journal article·2022-08

Effect of Al addition on the grain refinement and mechanical properties of as-cast Mg–5Y–4Sm alloys

Zhanhe Liu, Lei Wang, Liping Wang, Yicheng Feng, Fuwei Kang, Bing Wang, Shangzhuo Li, Changsheng Hu

Journal of Materials Science· Volume 57· Issue 31
Publisher page

Abstract

In recent years, the utilization of Al as a grain refiner in Mg–RE alloys has gained widespread attention because of its advantages such as low cost. In this study, Mg–5Y–4Sm–xAl (x = 0, 0.6, 1.2 and 1.8 wt.%) alloys were fabricated, and high grain refinement efficiency of Al addition was obtained. Subsequently, the effect of different Al addition on the grain refinement was investigated and the refinement mechanism was discussed deeply in two major aspects. Firstly, Al2RE particles were formed in the solidification process and acted as the nucleation sites of α-Mg. The numerical density and diameter of those particles were obviously increased by increasing Al addition. Secondly, the addition of Al reduced the solute elements content in the α-Mg melt, resulting in a decrease in the grain growth restriction factor (Q value). Furthermore, the synergistic effect of solute elements and nucleation particles on grain refinement was described by the interdependent theory. Finally, the Al addition is beneficial to improve the mechanical properties of alloy. When the Al addition was 1.8%, the room temperature tensile strength of the alloy reached a maximum of 221 MPa and the maximum elongation was 9.2%. When the Al addition was 1.2%, the yield strength of the alloy reached a maximum of 142 MPa.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Wu GH, Wang CL, Sun M, Ding WJ (2021) Recent developments and applications on high-performance cast magnesium rare-earth alloys. J Magnes Alloy 9:1–2010.1016/j.jma.2020.06.021 ↗
2. Lapovok R, Zolotoyabko E, Berner A, Berner A, Kauffmann Y, Lakin E, Larianovsky N, Shechtman D (2016) Structure and mechanical property variations in Mg–Gd–Y–Zn–Zr alloy depending on its composition and processing conditions. Philos Mag 96:1–2510.1080/14786435.2016.1154204 ↗
3. Bommala VK, Krishna MG, Rao CT (2019) Magnesium matrix composites for biomedical applications: a review. J Magnes Alloy 7:72–7910.1016/j.jma.2018.11.001 ↗
4. Kula A, Noble K, Mishra RK, Niewczas M (2016) Plasticity of Mg–Gd alloys between 4k and 298k. Philos Mag 96:134–16510.1080/14786435.2015.1123820 ↗
5. Liu DX, Yang DL, Li XL, Hu SW (2019) Mechanical properties, corrosion resistance and biocompatibilities of degradable Mg–RE alloys: a review. J Mater Res Technol 8:1538–154910.1016/j.jmrt.2018.08.003 ↗
6. Zhang JH, Liu SJ, Wu RZ, Hou LG, Zhang ML (2018) Recent developments in high-strength Mg–RE-based alloys: Focusing on Mg–Gd and Mg–Y systems. J Magnes Alloy 6:277–29110.1016/j.jma.2018.08.001 ↗
7. StJohn DH, Easton MA, Qian M, Taylor JA (2012) Grain Refinement of magnesium alloys: a review of recent research, theoretical developments, and their application. Metall Mater Trans A 44:2935–294910.1007/s11661-012-1513-x ↗
8. Ali Y, Qiu D, Jiang B, Pan F, Zhang MX (2015) Current research progress in grain refinement of cast magnesium alloys: a review article. J Alloy Compd 619:639–65110.1016/j.jallcom.2014.09.061 ↗
9. Gao L, Chen RS, Han EH (2009) Microstructure and strengthening mechanisms of a cast Mg–1.48Gd–1.13Y–0.16Zr (at.%) alloy. J Mater Sci 44:4443–445410.1007/s10853-009-3672-8 ↗
10. Qian M, Zheng L, Graham D, Frost MT, Stjohn DH (2001) Settling of undissolved zirconium particles in pure magnesium melts. J Light Met 1:157–16510.1016/S1471-5317(01)00009-8 ↗
11. Qian M, Hildebrand ZCG, Stjohn DH (2009) The loss of dissolved zirconium in zirconium–refined magnesium alloys after remelting. Metall Mater Trans A 40:2470–247910.1007/s11661-009-9928-8 ↗
12. Qiu D, Zhang MX, Taylor JA, Kelly PM (2009) A new approach to designing a grain refiner for Mg casting alloys and its use in Mg–Y-based alloys. Acta Mater 57:3052–305910.1016/j.actamat.2009.03.011 ↗
13. Dai JC, Zhu SM, Easton MA, Zhang MX, Qiu D, Wu GH, Liu WC, Ding WJ (2013) Heat treatment, microstructure and mechanical properties of a Mg–Gd–Y alloy grain-refined by Al additions. Mater Sci Eng A 576:298–30510.1016/j.msea.2013.04.016 ↗
14. Yin HY, Liu ZL, Liu XQ, Fan RY, Liu Y, Li J (2017) Effects of Al addition on the microstructure and mechanical properties of Mg–4Y alloys. Mater Sci Tech Lond 33:2188–219610.1080/02670836.2017.1353664 ↗
15. Wang CL, Dai JC, Liu WC, Zhang L, Wu GH (2015) Effect of Al additions on grain refinement and mechanical properties of Mg–Sm alloys. J Alloy Compd 620:172–17910.1016/j.jallcom.2014.09.025 ↗
16. Dai JC, Easton M, Zhu SM, Wu GH, Ding WJ (2012) Grain refinement of Mg–10Gd alloy by Al additions. J Mater 27:2790–2797
17. Liu D, Song JF, Jiang B, Zeng Y, Wang QH, Jiang ZT, Liu B, Huang GS, Pan FS (2018) Effect of Al content on microstructure and mechanical properties of as-cast Mg–5Nd alloys. J Alloy Compd 737:263–27010.1016/j.jallcom.2017.11.143 ↗
18. Jiang ZT, Jiang B, Ying Z, Dai JH, Pan FS (2015) Role of Al modification on the microstructure and mechanical properties of as-cast Mg–6Ce alloys. Mater Sci Eng A 645:57–6410.1016/j.msea.2015.08.002 ↗
19. Qiu D, Zhang MX (2014) The nucleation crystallography and wettability of Mg grains on active Al2Y inoculants in an Mg-10 wt% Y Alloy. J Alloy Compd 586:39–4410.1016/j.jallcom.2013.10.042 ↗
20. Dai JC, Easton MA, Zhang MX, Qiu D, Xiong X, Liu W, Wu G (2014) Effects of cooling rate and solute content on the grain refinement of Mg–Gd–Y alloys by aluminum. Metall Mater Trans A 45:4665–467810.1007/s11661-014-2390-2 ↗
21. StJohn DH, Qian M, Easton MA, Cao P (2011) The Interdependence theory: the relationship between grain formation and nucleant selection. Acta Mater 59:4907–492110.1016/j.actamat.2011.04.035 ↗
22. Wang L, Guo EJ, Jiang W, Feng YC, Chen HT (2019) Effect of Al addition on microstructure and mechanical properties of as-cast Mg–4Y–3Nd alloy. Philos Mag 100:1–14
23. Hu XY, Fu PH, StJohn DH, Peng LM, Sun M, Zhang MX (2016) On grain coarsening and refining of the Mg–3Al alloy by Sm. J Alloy Compd 663:387–39410.1016/j.jallcom.2015.11.193 ↗
24. Li CB, Yang SQ, Du J, Liao HB, Luo G (2020) Synergistic refining mechanism of Mg–3%Al alloy refining by carbon inoculation combining with Ca addition. J Magnes Alloy 8:1090–110110.1016/j.jma.2019.12.007 ↗
25. Li JL, Chen RS, Ma YQ, Wei K (2013) Effect of Zr modification on solidification behavior and mechanical properties of Mg–Y–RE (WE54) alloy. J Magnes Alloy 1:346–35110.1016/j.jma.2013.12.001 ↗
26. Liu D, Song JF, Jiang B, Zeng Y, Wang QH, Jiang ZT, Liu B, Huang GS, Pan FS (2017) Effect of Al content on microstructure and mechanical properties of as-cast Mg–5Nd alloys. J Alloy Compd 737:263–27010.1016/j.jallcom.2017.11.143 ↗
27. Stjohn DH, Ma Q, Easton MA, Peng C, Hildebrand ZJM (2005) Grain refinement of magnesium alloys. Metall Mater Trans A 36:1669–167910.1007/s11661-005-0030-6 ↗
28. Liu ZL (2017) Review of grain refinement of cast metals through inoculation: theories and developments. Metall Mater Trans A 48:4755–477610.1007/s11661-017-4275-7 ↗
29. Easton MA, Qian M, Prasad A, Stjohn DH (2016) Recent advances in grain refinement of light metals and alloys. Curr Opin Solid State Mater Sci 20:13–2410.1016/j.cossms.2015.10.001 ↗
30. Lee YC, Dahle AK, Stjohn DH (2000) The role of solute in grain refinement of magnesium. Metall Mater Trans A 31:2895–290610.1007/BF02830349 ↗
31. Qiu D, Zhang MX (2009) Effect of active heterogeneous nucleation particles on the grain refining efficiency in an Mg–10 wt.% Y cast alloy. J Alloy Compd 488:260–26410.1016/j.jallcom.2009.08.100 ↗
32. Stiohn DH, Easton MA, Qian M, Taylor JA (2013) Grain refinement of magnesium alloys: a review of recent research, theoretical developments, and their application. Metall Mater Trans A 44:2935–294910.1007/s11661-012-1513-x ↗
33. Tamura SYH, Mclean A (2017) Effect of eutectic behavior on yield stress of Mg–La–Zr Alloys. Mater Trans 59:647–651