journal article·2020-12

The effect of Ni-doping on the microstructure, hot deformation behavior, and processing map of as-cast Al–Si piston alloy

M. Mirzaee-Moghadam, Sh. Zangeneh, H. R. Lashgari, S. Rasaee, M. Mojtahedi

Journal of Materials Science· Volume 55· Issue 34
Publisher page

Abstract

Al–Si alloy is widely utilized in automobile pistons and cylinders due to good castability, high strength-to-weight ratio, excellent thermal conductivity, good resistance to corrosion/oxidation, and acceptable wear resistance. To increase the efficiency of engine motor, it is imperative to modify and engineer the microstructure of Al–Si alloy to enhance the high-temperature behavior. For this reason, in the current study, different concentration of Ni (0.8% and 2%) was doped into Al–Si alloy during casting to generate various Ni-rich intermetallic compounds within the alloy matrix. AlNiCu, AlCu, AlFeSi, and Mg2Si were found to be the main intermetallic compounds precipitated within the dendritic and interdendritic regions, which could enhance the thermal stability and high-temperature performance. High-temperature compression test at high temperatures ranging from 400 to 550 °C and at different strain rates ranging from 10−3 to 1 s−1 was carried out to develop high-temperature processing map and optimize the hot workability parameters of Ni-doped Al–Si alloy. The maximum power dissipation efficiency (η) was observed within the temperature range of 450–500 °C and strain rate of 0.05–0.08 s−1 (lower strain rate) for Al–Si–0.8%Ni alloy and within the temperature range of 450–500 °C and strain rate of 0.3–1 s−1 (medium to high strain rate) for Al–Si–2%Ni alloy. Dynamic recrystallization was found to be the primary softening mechanism at high temperatures (T > 450 °C).
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Research context

OpenAlex topics: Metallurgy and Material Forming · Aluminum Alloy Microstructure Properties · Microstructure and mechanical properties

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References (56)

Show source-provided references
1. Javidani M, Larouche D (2014) Application of cast Al–Si alloys in internal combustion engine components. Int Mater Rev 59:132–15810.1179/1743280413Y.0000000027 ↗
2. Manasijevic S, Pavlovic-Acimovic Z, Raic K, Radisa R, Kvrgić V (2013) Optimisation of cast pistons made of Al–Si piston alloy. Int J Cast Met Res 26:255–26110.1179/1743133612Y.0000000007 ↗
3. Manasijevic S, Radisa R, Markovic S, Acimovic-Pavlovic Z, Raic K (2011) Thermal analysis and microscopic characterization of the piston alloy AlSi13Cu4Ni2Mg. Intermetallics 19:486–49210.1016/j.intermet.2010.11.011 ↗
4. Azadi M, Winter G, Farrahi G, Eichlseder W (2012) Design of cylinder head and block in international combustion engines based on fatigue strength of materials. In: 8th international conference on internal combustion engines and oil
5. Hoag K, Dondlinger B (2015) Vehicular engine design. Springer, Berlin
6. Ahmad Z (2011) Recent trends in processing and degradation of aluminium alloys. BoD–Books on Demand, Norderstedt10.5772/741 ↗
7. Yang Y, Zhong S-Y, Chen Z, Wang M, Ma N, Wang H (2015) Effect of Cr content and heat-treatment on the high temperature strength of eutectic Al–Si alloys. J Alloy Compd 647:63–6910.1016/j.jallcom.2015.05.167 ↗
8. Belov N, Eskin D, Avxentieva NN (2005) Constituent phase diagrams of the Al–Cu–Fe–Mg–Ni–Si system and their application to the analysis of aluminium piston alloys. Acta Mater 53:4709–472210.1016/j.actamat.2005.07.003 ↗
9. Manasijevic S, Dolić N, Raic K, Radiša R (2014) Identification of phases formed by Cu and Ni in Al–Si piston alloys. La Metallurgia Italiana 106:13
10. Sjölander E, Seifeddine S (2010) The heat treatment of Al–Si–Cu–Mg casting alloys. J Mater Process Technol 210:1249–125910.1016/j.jmatprotec.2010.03.020 ↗
11. Taylor J, St John D, Barresi J, Couper M (2000) An empirical analysis of trends in mechanical properties of T6 heat treated Al-Si-Mg casting alloys. Int J Cast Met Res 12:419–43010.1080/13640461.2000.11819379 ↗
12. Zeren M, Karakulak E, Gümüş S (2011) Influence of Cu addition on microstructure and hardness of near-eutectic Al-Si-xCu-alloys. Trans Nonferrous Metals Soc China 21:1698–170210.1016/S1003-6326(11)60917-5 ↗
13. Dinnis C, Taylor J, Dahle A (2005) As-cast morphology of iron-intermetallics in Al–Si foundry alloys. Scr Mater 53:955–95810.1016/j.scriptamat.2005.06.028 ↗
14. Couture A (1981) Iron in aluminum casting alloys—a literature survey. Int Cast Metals J 6:9–17
15. Asghar Z, Requena G, Boller E (2011) Three-dimensional rigid multiphase networks providing high-temperature strength to cast AlSi10Cu5Ni1-2 piston alloy. Acta Mater 59:6420–643210.1016/j.actamat.2011.07.006 ↗
16. Medrano-Prieto HM, Garay-Reyes CG, Estrada-Guel I, Mendoza-Duarte JM, Guía-Tello JC, Ochoa-Gamboa RA, Ornelas-Gutiérrez CE, Rodríguez-Cabriales G, Castro-Carmona JS, Camacho-Montes H, Maldonado-Orozco MC, Martínez-Sánchez R (2020) Effect of Ni additions and hot deformation on precipitation behavior and hardness in Al–Si–Mg aged alloys. J Alloy Compd 828:15442910.1016/j.jallcom.2020.154429 ↗
17. Fang G, Zeng P (2006) Investigation of thermal formability of aluminum alloy 4032. J Mater Eng Perform 15:535–53910.1361/105994906X136043 ↗
18. Lee SY, Jung TK, Son HW, Kim SW, Son KT, Choi HJ, Oh SH, Lee J, Hyun SK (2018) Hot deformation behavior of hot-extruded AA7175 through hot torsion tests. J Nanosci Nanotechnol 18:2144–214710.1166/jnn.2018.14988 ↗
19. Lobanov ML, Loginov YN, Danilov SV, Golovin MA, Karabanalov MS (2018) Effect of hot rolling rate on the structure and texture condition of plates of the Al–Si–Mg alloy system. Met Sci Heat Treat 60:322–32810.1007/s11041-018-0279-1 ↗
20. Xu C, Zheng R, Hanada S, Xiao W, Ma C (2018) Effect of hot extrusion and subsequent T6 treatment on the microstructure evolution and tensile properties of an Al-6Si-2Cu-0.5 Mg alloy. Mater Sci Eng A 710:102–11010.1016/j.msea.2017.10.052 ↗
21. Lin YC, Xia Y-C, Chen X-M, Chen M-S (2010) Constitutive descriptions for hot compressed 2124-T851 aluminum alloy over a wide range of temperature and strain rate. Comput Mater Sci 50:227–23310.1016/j.commatsci.2010.08.003 ↗
22. Lin Y, Chen X-M (2011) A critical review of experimental results and constitutive descriptions for metals and alloys in hot working. Mater Des 32:1733–175910.1016/j.matdes.2010.11.048 ↗
23. Abbasi-Bani A, Zarei-Hanzaki A, Pishbin MH, Haghdadi N (2014) A comparative study on the capability of Johnson-Cook and Arrhenius-type constitutive equations to describe the flow behavior of Mg–6Al–1Zn alloy. Mech Mater 71:52–6110.1016/j.mechmat.2013.12.001 ↗
24. Sellars CM, McTegart W (1966) On the mechanism of hot deformation. Acta Metall 14:1136–113810.1016/0001-6160(66)90207-0 ↗
25. Chen L, Zhao G, Yu J (2015) Hot deformation behavior and constitutive modeling of homogenized 6026 aluminum alloy. Mater Des 74:25–3510.1016/j.matdes.2015.02.024 ↗
26. Rokni MR, Zarei-Hanzaki A, Roostaei AA, Abolhasani A (2011) Constitutive base analysis of a 7075 aluminum alloy during hot compression testing. Mater Des 32:4955–496010.1016/j.matdes.2011.05.040 ↗
27. Phaniraj C, Samantaray D, Mandal S, Bhaduri AK (2011) A new relationship between the stress multipliers of Garofalo equation for constitutive analysis of hot deformation in modified 9Cr–1Mo (P91) steel. Mater Sci Eng A 528:6066–607110.1016/j.msea.2011.04.025 ↗
28. Wu W-X, Jin L, Dong J, Ding W-J (2012) Prediction of flow stress of Mg–Nd–Zn–Zr alloy during hot compression. Trans Nonferrous Metals Soc China 22:1169–117510.1016/S1003-6326(11)61301-0 ↗
29. Li W, Li H, Wang Z, Zheng Z (2011) Constitutive equations for high temperature flow stress prediction of Al–14Cu–7Ce alloy. Mater Sci Eng A 528:4098–410310.1016/j.msea.2011.01.076 ↗
30. Prasad Y (1990) Recent advances in the science of mechanical processing. Indian J Technol 28:435–451
31. Prasad YVRK, Kamineni P, Sasidhara S (2015) Hot working guide. ASM International, US
32. Sun Y, Cao Z, Wan Z, Hu L, Ye W, Li N, Fan C (2018) 3D processing map and hot deformation behavior of 6A02 aluminum alloy. J Alloy Compd 742:356–36810.1016/j.jallcom.2018.01.299 ↗
33. Prasad YVRK, Gegel HL, Doraivelu SM, Malas JC, Morgan JT, Lark KA, Barker DR (1984) Modeling of dynamic material behavior in hot deformation: forging of Ti-6242. Metall Trans A 15:1883–189210.1007/BF02664902 ↗
34. Wen D-X, Lin YC, Li H-B, Xiao-Min C, Deng J, Li L-T (2014) Hot deformation behavior and processing map of a typical Ni-based superalloy. Mater Sci Eng A 591:183–19210.1016/j.msea.2013.09.049 ↗
35. Ou L, Zheng Z, Nie Y, Jian H (2015) Hot deformation behavior of 2060 alloy. J Alloy Compd 648:681–68910.1016/j.jallcom.2015.07.027 ↗
36. Poletti M, Degischer HP, Kremmer S, Marketz W (2008) Processing maps of Ti662 unreinforced and reinforced with TiC particles according to dynamic models. Mater Sci Eng A-Struct Mater 486:127–13710.1016/j.msea.2007.08.077 ↗
37. McQueen HJ, Evangelista E, Jin N, Kassner ME (1995) Energy dissipation efficiency in aluminum dependent on monotonic flow curves and dynamic recovery. Metall Mater Trans A 26:1757–176610.1007/BF02670763 ↗
38. Meng G, Li B, Li H, Huang H, Nie Z (2009) Hot deformation and processing maps of an Al–5.7wt.%Mg alloy with erbium. Mater Sci Eng A 517:132–13710.1016/j.msea.2009.03.068 ↗
39. Zhang J, Di H, Wang H, Mao K, Ma T, Cao Y (2012) Hot deformation behavior of Ti-15-3 titanium alloy: a study using processing maps, activation energy map, and Zener-Hollomon parameter map. J Mater Sci 47:4000–4011. https://doi.org/10.1007/s10853-012-6253-110.1007/s10853-012-6253-1 ↗
40. Son H-W, Jung T-K, Lee J-W, Hyun S-K (2017) Hot deformation characteristics of CaO-added AZ31 based on kinetic models and processing maps. Mater Sci Eng A 695:379–38510.1016/j.msea.2017.03.058 ↗
41. Malas JC III (1991) Methodology for design and control of thermomechanical processes. Ohio University, Athens
42. Hu HE, Wang X, Deng L (2013) High temperature deformation behavior and optimal hot processing parameters of Al–Si eutectic alloy. Mater Sci Eng A 576:45–5110.1016/j.msea.2013.03.059 ↗
43. Cheng W, Bai Y, Ma S, Wang L, Wang H, Yu H (2018) Hot deformation behavior and workability characteristic of a fine-grained Mg-8Sn-2Zn-2Al alloy with processing map. J Mater Sci Technol 35:1198–120910.1016/j.jmst.2018.12.001 ↗
44. Sunil B, Rajeev VR, Jose S (2018) A statistical study on the dry wear and friction characteristics of Al-12.6Si-3Cu- (2-2.6wt.%) Ni piston alloys. Mater Today Proc 5:1131–113710.1016/j.matpr.2017.11.193 ↗
45. Tahreen N, Zhang DF, Pan FS, Jiang XQ, Li C, Li DY, Chen DL (2015) Characterization of hot deformation behavior of an extruded Mg–Zn–Mn–Y alloy containing LPSO phase. J Alloy Compd 644:814–82310.1016/j.jallcom.2015.04.144 ↗
46. McQueen HJ, Ryan ND (2002) Constitutive analysis in hot working. Mater Sci Eng A 322:43–6310.1016/S0921-5093(01)01117-0 ↗
47. Li C, Liu Y, Tan Y, Zhao F (2018) Hot deformation behavior and constitutive modeling of H13-mod steel. Metals 8:84610.3390/met8100846 ↗
48. Sellars C, Tegart W (1966) Relationship between strength and structure in deformation at elevated temperatures. Mem Sci Rev Met 63:731–746
49. Zhou Z, Fan Q, Xia Z, Hao A, Yang W, Ji W, Cao H (2017) Constitutive relationship and hot processing maps of Mg-Gd-Y-Nb-Zr alloy. J Mater Sci Technol 33:637–64410.1016/j.jmst.2015.10.019 ↗
50. Zong Y, Shan D, Shi Z (2011) Study on hot deformation behaviour and constitutive equation of 4032 Al alloy. Mater Res Innov 15:s470–s47410.1179/143307511X12858957675877 ↗
51. Prasad YVRK (2003) Processing maps: a status report. J Mater Eng Perform 12:638–64510.1361/105994903322692420 ↗
52. Gholizadeh R, Shabestari SG (2011) Investigation of the effects of Ni, Fe, and Mn on the formation of complex intermetallic compounds in Al-Si-Cu-Mg-Ni alloys. Metall Mater Trans A 42:3447–345810.1007/s11661-011-0764-2 ↗
53. Zuo L, Ye B, Feng J, Zhang H, Kong X, Jiang H (2020) Effect of ε-Al3Ni phase on mechanical properties of Al–Si–Cu–Mg–Ni alloys at elevated temperature. Mater Sci Eng A 772:13879410.1016/j.msea.2019.138794 ↗
54. Li Y, Yang Y, Wu Y, Wang L, Liu X (2010) Quantitative comparison of three Ni-containing phases to the elevated-temperature properties of Al–Si piston alloys. Mater Sci Eng A 527:7132–713710.1016/j.msea.2010.07.073 ↗
55. Kawashima N, Nakamura Y (1952) Study on the recrystallization temperature of refined high purity aluminium (3rd report). The effect of small amounts of impurities. J Jpn Inst Metals Mater 16:26–2910.2320/jinstmet1952.16.1_26 ↗
56. Lasa L, Rodriguez-Ibabe J (2004) Evolution of the main intermetallic phases in Al-Si-Cu-Mg casting alloys during solution treatment. J Mater Sci 39:1343–1355. https://doi.org/10.1023/B:JMSC.0000013895.72084.c910.1023/B:JMSC.0000013895.72084.c9 ↗