Corrosion performance of reinforced mortar in the presence of polymeric nano-aggregates: electrochemical behavior, surface analysis, and properties of the steel/cement paste interface
Source abstract
Abstract
This study reports on the effect of admixed polyethylene oxide-b-polystyrene (PEO113-b-PS70) micelles on corrosion behavior of reinforced mortar. The electrochemical measurement shows that the corrosion performance of the reinforcing steel was not significantly improved. However, surface analysis and microstructural investigation at the steel/cement paste interface reveal that the admixed micelles lead to a steel surface layer with enhanced barrier properties in terms of morphology and composition. Therefore, the presence of micelles further minimized and halted the corrosion process, despite the very aggressive, chloride-containing environment of 5% NaCl. The reasons and mechanisms behind the hereby observed corrosion behavior of reinforced mortar in the presence of micelles are related to the influence of these nano-aggregates on microstructural properties. These further results in altered water/ion transport and chloride-binding mechanisms in the bulk mortar matrix and thus steel product layer modifications towards enhanced corrosion resistance.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Concrete Corrosion and Durability · Corrosion Behavior and Inhibition · Concrete and Cement Materials Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (68)
Show source-provided references
1. Broomfield J (1997) Corrosion of steel in concrete, understanding, investigating and repair. Spon, London10.4324/9780203414606 ↗
2. Şahmaran M (2007) J Mater Sci 42:9131. doi: 10.1007/s10853-007-1932-z10.1007/s10853-007-1932-z ↗
3. Elsener B (2002) Cem Concr Compos 24(1):6510.1016/S0958-9465(01)00027-0 ↗
4. Garces A, Andrade MC, Saez A, Alonso MC (2005) Corros Sci 47(2):28910.1016/j.corsci.2004.06.004 ↗
5. Uhlig HH (2000) In: Revie RW (ed) Uhlig’s corrosion handbook. Wiley, Ottawa, p 583
6. Bertolini L, Elsener B, Pedeferri P, Polder R (2004) Corrosion of steel in concrete: prevention, diagnosis, repair, 1st edn. Wiley, Weinheim
7. Petterson K (1994) In: Swamy RN (ed) Corrosion and corrosion protection of steel in concrete. Academic Press, Sheffield, p 461
8. Tuutti K (1982) Corrosion of steel in concrete. Swedish Cement and Concrete Research Institute, Stockholm
9. Chang T, Shih J, Yang K (2007) J Mater Sci 42:7478. doi: 10.1007/s10853-006-1462-010.1007/s10853-006-1462-0 ↗
10. Hui L, Xiao HG, Ou JP (2004) Cem Concr Res 34:43510.1016/j.cemconres.2003.08.025 ↗
11. Shebl SS, Allie L, Morsy MS, Aglan HA (2009) J Mater Sci 44:1600. doi: 10.1007/s10853-008-3214-910.1007/s10853-008-3214-9 ↗
12. Zhang MH, Li H (2011) Constr Build Mater 25(2):60810.1016/j.conbuildmat.2010.07.032 ↗
13. Tao J (2005) Cem Concr Res 35:194310.1016/j.cemconres.2005.07.004 ↗
14. Li H, Xiao H, Yuan J, Ou J (2003) Composites B 35:18510.1016/S1359-8368(03)00052-0 ↗
15. Jayapalan AR, Lee BY, Fredrich SM, Kurtis KE (2010) Transp Res Rec 2141:4110.3141/2141-08 ↗
16. Land G, Stephan D (2012) J Mater Sci 47:1011. doi: 10.1007/s10853-011-5881-110.1007/s10853-011-5881-1 ↗
17. Sanchez F, Sobolev K (2010) Constr Build Mater 24:206010.1016/j.conbuildmat.2010.03.014 ↗
18. Etteyeb N, Dhouibi L, Sanchez M, Alonso C, Andrade C, Triki E (2007) J Mater Sci 42:4721. doi: 10.1007/s10853-006-0880-310.1007/s10853-006-0880-3 ↗
19. Wombacher F, Maeder U, Marazzani B (2004) Cem Concr Compos 26:20910.1016/S0958-9465(03)00040-4 ↗
20. Elsener B, Büchler M, Stalder F, Böhni H (1999) Corrosion 55(12):115510.5006/1.3283953 ↗
21. Koleva DA, Ye G, Zhou J, Petrov P, van Breugel K (2008) International conference on microstructure related durability of cementitious composites, Nanjing, China, 13–15 October, 2008, RILEM Publications SARL, p 161
22. Koleva DA, van Breugel K, Ye G, Zhou J, Chamululu G, Koenders E (2009) In: Proceedings of the ACI fall meeting “nanotechnology of concrete: the next big thing is small
23. Koleva DA, van Breugel K, Boshkov N, Mol JMC, de Wit JHW (2010) ECS Trans 25(24):7910.1149/1.3316116 ↗
24. Hu J, Koleva DA, de Wit JHW, Kolev H, van Breugel K (2011) J Electrochem Soc 158(3):C7610.1149/1.3534796 ↗
25. Hu J, Koleva DA, van Breugel K (2010) 2nd international symposium on service life design for infrastructure (SLD2010), 4–6 October, Delft, The Netherlands. RILEM Publications SARL 70(2):791–797
26. Koleva DA, van Breugel K, de Wit JHW, van Westing E, Boshkov N, Fraaij ALA (2007) J Electrochem Soc 154(3):E4510.1149/1.2431318 ↗
27. Koleva DA, Hu J, Fraaij ALA, Stroeven P, Boshkov N, de Wit JHW (2006) Corros Sci 48:400110.1016/j.corsci.2006.03.003 ↗
28. Hu J (2004) Porosity of concrete, morphological study of model concrete. PhD thesis, Delft University of Technology, Delft
29. Ye G (2003) Experimental study and numerical simulation of the development of the microstructure & permeability of cementitious materials. PhD thesis, Delft University of Technology, Delft. http://Microlab.citg.tudelft.nl
30. Matyjaszewski K, Xia J (2001) J Chem Rev 101:292110.1021/cr940534g ↗
31. Eichhorn SJ, Dufresne A, Aranguren M, Marcovich NE, Capadona JR, Rowan SJ, Weder C, Thielemans W, Roman M, Renneckar S, Gindl W, Veigel S, Keckes J, Yano H, Abe K, Nogi M, Nakagaito AN, Mangalam A, Simonsen J, Benight AS, Bismarck A, Berglund LA, Peijs T (2010) J Mater Sci 45:1. doi: 10.1007/s10853-009-3874-010.1007/s10853-009-3874-0 ↗
32. Chang L, Wu S, Chen S, Li X (2011) J Mater Sci 46:2024. doi: 10.1007/s10853-010-5033-z10.1007/s10853-010-5033-z ↗
33. Hu J, Stroeven P (2003) Image Anal Stereol 22:9710.5566/ias.v22.p97-103 ↗
34. Koleva DA, van Breugel K, de Wit JHW, van Westing E, Copuroglu O, Fraaij ALA (2008) Mater Charact 59:80110.1016/j.matchar.2007.06.016 ↗
35. Koleva DA (2007) Corrosion and Protection in Reinforced Concrete, PhD Thesis, Delft University of Technology. Delft. http://Microlab.citg.tudelft.nl
36. Koleva DA, Hu J, Fraaij ALA, van Breugel K, de Wit JHW (2007) Cem Concr Res 37(4):60410.1016/j.cemconres.2006.12.001 ↗
37. Stroeven P, Hu J, Koleva DA (2010) Cem Concr Compos 32:29110.1016/j.cemconcomp.2010.01.007 ↗
38. Oliver WC, Pharr GM (2004) J Mater Res 19(1):310.1557/jmr.2004.19.1.3 ↗
39. Alonso C, Castellote M, Andrade C (2002) Electrochim Acta 47:346910.1016/S0013-4686(02)00283-9 ↗
40. Miranda JM, González JA, Cobo A, Otero E (2006) Corros Sci 48:217210.1016/j.corsci.2005.08.014 ↗
41. Aperador W, Mejía de Gutiérrez R, Bastidas DM (2009) Corros Sci 51:202710.1016/j.corsci.2009.05.033 ↗
42. Ford SJ, Shane JD, Mason TO (1998) Cem Concr Res 28(12):173710.1016/S0008-8846(98)00156-2 ↗
43. Poupard O, Aït-Mokhtar A, Dumargue P (2003) J Mater Sci 38:3521. doi: 10.1023/A:102560062499110.1023/A:1025600624991 ↗
44. Dhouibi L, Refait P, Triki E, Genin JMR (2006) J Mater Sci 41:4928. doi: 10.1007/s10853-006-0332-010.1007/s10853-006-0332-0 ↗
45. Andrade C, Keddam M, Nóvoa XR, Pérez MC, Rangel CM, Takenouti H (2001) Electrochim Acta 46:390510.1016/S0013-4686(01)00678-8 ↗
46. Cabeza M, Merino P, Miranda A, Nóvoa XR, Sanchez I (2002) Cem Concr Res 32:88110.1016/S0008-8846(02)00720-2 ↗
47. MacDonald JR (1987) Impedance spectroscopy: emphasizing solid materials and systems. Wiley, New York
48. Poupard O, Aït-Mokhtar A, Dumargue P (2003) J Mater Sci 38:2845. doi: 10.1023/A:102442831796810.1023/A:1024428317968 ↗
49. Sagüés AA, Pech-Canul MA, Shahid Al-Mansur AKM (2003) Corros Sci 45:710.1016/S0010-938X(02)00087-2 ↗
50. Feliú F, González JA, Feliú S (2004) J Electrochem Soc 151:B13410.1149/1.1643737 ↗
51. Zoltowski P (1998) J Electroanal Chem 443:14910.1016/S0022-0728(97)00490-7 ↗
52. Andrade C, Soler L, Alonso C, Nóvoa RX, Keddam M (1995) Corros Sci 37:201310.1016/0010-938X(95)00095-2 ↗
53. Poupard O, Aït-Mokhtar A, Dumargue P (2004) Cem Concr Res 34:99110.1016/j.cemconres.2003.11.009 ↗
54. Poupard O, L’Hostis V, Catinaud S, Petre-Lazar I (2006) Cem Concr Res 36:50410.1016/j.cemconres.2005.11.004 ↗
55. Huet B, L’Hostis V, Miserque F, Idrissi H (2005) Electrochim Acta 51:17210.1016/j.electacta.2005.04.014 ↗
56. Chudek JA, Hunter G, Jones MR, Scrimgeour SN, Hewlett PC, Kudryavtsev AB (2000) J Mater Sci 35:4275. doi: 10.1023/A:100482410002910.1023/A:1004824100029 ↗
57. Gaal GCM (2004) Prediction of deterioration of concrete bridges. PhD thesis, Delft University of Technology, Delft
58. Iñiguez-Sánchez C, Gómez-Zamorano L, Alonso M (2012) J Mater Sci. doi: 10.1007/s10853-011-6210-410.1007/s10853-011-6210-4 ↗
59. Justnes H (1996) A review of chloride binding in cementitious systems. Trondheim, Norway
60. Yuan Q, Shi C, Schutter G, Audenaert K, Deng D (2009) Constr Build Mater 23(1):110.1016/j.conbuildmat.2008.02.004 ↗
61. Beaudoin JJ, Ramachandran VS, Feldman RF (1990) Cem Concr Res 20(6):87510.1016/0008-8846(90)90049-4 ↗
62. Constantinides G, Ulm FJ, van Vliet K (2003) Mater Struct 36:19110.1007/BF02479557 ↗
63. Hughes JJ, Trtik P (2004) Mater Charact 53:22310.1016/j.matchar.2004.08.014 ↗
64. Jennings HM (2000) Cem Concr Res 30(1):10110.1016/S0008-8846(99)00209-4 ↗
65. Tennis PD, Jennings HM (2000) Cem Concr Res 30(6):85510.1016/S0008-8846(00)00257-X ↗
66. Constantinides G, Ulm F (2004) Cem Concr Res 34:6710.1016/S0008-8846(03)00230-8 ↗
67. Silva DA, Monteiro PJM (2005) Cem Concr Res 35:35110.1016/j.cemconres.2004.05.049 ↗
68. Yang Z, Shi X, Creighton AT, Peterson MM (2009) Constr Build Mater 23:228310.1016/j.conbuildmat.2008.11.011 ↗