journal article·2020-06

A novel nanotube based on self-assembled iron porphyrin/tantalum tungstate composite for electrochemical detection of dopamine

Zichun Fan, Mengjun Wang, Shining Wu, Haoran Wang, Jinpeng Li, Lin Liu, Jing Rong, Zhiwei Tong, Xiaobo Zhang

Journal of Materials Science· Volume 55· Issue 18
Publisher page

Abstract

The novel FeTMPyP [5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrinato iron (III)]/TaWO6 nanotube composite was fabricated through a rapid and convenient exfoliation/reassembling method. In this process, the layered structure of the original LiTaWO6 was reconstructed into the tubular structure of the FeTMPyP/TaWO6 composite. The change of morphology has been verified by the characterization means of scanning electron micrograph, transmission electron microscope and high-resolution transmission electron microscope. The composition of the as-prepared samples was determined by Fourier transformed infrared spectra and energy-dispersive spectroscopy. Furthermore, the FeTMPyP/TaWO6 composite as an effective sensing material showed excellent sensitivity for electrochemical detection of dopamine (DA). FeTMPyP/TaWO6-modified electrode can accelerate electron transfer process and enhance the current response to DA sensing. Also, a detection limit of DA was calculated as 1.2 μM at a signal-to-noise ratio of 3.0 with a wide concentration range from 12 to 427 μM.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrochemical sensors and biosensors · Conducting polymers and applications · Electrochemical Analysis and Applications

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