journal article·2018-05

C-doped Cr2O3/NaY composite membrane supported on stainless steel mesh with enhanced photocatalytic activity for cyclohexane oxidation

Xiaoxia Zhao, Ying Zhang, Ping Qiu, Ping Wen, Hui Wang, Guang Xu, Yang Han

Journal of Materials Science· Volume 53· Issue 9
Publisher page

Abstract

In this study, a C-doped Cr2O3/NaY composite membrane supported on stainless steel mesh with layer-by-layer structure was successfully synthesized and used in the partial oxidation of cyclohexane. In the composite membrane, NaY zeolite membrane acted as absorbent and the C-doped Cr2O3 behaved as photocatalyst, which was successfully prepared using a chromium-containing MOF as precursor. The supported composite membrane was characterized by a series of analysis techniques. Comparing with the stainless steel mesh-supported C-doped Cr2O3 membrane, the supported C-doped Cr2O3/NaY composite membrane exhibited superior visible-light-driven photocatalytic performance for cyclohexane oxidation. This is due to its layer-by-layer structure and NaY membrane with high surface areas and polarity which can preferentially adsorb KA oil products, avoiding their overoxidation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Shi C-F et al (2011) Cyclohexane mild oxidation catalyzed by new titanosilicate with hollow structure. Catal Today 175:398–40310.1016/j.cattod.2011.05.012 ↗
2. Du P et al (2006) Selective photo(catalytic)-oxidation of cyclohexane: effect of wavelength and TiO2 structure on product yields. J Catal 238:342–35210.1016/j.jcat.2005.12.011 ↗
3. Hattori H et al (2012) Efficient and selective photocatalytic cyclohexane oxidation on a layered titanate modified with iron oxide under sunlight and CO2 atmosphere. ACS Catal 2:1910–191510.1021/cs300339f ↗
4. Li J et al (2010) Selective oxidation of cyclohexane over transition-metal-incorporated HMS in a solvent-free system. Ind Eng Chem Res 49:5392–539910.1021/ie100092x ↗
5. Li J et al (2010) Selective oxidation of cyclohexane by oxygen in a solvent-free system over lanthanide-containing AlPO-5. Catal Lett 137:180–18910.1007/s10562-010-0352-x ↗
6. Zhou J-C et al (2014) An efficient oxidation of cyclohexane over Au@TiO2/MCM-41 catalyst prepared by photocatalytic reduction method using molecular oxygen as oxidant. Catal Commun 46:228–23310.1016/j.catcom.2013.12.026 ↗
7. Zhong W-Z et al (2015) Visible-light-responsive sulfated vanadium-doped TS-1 with hollow structure: enhanced photocatalytic activity in selective oxidation of cyclohexane. J Catal 330:208–22110.1016/j.jcat.2015.06.013 ↗
8. Shiraishi Y et al (2012) Visible light-induced partial oxidation of cyclohexane on WO3 loaded with Pt nanoparticles. Catal Sci Technol 2:400–40510.1039/C1CY00331C ↗
9. Tsukamoto D et al (2011) Visible-light-induced partial oxidation of cyclohexane by Cr/Ti/Si ternary mixed oxides with molecular oxygen. J Phys Chem C 115:19782–1978810.1021/jp2055552 ↗
10. Shiraishi Y et al (2006) Visible light-induced partial oxidation of olefins on Cr-containing silica with molecular oxygen. J Phys Chem B 110:6257–626310.1021/jp056845k ↗
11. Shiraishi Y et al (2008) Visible light-induced partial oxidation of cyclohexane on hydrophobically modified chromium-containing mesoporous silica with molecular oxygen. J Catal 254:365–37310.1016/j.jcat.2008.01.016 ↗
12. Wang H et al (2016) Synthesis of C–N dual-doped Cr2O3 visible light-driven photocatalyst derived from metal organic framework (MOF) for cyclohexane oxidation. RSC Adv 6:84871–8488110.1039/C6RA09908D ↗
13. Kamegawa T et al (2013) Design of TiO2-zeolite composites with enhanced photocatalytic performances under irradiation of UV and visible light. Microporous Mesoporous Mater 165:142–14710.1016/j.micromeso.2012.08.013 ↗
14. Cheng Z-L, Han S (2016) Preparation of a novel composite electrode based on N-doped TiO2-coated NaY zeolite membrane and its photoelectrocatalytic performance. Chin Chem Lett 27:467–47010.1016/j.cclet.2015.12.010 ↗
15. Guesh K et al (2016) Enhanced photocatalytic activity of TiO2 supported on zeolites tested in real wastewaters from the textile industry of Ethiopia. Microporous Mesoporous Mater 225:88–9710.1016/j.micromeso.2015.12.001 ↗
16. Kuwahara Y et al (2012) TiO2 photocatalyst for degradation of organic compounds in water and air supported on highly hydrophobic FAU zeolite: structural, sorptive, and photocatalytic studies. J Catal 285:223–23410.1016/j.jcat.2011.09.031 ↗
17. Guesh K et al (2016) Enhanced photocatalytic activity of supported TiO2 by selective surface modification of zeolite Y. Appl Surf Sci 378:473–47810.1016/j.apsusc.2016.04.029 ↗
18. Ide Y et al (2013) Layered silicate as an excellent partner of a TiO2 photocatalyst for efficient and selective green fine-chemical synthesis. J Am Chem Soc 135:11784–1178610.1021/ja406855e ↗
19. Yin X-J et al (2007) Zeolite P/NaX composite membrane for gas separation. Microporous Mesoporous Mater 105:156–16210.1016/j.micromeso.2007.06.028 ↗
20. Férey G et al (2005) A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309:2040–204210.1126/science.1116275 ↗
21. Mu W et al (1989) Room temperature photocatalytic oxidation of liquid cyclohexane into cyclohexanone over neat and modified TiO2. Catal Lett 3:73–8410.1007/BF00765057 ↗
22. Duan X-G et al (2015) Selective oxidation of cyclohexane on a novel catalyst Mg-Cu/SBA-15 by molecular oxygen. Dalton Trans 44:17381–1738810.1039/C5DT01803J ↗
23. Hwang K-C et al (2014) One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light. Science 346:1495–149810.1126/science.1259684 ↗
24. Xu Y, Schoonen MAA (2000) The absolute energy positions of conduction and valence bands of selected semiconducting minerals. Am Mineral 85:543–55610.2138/am-2000-0416 ↗