MoS2–Al2O3 nanofluid-induced microstructure evolution and corrosion resistance enhancement of hot-rolled steel surface
Source abstract
Abstract
The influence of MoS2–Al2O3 nanofluid as a functional lubricant on the microstructure and corrosion resistance of hot-rolled steel surface was studied. Because of the excellent lubrication performance of the nanofluid, the rolled surface quality improved with a 18.2% and 69.5% reduction in surface roughness and oxide scale thickness, respectively, when compared with the base-fluid without nanoparticles. The further microstructure characterization determined that the grain size, local misorientation and deformed grain fraction of the steel decreased significantly. A diffusion layer of Al2O3, FeS and FeMo4S6 was found in the outer oxide layer of rolled surface. Closely arranged Al2O3 grains inhibited the oxidation of steel strips that the oxidation activation energy was increased by about 14.5%. Through density functional theory (DFT) calculation, the formation of FeS and FeMo4S6 was attributed to the migration of Mo and S atoms from MoS2 into the Fe lattice through substitutional and interstitial diffusion, respectively, with the energy barrier of 0.84 eV and 0.54 eV. Finally, the protection of diffusion layer, reduction in surface defects, and alleviation of residual stress and deformation resulted in the enhancement of corrosion resistance. This study provides a possible route to achieve surface enhancement during the hot rolling process.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal and Thin Film Mechanics · High-Temperature Coating Behaviors · Lubricants and Their Additives
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
Show source-provided references
1. Meng Y, Sun J, He J, Yan X, Pei Y (2020) Recycling prospect and sustainable lubrication mechanism of water-based MoS2 nano-lubricant for steel cold rolling processurn. J Cleaner Prod 277:123991.10.1016/j.jclepro.2020.123991 ↗
2. Wu W, Liu Z, Wang Q, Li Q (2020) Improving the resistance of high-strength steel to SCC in a SO2-polluted marine atmosphere through Nb and Sb microalloying. Corrosion Sci 170:108693.10.1016/j.corsci.2020.108693 ↗
3. Bao Y, Sun J, Kong L (2017) Effects of nano-SiO2 as water-based lubricant additive on surface qualities of strips after hot rolling. Tribol Int 114:257–26310.1016/j.triboint.2017.04.026 ↗
4. Bhaumik S, Datta S, Pathak SD (2017) Analyses of tribological properties of castor oil with various carbonaceous micro- and nano-friction modifiers. J Tribol 139: 061802.10.1115/1.4036379 ↗
5. Seyedzavvar M, Abbasi H, Kiyasatfar M, Ilkhchi RN (2020) Investigation on tribological performance of CuO vegetable-oil based nanofluids for grinding operations. Adv Manufact 8:344–36010.1007/s40436-020-00314-1 ↗
6. Kong L, Sun J, Bao Y, Meng Y (2017) Effect of TiO2 nanoparticles on wettability and tribological performance of aqueous suspension. Wear 376–377:786–79110.1016/j.wear.2017.01.064 ↗
7. Bakalova T, Svobodová L (2019) Quality assessment of milling technology and the biocidal effects of SiO2 or TiO2 nanoadditives in cooling lubricant emulsions. J Manuf Process 45:509–51910.1016/j.jmapro.2019.07.032 ↗
8. Wu H, Qin L, Dong G, Hua M, Yang S, Zhang J (2017) An investigation on the lubrication mechanism of MoS2 nano sheet in point contact: The manner of particle entering the contact area. Tribol Int 107:48–5510.1016/j.triboint.2016.11.009 ↗
9. Xu Y, Peng Y, Dearn KD, Zheng X, Yao L, Hu X (2015) Synergistic lubricating behaviors of graphene and MoS2 dispersed in esterified bio-oil for steel/steel contact. Wear 342–343:297–30910.1016/j.wear.2015.09.011 ↗
10. Kumar AS, Deb S, Paul S (2020) Tribological characteristics and micromilling performance of nanoparticle enhanced water based cutting fluids in minimum quantity lubrication. J Manuf Process 56:766–77610.1016/j.jmapro.2020.05.032 ↗
11. Liu X, Zhou X, Yang C, Huang J, Kuang F, Wang H (2020) Study on the effect of particle size and dispersion of SiO2 on tribological properties of nitrile rubber. Wear 460–461:203428.10.1016/j.wear.2020.203428 ↗
12. Ismail NA, Mohd Zulkifli NW, Chowdhury ZZ, Johan MR (2020) Grafting of straight alkyl chain improved the hydrophobicity and tribological performance of graphene oxide in oil as lubricant. J Molecular Liquids 319:114276.10.1016/j.molliq.2020.114276 ↗
13. Perween S, Thakur NK, Beg M, Sharma S, Ranjan A (2019) Enhancing the properties of water based drilling fluid using bismuth ferrite nanoparticles. Colloids Surf A 561:165–17710.1016/j.colsurfa.2018.10.060 ↗
14. Wu H, Jiang C, Zhang J, Huang S, Wang L, Jiao S, Huang H, Jiang Z (2019) Oxidation behaviour of steel during hot rolling by using TiO2-containing water-based nanolubricant. Oxid Met 92:315–33510.1007/s11085-019-09924-y ↗
15. Roy S, Jazaa Y, Sundararajan S (2019) Investigating the micropitting and wear performance of copper oxide and tungsten carbide nanofluids under boundary lubrication. Wear 428–429:55–6310.1016/j.wear.2019.03.007 ↗
16. Xu Y, Zheng Q, You T, Yao L, Hu X (2019) Laser-induced improvement in tribological performances of surface coatings with MoS2 nanosheets and graphene. Surf Coat Technol 358:353–36110.1016/j.surfcoat.2018.11.063 ↗
17. Xiong S, Liang D, Wu H, Lin W, Chen J, Zhang B (2021) Preparation, characterization, tribological and lubrication performances of Eu doped CaWO4 nanoparticle as anti-wear additive in water-soluble fluid for steel strip during hot rolling. Appl Surface Sci 539:148090.10.1016/j.apsusc.2020.148090 ↗
18. Mohammed AA, Khodair ZT, Khadom AA (2020) Preparation, characterization and application of Al2O3 nanoparticles for the protection of boiler steel tubes from high temperature corrosion. Ceram Int 46:26945–2695510.1016/j.ceramint.2020.07.172 ↗
19. Yao J, He Y, Wang D, Peng H, Guo H, Gong S (2013) Thermal barrier coatings with (Al2O3-Y2O3)/(Pt or Pt-Au) composite bond coat and 8YSZ top coat on Ni-based superalloy. Appl Surf Sci 286:298–30510.1016/j.apsusc.2013.09.075 ↗
20. Vasudev H, Thakur L, Singh H, Bansal A (2020) An investigation on oxidation behaviour of high velocity oxy-fuel sprayed Inconel718-Al2O3 composite coatings. Surface Coatings Technol 393:125770.10.1016/j.surfcoat.2020.125770 ↗
21. Meng G, Liu H, Liu M, Xu T, Yang G, Li C, Li C (2020) Large-grain α-Al2O3 enabling ultra-high oxidation-resistant MCrAlY bond coats by surface pre-agglomeration treatment. Corrosion Sci 163:108275.10.1016/j.corsci.2019.108275 ↗
22. Du S, Sun J, Wu P (2018) Preparation, characterization and lubrication performances of graphene oxide-TiO2 nanofluid in rolling strips. Carbon 140:338–35110.1016/j.carbon.2018.08.055 ↗
23. Xu Z, Lou W, Zhao G, Zheng D, Hao J, Wang X (2019) Cu nanoparticles decorated WS2 nanosheets as a lubricant additive for enhanced tribological performance. RSC Adv 9:7786–779410.1039/C9RA00337A ↗
24. Zhang C, He Y, Li F, Di H, Zhang L, Zhan Y (2016) h-BN decorated with Fe3O4 nanoparticles through mussel-inspired chemistry of dopamine for reinforcing anticorrosion performance of epoxy coatings. J Alloy Compd 685:743–75110.1016/j.jallcom.2016.06.220 ↗
25. Manibalan G, Murugadoss G, Thangamuthu R, Mohan Kumar R, Jayavel R (2019) Facile synthesis of heterostructure CeO2-TiO2 nanocomposites for enhanced electrochemical sensor and solar cell applications. J Alloys Compounds 773:449–461.10.1016/j.jallcom.2018.09.210 ↗
26. Zheng X, Xu Y, Geng J, Peng Y, Olson D, Hu X (2016) Tribological behavior of Fe3O4/MoS2 nanocomposites additives in aqueous and oil phase media. Tribol Int 102:79–8710.1016/j.triboint.2016.05.024 ↗
27. He J, Sun J, Meng Y, Pei Y (2020) Superior lubrication performance of MoS2-Al2O3 composite nanofluid in strips hot rolling. J Manuf Process 57:312–32310.1016/j.jmapro.2020.06.037 ↗
28. Wu H, Zhao J, Xia W, Cheng X, He A, Yun JH, Wang L, Huang H, Jiao S, Huang L, Zhang S, Jiang Z (2017) Analysis of TiO2 nano-additive water-based lubricants in hot rolling of microalloyed steel. J Manuf Process 27:26–3610.1016/j.jmapro.2017.03.011 ↗
29. Yu X, Jiang Z, Zhao J, Wei D, Zhou J, Zhou C, Huang Q (2016) The role of oxide-scale microtexture on tribological behaviour in the nanoparticle lubrication of hot rolling. Tribol Int 93:190–20110.1016/j.triboint.2015.08.049 ↗
30. An Q, Huang L, Wei S, Zhang R, Rong X, Wang Y, Geng L (2019) Enhanced interfacial bonding and superior oxidation resistance of CoCrAlY-TiB2 composite coating fabricated by air plasma spraying. Corrosion Sci 158:108102.10.1016/j.corsci.2019.108102 ↗
31. Hwang JK (2019) The microstructure dependence of drawability in ferritic, pearlitic, and TWIP steels during wire drawing. J Mater Sci 54:8743–8759.https://doi.org/10.1007/s10853-019-03499-410.1007/s10853-019-03499-4 ↗
32. Liang S, Fazeli F, Zurob HS (2019) Effects of solutes and temperature on high-temperature deformation and subsequent recovery in hot-rolled low alloy steels, Mater Sci Eng A 765:138324.10.1016/j.msea.2019.138324 ↗
33. Singh RK, Sharma AK, Dixit AR, Tiwari AK, Pramanik A, Mandal A (2017) Performance evaluation of alumina-graphene hybrid nano-cutting fluid in hard turning. J Clean Prod 162:830–84510.1016/j.jclepro.2017.06.104 ↗
34. Javadzadeh Kalahroudi F, Koohdar H, Jafarian HR, Haung Y, Langdon TG, Nili-Ahmadabadi M (2019) On the microstructure and mechanical properties of an Fe-10Ni-7Mn martensitic steel processed by high-pressure torsion. Mater Sci Eng A 749:27–34.10.1016/j.msea.2019.02.002 ↗
35. Wan Y, Jiang W, Song M, Huang Y, Li J, Sun G, Shi Y, Zhai X, Zhao X, RenL (2019) Distribution and formation mechanism of residual stress in duplex stainless steel weld joint by neutron diffraction and electron backscatter diffraction. Materials Design 181:108086.10.1016/j.matdes.2019.108086 ↗
36. Ba Q, Song R, Zhou N, Pei Z, Feng Y, Song R (2019) Revealing working hardening behavior and substructure evolutions of ultrahigh strength and enhanced wear resistance Fe-25Mn-7Al-1C steel treated by explosion processing. J Mater Sci 55:1256–1268. https://doi.org/10.1007/s10853-019-04021-610.1007/s10853-019-04021-6 ↗
37. Zhang Z, Jing H, Xu L, Han Y, Gao Z, Zhao L, Zhang J (2017) Microstructural characterization and electron backscatter diffraction analysis across the welded interface of duplex stainless steel. Appl Surf Sci 413:327–34310.1016/j.apsusc.2017.03.301 ↗
38. Birks N, Meier GH, Pettit FS (2006) Introduction to the high-temperature oxidation of metals, 2nd edn. University of Cambridge, Cambridge10.1017/CBO9781139163903 ↗
39. Jain U, Sonber J, Tewari R (2019) High temperature oxidation behaviour of V-Ti-Ta alloys. Fusion Eng Des 144:125–13210.1016/j.fusengdes.2019.04.070 ↗
40. Chen RY, Yuen WYD (2003) Review of the high-temperature oxidation of iron and carbon steels in air or oxygen. Oxid Met 59:433–46810.1023/A:1023685905159 ↗
41. Menzinger M, Wolfgang R (1969) The meaning and use of the Arrhenius activation energy. Angew Chem Int Ed 8:438–44410.1002/anie.196904381 ↗
42. Santos P, Coutinho J, Öberg S (2018) First-principles calculations of iron-hydrogen reactions in silicon. J Appl Phys 123:245703.10.1063/1.5039647 ↗
43. Perdew JP, Burke K, Ernzerhof M (1996) Generalized gradient approximation made simple. Phys Rev Lett 77:3865–386810.1103/PhysRevLett.77.3865 ↗
44. Kresse G (1999) From ultrasoft pseudopotentials to the projector augmented-wave method. Phys Rev B 59:1758–177510.1103/PhysRevB.59.1758 ↗
45. Wen X, Bai P, Zheng S, Tian Y (2021) Adsorption and dissociation mechanism of hydrogen sulfide on layered FeS surfaces: A dispersion-corrected DFT study. Appl Surface Sci 537:147905.10.1016/j.apsusc.2020.147905 ↗
46. Tang H, Sun J, Yan X, Wu P (2019) Electrochemical and adsorption behaviors of thiadiazole derivatives on the aluminum surface. RSC Adv 9:34617–3462610.1039/C9RA05740D ↗
47. Salehi M, Mozammel M, Emarati SM (2019) Superhydrophobic and corrosion resistant properties of electrodeposited Ni-TiO2/TMPSi nanocomposite coating. Colloids Surf, A 573:196–20410.1016/j.colsurfa.2019.04.024 ↗
48. Wang C, Yu Y, Yu J, Zhang Y, Zhao Y, Yuan Q (2020) Microstructure evolution and corrosion behavior of dissimilar 304/430 stainless steel welded joints. J Manuf Process 50:183–19110.1016/j.jmapro.2019.12.015 ↗
49. Wu C, Liu Q, Chen R, Liu J, Zhang H, Li R, Takahashi K, Liu P, Wang J (2017) Fabrication of ZIF-8@SiO2 micro/nano hierarchical superhydrophobic surface on AZ31 magnesium alloy with impressive corrosion resistance and abrasion resistance. ACS Appl Mater Interfaces 9:11106–1111510.1021/acsami.6b16848 ↗
50. Fernandes CM, Fagundes TSF, Santos NE, Rocha TSM, Garrett R, Borges RM, Muricy G, Valverde AL, Ponzio EA (2019) Ircinia strobilina crude extract as corrosion inhibitor for mild steel in acid medium. Electrochim Acta 312:137–14810.1016/j.electacta.2019.04.148 ↗
51. Yin X, Mu P, Wang Q, Li J (2020) Superhydrophobic ZIF-8-based dual-layer coating for enhanced corrosion protection of Mg alloy. ACS Appl Mater Interfaces 12:35453–3546310.1021/acsami.0c09497 ↗
52. Zhang X, Lv Y, Shan F, Wu Y, Lu X, Peng Z, Liu B, Yang L, Dong Z (2020) Microstructure, corrosion resistance, osteogenic activity and antibacterial capability of Mn-incorporated TiO2 coating. Appl Surface Sci 531:147399.10.1016/j.apsusc.2020.147399 ↗
53. Zhang W, Li HJ, Li Y, Ma C, Pan, Q, Chen L, Wang LJ, Wu YC (2010) Anticorrosion performance of acriflavine-Zn2+ system for mild steel in seawater utilization. J Molecular Liquids 299:112152.10.1016/j.molliq.2019.112152 ↗
54. Sharma AK, Tiwari AK, Dixit AR (2015) Mechanism of nanoparticles functioning and effects in machining processes: a review. Materials Today-Proc 2:3539–354410.1016/j.matpr.2015.07.331 ↗
55. Nowak WJ (2020) Effect of surface roughness on oxidation resistance of stainless steel AISI 316Ti during exposure at high temperature. J Mater Eng Perform 29:8060–806910.1007/s11665-020-05267-x ↗
56. Zhang X, Ding P, Sun Y, Guo J (2016) Layered FeMo4S6 nanosheets with robust lithium storage and electrochemical hydrogen evolution. Mater Lett 183:1–410.1016/j.matlet.2016.07.054 ↗
57. Jia J, Yang G, Zhang C, Zhang S, Zhang Y, Zhang P (2019) Effects of magnetic ionic liquid as a lubricant on the friction and wear behavior of a steel-steel sliding contact under elevated temperatures. Friction 9:61–7410.1007/s40544-019-0324-0 ↗
58. Siva T, Rajkumar S, Muralidharan S, Sathiyanarayanan S (2019) Bipolar properties of coatings to enhance the corrosion protection performance. Progress Organic Coatings 137:105379.10.1016/j.porgcoat.2019.105379 ↗