A layered titanium-based transition metal oxide as stable anode material for magnesium-ion batteries
Source abstract
Abstract
Rechargeable magnesium (Mg) battery with high volumetric energy density is one of the most promising candidates for next-generation safe and clean renewable energy sources. Just like rechargeable lithium battery, the development of anode materials beyond metal Mg will greatly promote the practical process of rechargeable Mg battery system. In this study, we propose a strategy to realize the reversible storage of Mg2+ in possible zero-strain layered transition metal oxides (Li2TiO3) via nanotechnology for the first time. The as-prepared layered Li2TiO3 anode shows good cycling stability with a highly reversible Mg2+ storage capacity of 110 mA h g−1. The unusual Mg storage mechanism with stable phase transition reaction is proposed by various ex situ analyzing and testing techniques which will help advance the development process of the long-life rechargeable Mg batteries.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Layered Double Hydroxides Synthesis and Applications · Magnesium Alloys: Properties and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (27)
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1. Aurbach D, Lu Z, Schechter A, Gofer Y, Gizbar H, Turgeman R, Cohen Y, Moshkovich M, Levi E (2000) Prototype systems for rechargeable magnesium batteries. Nature 407:724–72710.1038/35037553 ↗
2. Liang Y, Feng R, Yang S, Ma H, Liang J, Chen J (2011) Rechargeable Mg batteries with graphene-like MoS2 cathode and ultrasmall Mg nanoparticle anode. Adv Mater 23:640–64310.1002/adma.201003560 ↗
3. Zhang R, Ling C, Mizuno F (2015) A conceptual magnesium battery with ultrahigh rate capability. Chem Commun (Camb) 51:1487–149010.1039/C4CC08690B ↗
4. Ling C, Zhang R (2017) Manganese dioxide as rechargeable magnesium battery cathode. Front Energy Res 5:30. https://doi.org/10.3389/fenrg.2017.0003010.3389/fenrg.2017.00030 ↗
5. Wang W, Liu L, Wang PF, Zuo TT, Yin YX, Wu N, Zhou JM, Wei Y, Guo YG (2018) A novel bismuth-based anode material with a stable alloying process by the space confinement of an in situ conversion reaction for a rechargeable magnesium ion battery. Chem Commun (Camb) 54:1714–171710.1039/C7CC08206A ↗
6. Meng Y, Wang D, Zhao Y, Lian R, Wei Y, Bian X, Gao Y, Du F, Liu B, Chen G (2017) Ultrathin TiO2-B nanowires as an anode material for Mg-ion batteries based on a surface Mg storage mechanism. Nanoscale 9:12934–1294010.1039/C7NR03493H ↗
7. Wu M, Zhang Y, Li T, Chen Z, Cao S-a, Xu F (2018) Copper sulfide nanoparticles as high-performance cathode materials for magnesium secondary batteries. Nanoscale 10:12526–1253410.1039/C8NR03375G ↗
8. Niu J, Yin K, Gao H, Song M, Ma W, Peng Z, Zhang Z (2019) Composition- and size-modulated porous bismuth-tin biphase alloys as anodes for advanced magnesium ion batteries. Nanoscale 11:15279–1528810.1039/C9NR05399A ↗
9. Aurbach D, Weissman I, Gofer Y, Levi E (2003) Nonaqueous magnesium electrochemistry and its application in secondary batteries. Chem Rec 3:61–7310.1002/tcr.10051 ↗
10. Aurbach D, Suresh GS, Levi E, Mitelman A, Mizrahi O, Chusid O, Brunelli M (2007) Progress in rechargeable magnesium battery technology. Adv Mater 19:4260–426710.1002/adma.200701495 ↗
11. Muldoon J, Bucur CB, Gregory T (2014) Quest for nonaqueous multivalent secondary batteries: magnesium and beyond. Chem Rev 114:11683–1172010.1021/cr500049y ↗
12. Levi E, Levi MD, Chasid O, Aurbach D (2009) A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries. J Electroceram 22:13–1910.1007/s10832-007-9370-5 ↗
13. Cheng Y, Shao Y, Raju V, Ji X, Mehdi BL, Han KS, Engelhard MH, Li G, Browning ND, Mueller KT, Liu J (2016) Molecular storage of Mg ions with vanadium oxide nanoclusters. Adv Funct Mater 26:3446–345310.1002/adfm.201505501 ↗
14. Chakrabarti S, Biswas K (2017) DFT study of Mg2TiO4 and Ni doped Mg1.5Ni0.5TiO4 as electrode material for Mg ion battery application. J Mater Sci 52:10972–10980. https://doi.org/10.1007/s10853-017-1260-x10.1007/s10853-017-1260-x ↗
15. Pei C, Yin Y, Sun R, Xiong F, Liao X, Tang H, Tan S, Zhao Y, An Q, Mai L (2019) Interchain-expanded vanadium tetrasulfide with fast kinetics for rechargeable magnesium batteries. ACS Appl Mater Interfaces 11:31954–3196110.1021/acsami.9b09592 ↗
16. Jiao L, Yuan H, Wang Y, Cao J, Wang Y (2005) Mg intercalation properties into open-ended vanadium oxide nanotubes. Electrochem Commun 7:431–436. https://doi.org/10.1016/j.elecom.2005.02.01710.1016/j.elecom.2005.02.017 ↗
17. Liang Y, Yoo HD, Li Y, Shuai J, Calderon HA, Robles Hernandez FC, Grabow LC, Yao Y (2015) Interlayer-expanded molybdenum disulfide nanocomposites for electrochemical magnesium storage. Nano Lett 15:2194–220210.1021/acs.nanolett.5b00388 ↗
18. Wang Y, Zhou A, Dai X, Feng L, Li J, Li J (2014) Solid-state synthesis of submicron-sized Li4Ti5O12/Li2TiO3 composites with rich grain boundaries for lithium ion batteries. J Power Sources 266:114–12010.1016/j.jpowsour.2014.05.002 ↗
19. Laumann A, Fehr KT, Wachsmann M, Holzapfel M, Iversen BB (2010) Metastable formation of low temperature cubic Li2TiO3 under hydrothermal conditions—its stability and structural properties. Solid State Ionics 181:1525–152910.1016/j.ssi.2010.08.017 ↗
20. Lakshmi-Narayana A, Dhananjaya M, Guru-Prakash N, Mauger A, Julien CM, Hussain OM (2019) Li2TiO3/Ni foam composite as high-performance electrode for energy storage and conversion. Heliyon 5:e0206010.1016/j.heliyon.2019.e02060 ↗
21. Lakshmi Narayana A, Dhananjaya M, Guru Prakash N, Hussain OM, Julien CM (2017) Nanocrystalline Li2TiO3 electrodes for supercapattery application. Ionics 23:3419–342810.1007/s11581-017-2147-1 ↗
22. Lakshmi-Narayana A, Dhananjaya M, Guru-Prakash N, Hussain OM, Mauger A, Julien CM (2018) Li2TiO3/graphene and Li2TiO3/CNT composites as anodes for high power Li-ion batteries. ChemistrySelect 3:9150–915810.1002/slct.201801510 ↗
23. Kataoka K, Takahashi Y, Kijima N, Nagai H, Akimoto J, Idemoto Y, Ohshima K-i (2009) Crystal growth and structure refinement of monoclinic Li2TiO3. Mater Res Bull 44:168–17210.1016/j.materresbull.2008.03.015 ↗
24. Yu C-L, Yanagisawa K, Kamiya S, Kozawa T, Ueda T (2014) Monoclinic Li2TiO3 nano-particles via hydrothermal reaction: processing and structure. Ceram Int 40:1901–190810.1016/j.ceramint.2013.07.097 ↗
25. Watanabe A, Matsunaga T, Abulikemu A, Shimoda K, Yamamoto K, Uchiyama T, Uchimoto Y (2020) Structural analysis of imperfect Li2TiO3 crystals. Journal Alloys Compd 819:15303710.1016/j.jallcom.2019.153037 ↗
26. Wu N, Yang ZZ, Yao HR, Yin YX, Gu L, Guo YG (2015) Improving the electrochemical performance of the Li4Ti5O12 electrode in a rechargeable magnesium battery by lithium-magnesium co-intercalation. Angew Chem Int Ed Engl 54:5757–576110.1002/anie.201501005 ↗
27. Wu N, Lyu YC, Xiao RJ, Yu X, Yin YX, Yang XQ, Li H, Gu L, Guo YG (2014) A highly reversible, low-strain Mg-ion insertion anode material for rechargeable Mg-ion batteries. NPG Asia Mater 6:e120–e12010.1038/am.2014.61 ↗