journal article·2019-05

Facile fabrication of self-healing superhydrophobic nanocomposite films enabled by near-infrared light

Wei Li, Gang Wu, Jinhui Tan, Yuntao Zhu, Xufeng Yu, Yang Lei, Gang Sun, Bo You

Journal of Materials Science· Volume 54· Issue 10
Publisher page

Abstract

A novel robust self-healing superhydrophobic F-SiO2/Fe3O4/EP(epoxy)/PCL nanocomposite film was fabricated through a facile two-step method including resin spraying and NPs perpendicular gradient deposition. Specially, the epoxy/polycaprolactone (EP/PCL) mixed resin matrix was prepared through a spraying process and the functioned silica/magnetic iron oxide (F-SiO2/Fe3O4) nanoparticles were then deposited on the resin matrix by gradient distribution under gravity and solvent evaporation. The THF/ethanol mixture solvent which acted as film microstructure-directing agent guided the F-SiO2/Fe3O4 nanoparticles gradient distribution in the nanocomposite films. The results showed that the cutting cracks on the nanocomposite film could be rapidly self-healed and the film would maintain its superhydrophobicity after irradiation by near-infrared light. The nanocomposite films, especially the F-SiO2(8.5wt%)/Fe3O4(1.0wt%)/EP/PCL nanocomposite film, showed high resistant properties on abrasion, corrosive liquids and UV irradiation. The recovery mechanism of the nanocomposite films was also investigated.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Aerogels and thermal insulation · High voltage insulation and dielectric phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Wang Y, Gong X (2017) Special oleophobic and hydrophilic surfaces: approaches, mechanisms, and applications. J Mater Chem A 5:3759–377310.1039/C6TA10474F ↗
2. Liu YH, Liu ZL, Liu YP, Hu HY, Li Y, Yan PX, Yu B, Zhou F (2015) One-step modification of fabrics with bioinspired polydopamine@octadecylamine nanocapsules for robust and healable self-cleaning performance. Small 11:426–43110.1002/smll.201402383 ↗
3. Cao CY, Ge MZ, Huang JY, Li SH, Deng S, Zhang SN, Chen Z, Zhang KQ, Al-Deyab SS, Lai YK (2016) Robust fluorine-free superhydrophobic PDMS—ormosil@ fabrics for highly effective self-cleaning and efficient oil–water separation. J Mater Chem A 4:12179–1218710.1039/C6TA04420D ↗
4. Chen KL, Zhou SX, Yang S, Wu LM (2015) Fabrication of all-water-based self-repairing superhydrophobic coatings based on UV-responsive microcapsules. Adv Funct Mater 25:1035–104110.1002/adfm.201403496 ↗
5. Xing YJ, Xue YP, Song JL, Sun YK, Huang L, Liu X, Sun J (2018) Superhydrophobic coatings on wood substrate for self-cleaning and EMI shielding. Appl Surf Sci 436:865–87210.1016/j.apsusc.2017.12.083 ↗
6. Cheng MJ, Zhang SS, Dong HY, Han SH, Wei H, Shi F (2015) Improving the durability of a drag-reducing nanocoating by enhancing its mechanical stability. ACS Appl Mater Interfaces 7:4275–428210.1021/am5085012 ↗
7. Hwang GB, Patir A, Page K, Lu Y, Allan E, Parkin IP (2017) Buoyancy increase and drag-reduction through a simple superhydrophobic coating. Nanoscale 9:7588–759410.1039/C7NR00950J ↗
8. Zhang SS, Ouyang X, Li J, Gao S, Han SH, Liu LH, Wei H (2014) Underwater drag-reducing effect of superhydrophobic submarine model. Langmuir 31:587–59310.1021/la504451k ↗
9. Zhou X, Lee Y-Y, Chong KSL, He CB (2018) Superhydrophobic and slippery liquid-infused porous surfaces formed by the self-assembly of a hybrid ABC triblock copolymer and their antifouling performance. J Mater Chem B 6:440–44810.1039/C7TB02457F ↗
10. Siddiqui AR, Maurya R, Balani K (2017) Superhydrophobic self-floating carbon nanofiber coating for efficient gravity-directed oil/water separation. J Mater Chem A 5:2936–294610.1039/C6TA10411H ↗
11. Li J, Xu CC, Zhang Y, Wang RF, Zha F, She HD (2016) Robust superhydrophobic attapulgite coated polyurethane sponge for efficient immiscible oil/water mixture and emulsion separation. J Mater Chem A 4:15546–1555310.1039/C6TA07535E ↗
12. Wang Y, Gong X (2017) Superhydrophobic coatings with periodic ring structured patterns for self-cleaning and oil-water separation. Adv Mater Interfaces 4:170019010.1002/admi.201700190 ↗
13. Yin K, Du HF, Dong XR, Wang C, Duan JA, He J (2017) Femtosecond laser induced robust periodic nanoripple structured mesh for highly efficient oil–water separation. Nanoscale 9:14229–1423510.1039/C7NR04582D ↗
14. Zhang SX, Jiang GS, Gao SJ, Jin HL, Zhu YZ, Zhang F, Jin J (2018) Cupric phosphate nanosheets-wrapped inorganic membranes with superhydrophilic and outstanding anticrude oil-fouling property for oil/water separation. ACS Nano 12:795–80310.1021/acsnano.7b08121 ↗
15. Gao SW, Dong XL, Huang JY, Li SH, Li YW, Chen Z, Lai YK (2018) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation. Chem Eng J 333:621–62910.1016/j.cej.2017.10.006 ↗
16. Qian HC, Xu DK, Du CW, Zhang DW, Li XG, Huang LY, Deng LP, Tu YC, Mol JMC, Terryn HA (2017) Dual-action smart coatings with a self-healing superhydrophobic surface and anti-corrosion properties. J Mater Chem A 5:2355–236410.1039/C6TA10903A ↗
17. Wu Y, Zhou SX, You B, Wu LM (2017) Bioinspired design of three-dimensional ordered tribrachia-post arrays with re-entrant geometry for omniphobic and slippery surfaces. ACS Nano 11:8265–827210.1021/acsnano.7b03433 ↗
18. Yin K, Du HF, Dong XR, Wang C, Duan J-A, He J (2017) A simple way to achieve bioinspired hybrid wettability surface with micro/nanopatterns for efficient fog collection. Nanoscale 9:14620–1462610.1039/C7NR05683D ↗
19. Cheng TT, He R, Zhang QH, Zhan XL, Chen FQ (2015) Magnetic particle-based super-hydrophobic coatings with excellent anti-icing and thermoresponsive deicing performance. J Mater Chem A 3:21637–2164610.1039/C5TA05277G ↗
20. Shen YZ, Tao J, Tao HJ, Chen SL, Pan L, Wang T (2015) Anti-icing potential of superhydrophobic Ti6Al4V surfaces: ice nucleation and growth. Langmuir 31:10799–1080610.1021/acs.langmuir.5b02946 ↗
21. Cao LL, Jones AK, Sikka VK, Wu JZ, Gao D (2009) Anti-icing superhydrophobic coatings. Langmuir 25:12444–1244810.1021/la902882b ↗
22. Guo P, Zheng YM, Wen MX, Song C, Lin YC, Jiang L (2012) Icephobic/anti-icing properties of micro/nanostructured surfaces. Adv Mater 24:2642–264810.1002/adma.201104412 ↗
23. Liu MM, Hou YY, Li J, Tie L, Peng YB, Guo ZG (2017) Inorganic adhesives for robust, self-healing, superhydrophobic surfaces. J Mater Chem A 5:19297–1930510.1039/C7TA06001G ↗
24. Xu ZL, Miyazaki K, Hori T (2016) Fabrication of polydopamine-coated superhydrophobic fabrics for oil/water separation and self-cleaning. Appl Surf Sci 370:243–25110.1016/j.apsusc.2016.02.135 ↗
25. Wang XL, Liu XJ, Zhou F, Liu WM (2011) Self-healing superamphiphobicity. Chem Commun 47:2324–232610.1039/C0CC04066E ↗
26. Li Y, Li L, Sun JQ (2010) Bioinspired self-healing superhydrophobic coatings. Angew Chem Int Ed 49:6129–613310.1002/anie.201001258 ↗
27. Wang HX, Xue YH, Ding J, Feng LF, Wang XG, Lin T (2011) Durable, self-healing superhydrophobic and superoleophobic surfaces from fluorinated-decyl polyhedral oligomeric silsesquioxane and hydrolyzed fluorinated alkyl silane. Angew Chem Int Ed 50:11433–1143610.1002/anie.201105069 ↗
28. Li Y, Chen SS, Wu MC, Sun JQ (2014) All spraying processes for the fabrication of robust, self-healing, superhydrophobic coatings. Adv Mater 26:3344–334810.1002/adma.201306136 ↗
29. Yeong YH, Wang CY, Wynne KJ, Gupta MC (2016) Oil-infused superhydrophobic silicone material for low ice adhesion with long-term infusion stability. ACS Appl Mater Interfaces 8:32050–3205910.1021/acsami.6b11184 ↗
30. Wu MC, An N, Li Y, Sun JQ (2016) Layer-by-layer assembly of fluorine-free polyelectrolyte-surfactant complexes for the fabrication of self-healing superhydrophobic films. Langmuir 32:12361–1236910.1021/acs.langmuir.6b02607 ↗
31. Wu MC, Li Y, An N, Sun JQ (2016) Applied voltage and near-infrared light enable healing of superhydrophobicity loss caused by severe scratches in conductive superhydrophobic films. Adv Funct Mater 26:6777–678410.1002/adfm.201601979 ↗
32. Bai X, Xue C-H, Jia S-T (2016) Surfaces with sustainable superhydrophobicity upon mechanical abrasion. ACS Appl Mater Interfaces 8:28171–2817910.1021/acsami.6b08672 ↗
33. Deng H, Li XL, Peng Q, Wang X, Chen JP, Li YD (2005) Monodisperse magnetic single-crystal ferrite microspheres. Angew Chem Int Ed 117:2842–284510.1002/ange.200462551 ↗
34. Wang N, Xiong DS, Lu Y, Pan S, Wang K, Deng YL, Shi Y (2016) Design and fabrication of the lyophobic slippery surface and its application in anti-icing. J Phys Chem C 120:11054–1105910.1021/acs.jpcc.6b04778 ↗
35. Luo XF, Ou RQ, Eberly DE, Singhal A, Viratyaporn W, Mather PT (2009) Thermoplastic/thermoset blend exhibiting thermal mending and reversible adhesion. ACS Appl Mater Interfaces 1:612–62010.1021/am8001605 ↗