journal article·2009-08

PWA/silica/PFSA composite membrane for direct methanol fuel cells

Fangjian Shang, Lei Li, Yongming Zhang, Hong Li

Journal of Materials Science· Volume 44· Issue 16
Publisher page

Abstract

A novel composite membrane was prepared by incorporation of silica-included phosphotungstic acid (PWA) additive into perfluorosulfonic acid (PFSA) followed by solution casting. Physico-chemical properties of the composite membranes were studied by Fourier transform infrared (FT-IR) spectroscopy, thermogravimetry analysis (TGA), water uptake and swelling ratio. The results of FT-IR and TGA illustrated the stability of the PWA-silica additive in the PFSA matrix. Lower PWA-silica additive loading (2.5 and 5 wt%) in the composite membranes helped to inhibit methanol crossover and enhance the proton conductivity. However, higher additive content shows decrease in both methanol resistance and proton conductivity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fuel Cells and Related Materials · Membrane-based Ion Separation Techniques · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (19)

Show source-provided references
1. Mioc U, Davidovic M, Tjapkin N, Colomban P, Novak A (1991) Solid State Ion 46:10310.1016/0167-2738(91)90136-Y ↗
2. Sahu AK, Selvarani G, Pitchumani S, Sridhar P, Shukla AK (2007) J Electrochem Soc 154:B12310.1149/1.2401031 ↗
3. Ren X, Zawadzinski TA, Uribe F, Dai H, Gottesfeld S (1995) Electrochem Soc Proc 95:84
4. Ramani V, Kuna HK, Fenton JM (2004) J Membr Sci 232:3110.1016/j.memsci.2003.11.016 ↗
5. Kim HK, Chang H (2007) J Membr Sci 288:18810.1016/j.memsci.2006.11.038 ↗
6. Zaidi SMJ, Mikhailenko SD, Robertson GP, Guiver MD, Kaliaguine S (2000) J Membr Sci 173:1710.1016/S0376-7388(00)00345-8 ↗
7. Tazi B, Savadogo O (2000) Electrochim Acta 45:432910.1016/S0013-4686(00)00536-3 ↗
8. Shao ZG, Joghee P, Hsing IM (2004) J Membr Sci 229:4310.1016/j.memsci.2003.09.014 ↗
9. Xu WL, Lu TH, Liu CP, Xing W (2005) Electrochim Acta 50:328010.1016/j.electacta.2004.12.014 ↗
10. Staiti P, Aricò AS, Baglio V, Lufrano F, Passalacqua E, Antonucci V (2001) Solid State Ion 145:10110.1016/S0167-2738(01)00919-5 ↗
11. Izumi Y, Hisano K, Hida T (1999) Appl Catal A Gen 181:27710.1016/S0926-860X(98)00399-8 ↗
12. Luan YH, Zhang YM, Zhang H, Li L, Li H, Liu YG (2008) J Appl Polym Sci 107:39610.1002/app.27070 ↗
13. Staiti P, Freni S, Hocevar S (1999) J Power Sources 79:25010.1016/S0378-7753(99)00177-9 ↗
14. Li L, Wang YX (2006) J Power Sources 162:54110.1016/j.jpowsour.2006.06.010 ↗
15. Jiang RC, Kunz HR, Fenton JM (2006) J Membr Sci 272:11610.1016/j.memsci.2005.07.026 ↗
16. Deng Q, Moore RB, Mauritz KA (1998) J Appl Polym Sci 68:74710.1002/(SICI)1097-4628(19980502)68:5<747::AID-APP7>3.0.CO;2-O ↗
17. Miyake N, Wainright JS, Savinell RF (2001) J Electrochem Soc 148:A89810.1149/1.1383071 ↗
18. Cho HD, Won J, Ha HY (2008) Renew Energy 33:24810.1016/j.renene.2007.05.013 ↗
19. Shahi VK (2007) Solid State Ion 177:339510.1016/j.ssi.2006.10.023 ↗