A high compatibility SiOCN coating on stainless steel
Source abstract
Abstract
In this study, a unique SiOCN ceramic coating with exceptional compliance has been developed using perhydropolysilazane and polysiloxane preceramic polymers. The coating layers are defect-free and smooth with < 42 nm average surface roughness. The inter-diffusion of Si, C, and N further enhances the coating integration. The SiOCN coating has a hardness of 6.3 $$pm$$ 0.7 GPa and shows plastic deformation. With repeated thermal quenching, the SiOCN hybrid coating stays intact and demonstrates a compliant deformation behavior, which has never been observed for polymer-derived ceramic coatings. This coating has great potential in corrosion prevention of steel substrates in different harsh environments, especially for nuclear waste storage canisters.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced ceramic materials synthesis · Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (54)
Show source-provided references
1. Gardner L, Harward A, Howard J, Fredrickson G, Yoo T-S, Simpson M, Carlson K (2022) Deliquescence of eutectic LiCl-KCl diluted with NaCl for interim waste salt storage. Nucl Technol 208:310–31710.1080/00295450.2021.1889923 ↗
2. Chopra OK, Diercks DR, Fabian RR, Han ZH, Liu YY (2014) Managing aging effects on dry cask storage systems for extended long-term storage and transportation of used fuel (REV. 2), United States, p. Medium: ED10.2172/1159908 ↗
3. Guo X, Gin S, Frankel GS (2020) Review of corrosion interactions between different materials relevant to disposal of high-level nuclear waste. npj Mater Degrad 4:3410.1038/s41529-020-00140-7 ↗
4. Lee KN (2000) Current status of environmental barrier coatings for Si-Based ceramics. Surf Coat Technol 133–134:1–7
5. Tomastik J, Ctvrtlik R (2016) Tribological properties of magnetron sputtered amorphous silicon carbide and silicon carbonitride coatings. Defect Diffus Forum 368:91–9410.4028/www.scientific.net/DDF.368.91 ↗
6. Barroso G, Li Q, Bordia RK, Motz G (2019) Polymeric and ceramic silicon-based coatings–a review. J Mater Chem A 7:1936–196310.1039/C8TA09054H ↗
7. Fukushima M, Yasuda E, Nakamura Y, Kita H, Kawabata H, Tanabe Y (2005) Preparation of a transition metal containing polymethylsilsesquioxane hybrids and silicon oxycarbide ceramics. J Ceram Soc Jpn 113:210–21510.2109/jcersj.113.210 ↗
8. Pivin JC, Colombo P, Martucci A, Sorarù GD, Pippel E, Sendova-Vassileva M (2003) Ion beam induced conversion of Si-based polymers and gels layers into ceramics coatings. J Sol Gel Sci Technol 26:251–25510.1023/A:1020759301482 ↗
9. Gunthner M, Kraus T, Dierdorf A, Decker D, Krenkel W, Motz G (2009) Advanced coatings on the basis of Si(C)N precursors for protection of steel against oxidation. J Eur Ceram Soc 29:2061–206810.1016/j.jeurceramsoc.2008.11.013 ↗
10. Erb D, Lu K (2018) Effects of SiO2-forming additive on polysiloxane derived SiOC ceramics. Microporous Mesoporous Mater 266:75–8210.1016/j.micromeso.2018.02.034 ↗
11. Torrey JD, Bordia RK (2008) Processing of polymer-derived ceramic composite coatings on steel. J Am Ceram Soc 91:41–4510.1111/j.1551-2916.2007.02019.x ↗
12. Parchoviansky M, Petrikova I, Barroso GS, Svancarek P, Galuskova D, Motz G, Galusek D (2018) Corrosion and oxidation behavior of polymer derived ceramic coatings with passive glass fillers on AISI 441 Stainless Steel. Ceram Silikaty 62:146–15710.13168/cs.2018.0006 ↗
13. Lukacs A (2006) Polysilazane precursors to advanced ceramics, Materials Science & Technology Conference Processing, American Ceramic Society Bulletin, Cincinnati, OH, USA, 2007, pp 9301–9306
14. Colombo P, Paulson TE, Pantano CG (1994) Atmosphere effects in the processing of silicon carbide and silicon oxycarbide thin films and coatings. J Sol Gel Sci Technol 2:601–60410.1007/BF00486317 ↗
15. Xu J, Favergeon J, Mazeran PE, Moulin G, Vu C (2011) Use of silicon-based coating for high temperature protection of metallic alloys. Mater Sci Forum 696:308–31310.4028/www.scientific.net/MSF.696.308 ↗
16. Badzian A, Badzian T, Drawl WD, Roy R (1998) Silicon carbonitride: a rival to cubic boron nitride. Diam Relat Mater 7:1519–152510.1016/S0925-9635(98)00228-3 ↗
17. Hoche H, Allebrandt D, Bruns M, Riedel R, Fasel C (2008) Relationship of chemical and structural properties with the tribological behavior of sputtered SiCN films. Surf Coat Technol 202:5567–557110.1016/j.surfcoat.2008.06.126 ↗
18. Riedel R, Kleebe HJ, Schonfelder H, Aldinger F (1995) A covalent micro nanocomposite resistant to high-temperature oxidation. Nature 374:526–52810.1038/374526a0 ↗
19. An L, Riedel R, Konetschny C, Kleebe HJ, Raf R (1998) Newtonian viscosity of amorphous silicon carbonitride at high temperature. J Am Ceram Soc 81:1349–135210.1111/j.1151-2916.1998.tb02489.x ↗
20. Gunthner M, Wang K, Bordia RK, Motz G (2012) Conversion behaviour and resulting mechanical properties of polysilazane-based coatings. J Eur Ceram Soc 32:1883–189210.1016/j.jeurceramsoc.2011.09.005 ↗
21. Tomastik J, Ctvrtlik R, Ingr T, Manak J, Opletalova A (2018) Effect of nitrogen doping and temperature on mechanical durability of silicon carbide thin films. Sci Rep 8:1042810.1038/s41598-018-28704-3 ↗
22. Alipour Skandani A, Ctvrtlik R, Al-Haik M (2014) Nanocharacterization of the negative stiffness of ferroelectric materials. Appl Phys Lett 105:08290610.1063/1.4894274 ↗
23. Blankenburg L, Schrodner M (2015) Perhydropolysilazane derived silica for flexible transparent barrier foils using a reel-to-reel wet coating technique: Single- and multilayer structures. Surf Coat Technol 275:193–20610.1016/j.surfcoat.2015.05.019 ↗
24. Chen ZF, Li GJ, Wang LY, Lin YL, Zhou W (2018) A strategy for constructing superhydrophobic multilayer coatings with self-cleaning properties and mechanical durability based on the anchoring effect of organopolysilazane. Mater Des 141:37–4710.1016/j.matdes.2017.12.034 ↗
25. Barroso G, Li Q, Bordia RK, Motz G (2019) Polymeric and ceramic silicon-based coatings-a review. J Mater Chem A 7:1936–196310.1039/C8TA09054H ↗
26. Yang N, Lu K (2020) Porous and ultrahigh surface area SiOC ceramics based on perhydropolysilazane and polysiloxane. Microporous Mesoporous Mater 306:11047710.1016/j.micromeso.2020.110477 ↗
27. Yang N, Wang W, Cai W, Lu K (2020) Corrosion and tribocorrosion mitigation of perhydropolysilazane-derived coatings on low carbon steel. Corros Sci 177:10894610.1016/j.corsci.2020.108946 ↗
28. Channa IA, Shah AA, Rizwan M, Makhdoom MA, Chandio AD, Shar MA, Mahmood A (2021) Process parameter optimization of a polymer derived ceramic coatings for producing ultra-high gas barrier. Materials (Basel) 14:700010.3390/ma14227000 ↗
29. Channa IA, Distler A, Zaiser M, Brabec CJ, Egelhaaf H-J (2019) Thin film encapsulation of organic solar cells by direct deposition of polysilazanes from solution. Adv Energy Mater 9:190059810.1002/aenm.201900598 ↗
30. Han D, Wang Y, Pan Y, Qiu J, Wang J, Wang C, Liu H (2022) Influence of spraying perhydropolysilazane coating on friction and wear of end-face metal during the mixing process. Polym Testing 115:10774310.1016/j.polymertesting.2022.107743 ↗
31. Saito R, Kobayashi S-I, Hayashi H, Shimo T (2007) Surface hardness and transparency of poly(methyl methacrylate)-silica coat film derived from perhydropolysilazane. J Appl Polym Sci 104:3388–339510.1002/app.25943 ↗
32. Ohishi T, Yanagida K (2016) Preparation and gas barrier characteristics of polysilazane derived multi-layered silica thin films formed on alicyclic polyimide film using ultraviolet irradiation. Front Nanosci Nanotechnol 2:173–17810.15761/FNN.1000131 ↗
33. Gunthner M, Kraus T, Krenkel W, Motz G, Dierdorf A, Decker D (2009) Particle-filled PHPS silazane-based coatings on steel. Int J Appl Ceram Technol 6:373–38010.1111/j.1744-7402.2008.02346.x ↗
34. Bauer F, Decker U, Dierdorf A, Ernst H, Heller R, Liebe H, Mehnert R (2005) Preparation of moisture curable polysilazane coatings: part I elucidation of low temperature curing kinetics by FT-IR spectroscopy. Prog Org Coat 53:183–19010.1016/j.porgcoat.2005.02.006 ↗
35. Bawane K, Lu K, Li Q, Bordia R (2020) High temperature oxidation behaviors of SiON coated AISI 441 in Ar+O2, Ar+H2O, and Ar+CO2 atmospheres. Corros Sci 166:10842910.1016/j.corsci.2020.108429 ↗
36. Wang W, Tamakloe S, Deng Z, Li L, Cai W, Lu K (2022) Effects of processing temperature on the corrosion and tribocorrosion resistance of perhydropolysilazane-derived coatings on AISI 304 steel. Surf Coat Technol 439:12846310.1016/j.surfcoat.2022.128463 ↗
37. Adigun OD, Ricohermoso E III, Daniyan AA, Umoru LE, Ionescu E (2022) Structure and electrical properties of carbon-rich polymer derived silicon carbonitride (SiCN). Ceramics 5:690–70510.3390/ceramics5040050 ↗
38. Boden G, Neumann A, Breuning T, Tschernikova E, Hermel W (1998) Nanosized Si-C-N-powders by polysilazane pyrolysis and Si3N4/SiC-composite materials thereof. J Eur Ceram Soc 18:1461–146910.1016/S0955-2219(98)00015-6 ↗
39. Kleebe H-J, Stoermer H, Trassl S, Ziegler G (2001) Thermal stability of SiCN ceramics studied by spectroscopy and electron microscopy. Appl Organomet Chem 15:858–86610.1002/aoc.243 ↗
40. Yang N, Lu K (2019) Thermophysical property and electrical conductivity of titanium isopropoxide–polysiloxane derived ceramics. J Eur Ceram Soc 39:4029–403710.1016/j.jeurceramsoc.2019.06.020 ↗
41. Lu K, Erb D (2018) Polymer derived silicon oxycarbide-based coatings. Int Mater Rev 63:139–16110.1080/09506608.2017.1322247 ↗
42. Ma R, Lu K, Erb D (2018) Effect of solvent in preparation of SiOC bulk ceramics. Mater Chem Phys 218:140–14610.1016/j.matchemphys.2018.07.043 ↗
43. Ma R, Erb D, Lu K (2018) Flash pyrolysis of polymer-derived SiOC ceramics. J Eur Ceram Soc 38:4906–491410.1016/j.jeurceramsoc.2018.07.010 ↗
44. Bawane K, Erb D, Lu K (2019) Carbon content and pyrolysis atmosphere effects on phase development in SiOC systems. J Eur Ceram Soc 39:2846–285410.1016/j.jeurceramsoc.2019.03.032 ↗
45. Su Q, Zhernenkov M, Ding H, Price L, Haskel D, Watkins EB, Majewski J, Shao L, Demkowicz MJ, Nastasi M (2017) Reaction of amorphous/crystalline SiOC/Fe interfaces by thermal annealing. Acta Mater 135:61–6710.1016/j.actamat.2017.06.020 ↗
46. Beake BD, Goodes SR, Smith JF, Madani R, Rego CA, Cherry RI, Wagner T (2002) Investigating the fracture resistance and adhesion of DLC films with micro-impact testing. Diam Relat Mater 11:1606–160910.1016/S0925-9635(02)00107-3 ↗
47. Leyland A, Matthews A (2000) On the significance of the H/E ratio in wear control: a nanocomposite coating approach to optimised tribological behaviour. Wear 246:1–1110.1016/S0043-1648(00)00488-9 ↗
48. Matthews A, Leyland A (2000) Developments in PVD tribological coatings, 5th ASM heat treatment and surface engineering conf. Europe. Gothenburg, Sweden, p 12
49. Beake BD, Vishnyakov VM, Harris AJ (2011) Relationship between mechanical properties of thin nitride-based films and their behaviour in nano-scratch tests. Tribol Int 44:468–47510.1016/j.triboint.2010.12.002 ↗
50. Vasinonta A, Beuth JL (2001) Measurement of interfacial toughness in thermal barrier coating systems by indentation. Eng Fract Mech 68:843–86010.1016/S0013-7944(00)00130-2 ↗
51. Vivar Mora L, Taylor A, Paul S, Dawson R, Wang C, Taleb W, Owen J, Neville A, Barker R (2018) Impact of silica nanoparticles on the morphology and mechanical properties of sol-gel derived coatings. Surf Coat Technol 342:48–5610.1016/j.surfcoat.2018.02.080 ↗
52. Meng F, Wong LNY, Zhou H (2021) Rock brittleness indices and their applications to different fields of rock engineering: a review. J Rock Mech Geotech Eng 13:221–24710.1016/j.jrmge.2020.06.008 ↗
53. Innocenzi P, Esposto M, Maddalena A (2001) Mechanical properties of 3-glycidoxypropyltrimethoxysilane based hybrid organic-inorganic materials. J Sol-Gel Sci Technol 20:293–30110.1023/A:1008782203971 ↗
54. Skordaris G, Bouzakis KD, Charalampous P, Bouzakis E, Paraskevopoulou R, Lemmer O, Bolz S (2014) Brittleness and fatigue effect of mono- and multi-layer PVD films on the cutting performance of coated cemented carbide inserts. CIRP Ann 63:93–9610.1016/j.cirp.2014.03.081 ↗