Enhancing the cycling performance and voltage characteristics via regulating the nickel–cobalt ratio for lithium-rich manganese-based cathode materials
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (49)
Show source-provided references
1. Wang L, Sun X, Ma J, Chen B, Li C, Li J, Chang L, Yu X, Chan T, Hu Z, Noked M, Cui G (2021) Bidirectionally compatible buffering layer enables highly stableand conductive interface for 4. 5 V sulfide‐based all‐solid‐state lithium batteries. Adv Energy Mater 11:2100881. https://doi.org/10.1002/aenm.20210088110.1002/aenm.202100881 ↗
2. Cronk A, Chen Y-T, Deysher G, Ham S-Y, Yang H, Ridley P, Sayahpour B, Nguyen LHB, Oh JAS, Jang J, Tan DHS, Meng YS (2023) Overcoming the interfacial challenges of LiFePO4 in inorganic all-solid-state batteries. ACSEnergy Lett 8:827–835. https://doi.org/10.1021/acsenergylett.2c0213810.1021/acsenergylett.2c02138 ↗
3. Li M, Li MN, Banis X, Li R, Li L, Zhang S, Zhao S, Lu S, Huang H, Su D, Sun X (2020) Stabilizing and understanding the interface between nickel-rich cathode and PEO-based electrolyte by lithium niobium oxide coating for high-performance all-solid-statebatteries. Nano Energy 78:105107. https://doi.org/10.1016/j.nanoen.2020.10510710.1016/j.nanoen.2020.105107 ↗
4. Da Silva MAS, Nobrega FAC, Do Carmo FF et al (2024) Investigation of dielectric properties of a Li4Ti5O12 ceramic matrix for microwave temperature sensing applications. J Aust Ceram Soc 60:355–362. https://doi.org/10.1007/s41779-024-01009-710.1007/s41779-024-01009-7 ↗
5. Zhao S, Yan K, Zhang J, Sun B, Wang G (2021) Reaction mechanisms of layered lithium‐rich cathode materials for high‐energy lithium‐ion batteries. Angew Chem Int Ed 60:2208–2220. https://doi.org/10.1002/anie.20200026210.1002/anie.202000262 ↗
6. Luo D, Yang X, Xiao Y, Zhu H (2025) Insights into the challenges and potential solutions of Li- and Mn-rich layered cathode materials. Progress in Nat Sci: Mater Int. https://doi.org/10.1016/j.pnsc.2025.06.01310.1016/j.pnsc.2025.06.013 ↗
7. Thackeray MM, Kang S-H, Johnson CS, Vaughey JT, Benedek R, Hackney SA (2007) Li2MnO3-stabilized LiMO2(M=Mn, Ni, Co)electrodes for lithium-ion batteries. J Mater Chem 17:3112. https://doi.org/10.1039/b702425h10.1039/b702425h ↗
8. Li J, Camardese J, Glazier S, Dahn JR (2014) Structural and electrochemical study of the Li–Mn–Ni oxide system within the layered single phase region. Chem Mater 26:7059–7066. https://doi.org/10.1021/cm503505b10.1021/cm503505b ↗
9. Boulineau A, Croguennec L, Delmas C, Weill F (2009) Reinvestigation of Li2MnO3 structure: electron diffraction and high resolution TEM. Chem Mater 21(18):4216–422210.1021/cm900998n ↗
10. Guerrini N, Jin L, Lozano JG, Luo K, Sobkowiak A, Tsuruta K, Massel F, Duda LC, Roberts MR, Bruce PG (2020) Charging mechanism of Li2MnO3. Chem Mater 32(9):3733–374010.1021/acs.chemmater.9b04459 ↗
11. Yin C, Wan L, Qiu B, Wang F, Jiang W, Cui H, Bai J, Ehrlich S, Wei Z, Liu Z (2021) Boosting energy efficiency of Li-rich layered oxide cathodes by tuning oxygen redox kinetics and reversibility. Energy Storage Mater 35:388–399. https://doi.org/10.1016/j.ensm.2020.11.03410.1016/j.ensm.2020.11.034 ↗
12. Wu Y, Xie L, He X, Zhuo L, Wang L, Ming J (2018) Electrochemical activation, voltage decay and hysteresis of Li-rich layered cathode probed by various cobalt content. Electrochim Acta 265:115–120. https://doi.org/10.1016/j.electacta.2018.01.18110.1016/j.electacta.2018.01.181 ↗
13. Guo W, Zhang C, Zhang Y, Lin L, He W, Xie Q, Sa B, Wang L, Peng D (2021) A universal strategy toward the preciseregulation of initial coulombic efficiency of Li‐rich Mn‐based cathode materials. Adv Mater 33:2103173. https://doi.org/10.1002/adma.20210317310.1002/adma.202103173 ↗
14. Zheng H, Wang L, Lu J (2025) Understanding voltage decay and hysteresis in Li‐rich layered oxide cathodes. Adv Funct Mater 35:2503578. https://doi.org/10.1002/adfm.20250357810.1002/adfm.202503578 ↗
15. Zhang K, Li B, Zuo Y, Song J, Shang H, Ning F, Xia D (2019) Voltage decay in layered Li-rich Mn-based cathodematerials. Electrochem Energ Rev 2(4):606–623. https://doi.org/10.1007/s41918-019-00049-z10.1007/s41918-019-00049-z ↗
16. Shao Y, Xu J, Amardeep A, Xia Y, Meng X, Liu J, Liao S (2024) Lithium‐ion conductive coatings for nickel‐rich cathodes for lithium‐ionbatteries. Small Methods 8:2400256. https://doi.org/10.1002/smtd.20240025610.1002/smtd.202400256 ↗
17. Shumei D, Dan T, Ping L, Huiqin L, Fenyan W, Zhang H (2023) Research progress and prospectin element doping oflithium-rich layered oxidesas cathode materials for lithium-ion batteries. J Solid State Electrochem 27:1–23. https://doi.org/10.1007/s10008-022-05294-910.1007/s10008-022-05294-9 ↗
18. Zhang Y, Shi X, Zheng S, Ouyang Y, Li M, Meng C, Yu Y, Wu Z-S (2023) Alternate heterogeneous superlattice control of lattice strain to stabilize Li-rich cathode. Energy Environ Sci 16:5043–5051. https://doi.org/10.1039/D3EE01318A10.1039/D3EE01318A ↗
19. Zhou Z, Luo Z, He Z, Zheng J, Li Y, Yan C, Mao J (2021) Suppress voltage decay of lithium-rich materials by coating layers with different crystalline states. J Energy Chem 60:591–598. https://doi.org/10.1016/j.jechem.2021.01.02010.1016/j.jechem.2021.01.020 ↗
20. Zhang W, Qiu C, Lin Z, Zhao G, Liu Y, Wang P, Lin Y, Huang Z, Li J (2024) Modification of Li3PO4 layer effectively boosting lithium storage and thermal safety performance for LiCoO2 batteries. J Energy Chem 99:615–626. https://doi.org/10.1016/j.jechem.2024.08.01010.1016/j.jechem.2024.08.010 ↗
21. Zhou X, Zhang F, Fu X, Zhang N, Huang J, Cai X, Ding H, Li B, Niu L, Li S (2022) Utilizing fast ion conductor for single-crystal Ni-rich cathodes to achieve dual-functional modification of conductor network constructing and near-surface doping. Energy Storage Mater 52:19–28. https://doi.org/10.1016/j.ensm.2022.07.02910.1016/j.ensm.2022.07.029 ↗
22. Zhang X, Shi J, Liang J, Yin Y, Zhang J, Yu X, Guo Y (2018) Suppressing surface lattice oxygen release of Li‐rich cathode materials via hetero structured spinel Li4Mn5O12 coating. Adv Mater 30:1801751. https://doi.org/10.1002/adma.20180175110.1002/adma.201801751 ↗
23. Huang C, Wang Z, Fang Z-Q, Zhao S-X, Ci L (2021) Achieving high initial coulombic efficiency and low voltage dropping in Li-rich Mn-based cathode materials by Metal-Organic frameworks-derived coating. J Power Sources 499:229967. https://doi.org/10.1016/j.jpowsour.2021.22996710.1016/j.jpowsour.2021.229967 ↗
24. Alshammari DA, Abd El-Gawad HH, Abdullah M et al (2024) CuTe supported on graphitic carbon nitride nanocomposite as an effective electrocatalyst for oxidation of water in basic media. J Electroanal Chem 953:118018. https://doi.org/10.1016/j.jelechem.2023.11801810.1016/j.jelechem.2023.118018 ↗
25. Wu F, Liu J, Li L, Zhang X, Luo R, Ye Y, Chen R (2016) Surface modification of Li-rich cathode materials for lithium-ion batteries with a PEDOT:PSS conducting polymer. ACS Appl Mater Interfaces 8:23095–23104. https://doi.org/10.1021/acsami.6b0743110.1021/acsami.6b07431 ↗
26. Trukhanov AV, Zhao X, Kostishin VG et al (2024) Evolution of the structural parameters and magnetic characteristics in “ferrite/polymer” nanocomposites. J Alloys Compd 986:174048. https://doi.org/10.1016/j.jallcom.2024.17404810.1016/j.jallcom.2024.174048 ↗
27. Trukhanov AV, Tishkevich DI, Podgornaya SV et al (2022) Impact of the nanocarbon on magnetic and electrodynamic properties of the ferrite/polymer composites. Nanomaterials 12:868. https://doi.org/10.3390/nano1205086810.3390/nano12050868 ↗
28. Wang Q, He W, Wang L, Li S, Zheng H, Liu Q, Cai Y, Lin J, Xie Q, Peng D-L (2021) Morphology control and Na+ doping toward high-performance Li-rich layered cathode materials for lithium-ion batteries. ACS Sustain Chem Eng 9:197–206. https://doi.org/10.1021/acssuschemeng.0c0659510.1021/acssuschemeng.0c06595 ↗
29. Phattharasupakun N, Geng C, Johnson MB, Väli R, Sawangphruk M, Dahn JR (2020) Impact of Cr doping on the voltage fade of Li-rich Mn-rich Li1.11Ni0.33Mn0.56O2 and Li1.2Ni0.2Mn0.6O2 positive electrode materials. J Electrochem Soc 167:160545. https://doi.org/10.1149/1945-7111/abd44e10.1149/1945-7111/abd44e ↗
30. Cho M, Song SH, Hong S, Kim KS, Avdeev M, Yoo J, Ko K, Hong J, Kim J, Lee S, Kim H (2021) Critical role of Ti4+ in stabilizing high‐voltage redox reactions in Li‐rich layered material. Small 17:2100840. https://doi.org/10.1002/smll.20210084010.1002/smll.202100840 ↗
31. Liu S, Liu Z, Shen X, Li W, Gao Y, Banis MN, Li M, Chen K, Zhu L, Yu R, Wang Z, Sun X, Lu G, Kong Q, Bai X, Chen L (2018) Surface doping to enhance structural integrity and performance of Li‐rich layered oxide. Adv Energy Mater 8:1802105. https://doi.org/10.1002/aenm.20180210510.1002/aenm.201802105 ↗
32. Wan J-Z, Ma C, Gao L, Chen J-S, Wang K-X (2025) Boosting the rate performance of lithium-rich cathode materials with W-doping. J Mater Chem A 13:25926–25933. https://doi.org/10.1039/D5TA02230D10.1039/D5TA02230D ↗
33. Yin C, Wen X, Wan L, Shi Z, Wei Z, Li X, Gu Q, Qiu B, Liu Z (2021) Surface reinforcement doping to suppress oxygen release of Li-rich layered oxides. J Power Sources 503:230048. https://doi.org/10.1016/j.jpowsour.2021.23004810.1016/j.jpowsour.2021.230048 ↗
34. Zhang K, Qi J, Song J, Zuo Y, Yang Y, Yang T, Chen T, Liu X, Chen L, Xia D (2022) Sulfuration of Li‐rich Mn‐based cathode materials for multianionic redox and stabilized coordination environment. Adv Mater 34:2109564. https://doi.org/10.1002/adma.20210956410.1002/adma.202109564 ↗
35. Trukhanov SV, Trukhanov AV, Turchenko VA et al (2018) Polarization origin and iron positions in indium doped barium hexaferrites. Ceram Int 44:290–300. https://doi.org/10.1016/j.ceramint.2017.09.17210.1016/j.ceramint.2017.09.172 ↗
36. Trukhanov AV, Kostishyn VG, Panina LV et al (2018) Control of electromagnetic properties in substituted M-type hexagonal ferrites. J Alloys Compd 754:247–256. https://doi.org/10.1016/j.jallcom.2018.04.15010.1016/j.jallcom.2018.04.150 ↗
37. Troyanchuk IO, Khalyavin DD, Trukhanov SV et al (1999) Magnetotransport properties of the Sm0.56 (Sr0.44 - x Me x)MnO3 (Me = Ba, Ca, Cd) perovskites. J Phys Condens Matter 11:8913–8920. https://doi.org/10.1088/0953-8984/11/45/31410.1088/0953-8984/11/45/314 ↗
38. Turchenko V, Bondyakov AS, Trukhanov S et al (2023) Microscopic mechanism of ferroelectric properties in barium hexaferrites. J Alloys Compd 931:167433. https://doi.org/10.1016/j.jallcom.2022.16743310.1016/j.jallcom.2022.167433 ↗
39. Sun G, Yu F-D, Que L-F et al (2019) Local electronic structure modulation enhances operating voltage in Li-rich cathodes. Nano Energy 66:104102. https://doi.org/10.1016/j.nanoen.2019.10410210.1016/j.nanoen.2019.104102 ↗
40. Wang H, Zhan F, Zhan H, Ming X (2022) Improve the midpoint voltage and structural stability of Li-rich manganese-based cathode material by increasing the nickel content. Catalysts 12:584. https://doi.org/10.3390/catal1206058410.3390/catal12060584 ↗
41. Li B, Zhuo Z, Zhang L et al (2023) Decoupling the roles of Ni and Co in anionic redox activity of Li-rich NMC cathodes. Nat Mater 22:1370–1379. https://doi.org/10.1038/s41563-023-01679-x10.1038/s41563-023-01679-x ↗
42. Tripathi P, Lee SJ (2025) Particle geometry space: an integrated characterization of particle shape, surface area, volume, specific surface, and size distribution. Transp Geotech 52:101579. https://doi.org/10.1016/j.trgeo.2025.10157910.1016/j.trgeo.2025.101579 ↗
43. Trukhanov SV, Fedotova VV, Trukhanov AV et al (2008) Cation ordering and magnetic properties of neodymium-barium manganites. Tech Phys 53:49–54. https://doi.org/10.1134/S106378420801009X10.1134/S106378420801009X ↗
44. Mo W, Wang Z, Wang J et al (2020) Tuning the surface of LiNi0.8Co0.1Mn0.1O2 primary particle with lithium boron oxide toward stable cycling. Chem Eng J 400:125820. https://doi.org/10.1016/j.cej.2020.12582010.1016/j.cej.2020.125820 ↗
45. Trukhanov SV, Troyanchuk IO, Pushkarev NV, Szymczak H (2003) The magnetic properties of anion-deficient La1 – xBaxMnO3 – x/2 (0 ≤ x ≤ 0.30) manganites. J Exp Theor Phys 96:110–11710.1134/1.1545390 ↗
46. Ku K, Hong J, Kim H, Park H, Seong WM, Jung S, Yoon G, Park K, Kim H, Kang K (2018) Suppression of voltage decay through manganese deactivation and nickel redox buffering in high-energy layered lithium‐rich electrodes. Adv Energy Mater 8:1800606. https://doi.org/10.1002/aenm.20180060610.1002/aenm.201800606 ↗
47. Sathiya M, Rousse G, Ramesha K et al (2013) Reversible anionic redox chemistry in high-capacity layered-oxide electrodes. Nat Mater 12:827–835. https://doi.org/10.1038/nmat369910.1038/nmat3699 ↗
48. Zhang J, Yuan H, Qin Z, Ding P, Yu D, Wu H, Wang J, Shao Y, Zhou W, Nan C-W, Ren Y, Li L (2025) Regulating the manganese valence state improves the kinetic properties of manganese-based cathodes. Adv Funct Mater 35:2413684. https://doi.org/10.1002/adfm.20241368410.1002/adfm.202413684 ↗
49. Zhang J, Wu F, Dai X et al (2021) Enhancing the high-voltage cycling performance and rate capability of LiNi0.8 Co0.1Mn0.1O2 cathode material by codoping with Na and Br. ACS Sustain Chem Eng 9:1741–1753. https://doi.org/10.1021/acssuschemeng.0c0770310.1021/acssuschemeng.0c07703 ↗