcohol) composite films reinforced with carboxylated functional microcrystalline cellulose from jute fiber. Compos Adv Mater. https://doi.org/10.1177/2634983322110388810.1177/26349833221103888 ↗
27. Uto K, Liu Y, Mu M et al (2024) Humidity-responsive polyvinyl alcohol/microcrystalline cellulose composites with shape memory features for hair-styling applications. Adv Mater Interfaces. https://doi.org/10.1002/admi.20230027410.1002/admi.202300274 ↗
28. Sachchu MMH, Anik FK, Ahmed S et al (2025) Crystallographic investigation of PVA@PLA nanocomposite film by X-ray diffraction: insight from high resolution TEM. J Eng Res Rep 27:310–327. https://doi.org/10.9734/jerr/2025/v27i3143610.9734/jerr/2025/v27i31436 ↗
29. Isogai A, Usuda M (1990) Crystallinity indexes of cellulosic materials. Sen-i Gakkaishi 46:324–329. https://doi.org/10.2115/fiber.46.8_32410.2115/fiber.46.8_324 ↗
30. Lu J, Wang T, Drzal LT (2008) Preparation and properties of microfibrillated cellulose polyvinyl alcohol composite materials. Compos Part A Appl Sci Manuf 39:738–746. https://doi.org/10.1016/j.compositesa.2008.02.00310.1016/j.compositesa.2008.02.003 ↗
31. Holder CF, Schaak RE (2019) Tutorial on powder X-ray diffraction for characterizing nanoscale materials. ACS Nano 13:7359–7365. https://doi.org/10.1021/acsnano.9b0515710.1021/acsnano.9b05157 ↗
32. Cline WF, Hediger FH (1953) A study of the identification of certain clay minerals by x-ray diffraction. 90
33. Zagho MM, Khader MM (2016) The impact of clay loading on the relative intercalation of poly(Vinyl alcohol)-clay composites. J Mater Sci Chem Eng 04:20–31. https://doi.org/10.4236/msce.2016.41000310.4236/msce.2016.410003 ↗
34. Gentile G, Cocca M, Avolio R et al (2018) Effect of microfibrillated cellulose on microstructure and properties of poly(vinyl alcohol) foams. Polymers. https://doi.org/10.3390/polym1008081310.3390/polym10080813 ↗
35. Aridi et al (2010) . Structural FTIR analysis of cellulose functional groups isolated from Leucaena leucocephala pods using different bleaching agents
36. Hospodarova V, Singovszka E, Stevulova N (2018) Characterization of cellulosic fibers by FTIR spectroscopy for their further implementation to building materials. Am J Anal Chem 09:303–310. https://doi.org/10.4236/ajac.2018.9602310.4236/ajac.2018.96023 ↗
37. Aprilia S, Razali N, Syamsuddin Y et al (2019) Composites polyvinyl alcohol filled with nanocellulose from oil palm waste by formic acid hydrolysis. MATEC Web Conf 268:04012. https://doi.org/10.1051/matecconf/20192680401210.1051/matecconf/201926804012 ↗
38. Chang JH (2019) Comparative analysis of properties of PVA composites with various nanofillers: pristine clay, organoclay, and functionalized graphene. Nanomaterials. https://doi.org/10.3390/nano903032310.3390/nano9030323 ↗
39. Baidya S (2025) Poly-vinyl alcohol/hydroxy-ethyl cellulose/montmorillonite nanoclay-based food packaging film for dielectric heating of vegetable sandwiches. Int J Biol Macromol. https://doi.org/10.1016/j.ijbiomac.2025.14081710.1016/j.ijbiomac.2025.140817 ↗
40. Tang C, Liu H (2008) Cellulose nanofiber reinforced poly(vinyl alcohol) composite film with high visible light transmittance. Compos Part A Appl Sci Manuf 39:1638–1643. https://doi.org/10.1016/j.compositesa.2008.07.00510.1016/j.compositesa.2008.07.005 ↗
41. Spoljaric S, Salminen A, Dang Luong N et al (2014) Nanofibrillated cellulose, poly(vinyl alcohol), montmorillonite clay hybrid nanocomposites with superior barrier and thermomechanical properties. Polym Compos 35:1117–1131. https://doi.org/10.1002/pc.2275910.1002/pc.22759 ↗
42. Lim WS, Kim MH, Park HJ, Lee MH (2024) Characterization of polyvinyl alcohol (PVA)/polyacrylic acid (PAA) composite film-forming solutions and resulting films as affected by beeswax content. Polymers. https://doi.org/10.3390/polym1603031010.3390/polym16030310 ↗
43. Gil-Guillén I, González-Martínez C, Chiralt A (2025) Influence of the cellulose purification method on the properties of PVA composites with almond shell fibres. Molecules. https://doi.org/10.3390/molecules3002037210.3390/molecules30020372 ↗
44. Osman IM, Hussein K, Alatta NO et al (2021) Effects of addit and gamma irradiat on the structural and optical properties of polyvinyl alcohol doped with silver nitrate 9:1780–1792
45. Medina L (2019) High clay content cellulose nanocomposites for mechanical performance and fire retardancy. Trita-Cbh-Fou Nv 201926:62
46. Mavila B, Pradeep H, Suresh S et al (2024) Poly(vinyl alcohol) embedded with Montmorillonite clay and nano titania: a scale-up for sustainable environmental remediation. ACS Omega 9:51120–51135. https://doi.org/10.1021/acsomega.4c0653010.1021/acsomega.4c06530 ↗
47. Kord B, Malekian B, Yousefi H, Najafi A (2016) Preparation and characterization of nanofibrillated cellulose/poly (vinyl alcohol) composite films. Maderas Cienc Tecnol 18:743–752. https://doi.org/10.4067/S0718-221X201600500006510.4067/S0718-221X2016005000065 ↗
48. Ali MHM, Kahder MM, Al-Saad KA, Al-Meer S (2013) Properties of nanoclay PVA composites materials. QScience Connect. https://doi.org/10.5339/connect.2013.110.5339/connect.2013.1 ↗
49. Gadhave RV (2023) Comparative study of effect of addition of calcium carbonate and clay on the performance properties of polyvinyl acetate wood glue. Open J Polym Chem 13:1–13. https://doi.org/10.4236/ojpchem.2023.13100110.4236/ojpchem.2023.131001 ↗
50. McNamara JT, Morgan JLW, Zimmer J (2015) A molecular description of cellulose biosynthesis. Annu Rev Biochem 84:895–921. https://doi.org/10.1146/annurev-biochem-060614-03393010.1146/annurev-biochem-060614-033930 ↗
51. Mahardika M, Asrofi M, Amelia D, et al (2021) Tensile strength and moisture resistance properties of biocomposite films based on polyvinyl alcohol (PVA) with cellulose as reinforcement from Durian peel fibers. E3S Web Conf 302. https://doi.org/10.1051/e3sconf/20213020200110.1051/e3sconf/202130202001 ↗
52. Huang S, Wang X, Zhang Y et al (2022) Cellulose nanofibers/polyvinyl alcohol blends as an efficient coating to improve the hydrophobic and oleophobic properties of paper. Sci Rep 12:39–55. https://doi.org/10.1038/s41598-022-20499-810.1038/s41598-022-20499-8 ↗
53. Taleb K, Saidi-Besbes S, Pillin I, Grohens Y (2022) Biodegradable poly(butylene succinate) nanocomposites based on dimeric surfactant organomodified clays with enhanced water vapor barrier and mechanical properties. ACS Omega 7:43254–43264. https://doi.org/10.1021/acsomega.2c0596410.1021/acsomega.2c05964 ↗
54. Kouser S, Prabhu A, Prashantha K et al (2022) Modified halloysite nanotubes with Chitosan incorporated PVA/PVP bionanocomposite films: thermal, mechanical properties and biocompatibility for tissue engineering. Colloids Surf A Physicochem Eng Asp. https://doi.org/10.1016/j.colsurfa.2021.12794110.1016/j.colsurfa.2021.127941 ↗
55. Jain N, Singh VK, Chauhan S (2017) A review on mechanical and water absorption properties of polyvinyl alcohol based composites/films. J Mech Behav Mater 26:213–222. https://doi.org/10.1515/jmbm-2017-002710.1515/jmbm-2017-0027 ↗
56. Tsioptsias C, Fardis D, Ntampou X et al (2023) Thermal behavior of poly(vinyl alcohol) in the form of physically crosslinked film. Polymers. https://doi.org/10.3390/polym1508184310.3390/polym15081843 ↗
57. Chakraborty G, Valapa RB, Pugazhenthi G, Katiyar V (2018) Investigating the properties of poly (lactic acid)/exfoliated graphene based nanocomposites fabricated by versatile coating approach. Int J Biol Macromol 113:1080–1091. https://doi.org/10.1016/j.ijbiomac.2018.03.03710.1016/j.ijbiomac.2018.03.037 ↗
58. Borkotoky SS, Dhar P, Katiyar V (2018) Biodegradable poly (lactic acid)/Cellulose nanocrystals (CNCs) composite microcellular foam: effect of nanofillers on foam cellular morphology, thermal and wettability behavior. Int J Biol Macromol 106:433–446. https://doi.org/10.1016/j.ijbiomac.2017.08.03610.1016/j.ijbiomac.2017.08.036 ↗
59. Alhulaybi ZA, Dubdub I (2024) Kinetics study of PVA polymer by model-free and model-fitting methods using TGA. Polymers (Basel). https://doi.org/10.3390/polym1605062910.3390/polym16050629 ↗
60. Morancho JM, Salla JM, Cadenato A et al (2011) Kinetic studies of the degradation of poly(vinyl alcohol)-based proton-conducting membranes at low temperatures. Thermochim Acta 521:139–147. https://doi.org/10.1016/j.tca.2011.04.01610.1016/j.tca.2011.04.016 ↗
61. Gautam A, Komal P (2019) Synthesis of montmorillonite clay/poly(vinyl alcohol) nanocomposites and their mechanical properties. J Nanosci Nanotechnol 19:8071–8077. https://doi.org/10.1166/jnn.2019.1686910.1166/jnn.2019.16869 ↗
62. Karim MA, Dipti SS, Elahi MME (2024) Clay powder in polymer composite membranes enhanced the performance of direct methanol fuel cells. Polym Polym Compos. https://doi.org/10.1177/0967391124127530210.1177/09673911241275302 ↗
63. Osolnik U, Vek V, Korošec RC et al (2024) Integration of wood-based components–cellulose nanofibrils and tannic acid-into a poly(vinyl alcohol) matrix to improve functional properties. Int J Biol Macromol. https://doi.org/10.1016/j.ijbiomac.2023.12849510.1016/j.ijbiomac.2023.128495 ↗
64. Sedaghat E, Rostami AA, Ghaemy M, Rostami A (2017) Kinetic analysis of thermal degradation of poly (Vinyl Alcohol)/starch/nano clay nanocomposite using differential isoconversional and master plot approaches. Int J Appl Chem 13:855–877
65. Frone AN, Panaitescu DM, Spataru DD et al (2011) Preparation and characterization of PVA composites with cellulose nanofibers obtained by ultrasonication. BioResources 6:487–512. https://doi.org/10.15376/biores.6.1.487-51210.15376/biores.6.1.487-512 ↗
66. Nurhaliza TA, Humaidi S (2024) Investigating the impact of polyvinyl alcohol addition on the thermal behavior and chemical structure of electrospun cellulose nanofibers. E3S Web Conf 481. https://doi.org/10.1051/e3sconf/20244810601110.1051/e3sconf/202448106011 ↗
67. Pshezhetskii VS, Rakhnyanskaya AA, Gaponenko IM, Nalbandyan YE (1990) A differential scanning calorimetry study of polyvinyl alcohol. Polymer Science U.S.S.R. 32:722–726. https://doi.org/10.1016/0032-3950(90)90394-L10.1016/0032-3950(90)90394-L ↗
68. Cholant GM, Bosenbecker MW, Reichert AA et al (2025) Polyvinyl alcohol films reinforced with nanocellulose from rice husk. Macromol. https://doi.org/10.3390/macromol501000610.3390/macromol5010006 ↗
69. Voronova MI, Surov OV, Guseinov SS et al (2015) Thermal stability of polyvinyl alcohol/nanocrystalline cellulose composites. Carbohydr Polym 130:440–447. https://doi.org/10.1016/j.carbpol.2015.05.03210.1016/j.carbpol.2015.05.032 ↗
70. Adamu M, Rahman MR, Hamdan S (2019) Formulation optimization and characterization of bamboo/polyvinyl alcohol/clay nanocomposite by response surface methodology. Compos Part B Eng. https://doi.org/10.1016/j.compositesb.2019.10729710.1016/j.compositesb.2019.107297 ↗
71. Ji T, Zhang R, Dong X et al (2020) Effects of ultrasonication time on the properties of polyvinyl alcohol/sodium carboxymethyl cellulose/nano-zno/multilayer graphene nanoplatelet composite films. Nanomaterials 10:1–27. https://doi.org/10.3390/nano1009179710.3390/nano10091797 ↗
72. de Lima GG, Ferreira BD, Matos M et al (2020) Effect of cellulose size-concentration on the structure of polyvinyl alcohol hydrogels. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2020.11661210.1016/j.carbpol.2020.116612 ↗
73. Peng H, Wang S (2018). Properties and reinforcing mechanism of cellulose reinforced polyvinyl alcohol hydrogel membranes. https://doi.org/10.2991/ismems-17.2018.610.2991/ismems-17.2018.6 ↗
74. Taghizadeh MT, Sabouri N, Ghanbarzadeh B (2013) Polyvinyl alcohol: starch: carboxymethyl cellulose containing sodium montmorillonite clay blends; mechanical properties and biodegradation behavior. Springerplus 2:1–8. https://doi.org/10.1186/2193-1801-2-37610.1186/2193-1801-2-376 ↗
75. Sharma P, Agrawal PK, Singh VK et al (2023) A comprehensive review on properties of polyvinyl alcohol (PVA) crosslinked with carboxylic acid. J Mater Environ Sci 2023:1236–1252