Synthesis and electrochemical characterization of LiCo1/3Ni1/3Mn1/3O2 by radiated polymer gel method
Source abstract
Abstract
Layered LiCo1/3Ni1/3Mn1/3O2 as a lithium insertion positive-electrode material was prepared by a radiated polymer gel method. The synthesis conditions and microstructure, morphology and electrochemical properties of the products were investigated by XRD, SEM and electrochemical cell cycling. It was found that the positive-electrode material annealed at 950 °C showed the best electrochemical property with the first specific discharge capacity of 178 mAh/g at C/6 and stable cycling ability between 2.8 and 4.5 V versus Li/Li+. The optimized LiCo1/3Ni1/3Mn1/3O2 exhibited rather good rate capability with the specific capacity of 173 mAh/g at 0.2C and 116 mAh/g at 4C under a fast charge and discharge mode in rate performance test.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (26)
Show source-provided references
1. Mizushima K, Jones PC, Wiseman PJ, Goodenough JB (1980) Mater Res Bull 15:78310.1016/0025-5408(80)90012-4 ↗
2. Reimers JN, Dahn JR (1992) J Electrochem Soc 139:209110.1149/1.2221184 ↗
3. MacNeil DD, Lu ZH, Dahn JR (2002) J Electrochem Soc 149:A133210.1149/1.1505633 ↗
4. Shaju KM, Bruce PG (2006) Adv Mater 18:233010.1002/adma.200600958 ↗
5. Ohzuku T, Makimura Y (2001) Chem Lett 64210.1246/cl.2001.642 ↗
6. Koyama Y, Tanaka I, Adachi H, Makimura Y, Ohzuku T (2003) J Power Sources 119:64410.1016/S0378-7753(03)00194-0 ↗
7. Yabuuchi N, Ohzuku T (2003) J Power Sources 119–121:17110.1016/S0378-7753(03)00173-3 ↗
8. Yabuuchi N, Ohzuku T (2005) J Power Sources 146:63610.1016/j.jpowsour.2005.03.080 ↗
9. Koyama Y, Yabuuchi N, Tanaka I, Adachi H, Ohzuku T (2004) J Electrochem Soc 151:A154510.1149/1.1784823 ↗
10. Yabuuchi N, Koyama Y, Nakayama N, Ohzuku T (2005) J Electrochem Soc 152:A143410.1149/1.1924227 ↗
11. Choi J, Manthiram A (2005) J Electrochem Soc 152:A171410.1149/1.1954927 ↗
12. Hwang BJ, Tsai YW, Carlier D, Ceder G (2003) Chem Mater 15:367610.1021/cm030299v ↗
13. Tsai YW, Hwang BJ, Ceder G, Sheu HS, Liu DG, Lee JF (2005) Chem Mater 17:319110.1021/cm048027v ↗
14. Yoon W, Grey CP, Balasubramanian M, Yang X, Fisher DA, MacBreen J (2004) Electrochem Solid-State Lett 7:A5310.1149/1.1643592 ↗
15. Deb A, Bergmann U, Cramer SP, Cairns EJ (2005) J Appl Phys 97:11352310.1063/1.1921328 ↗
16. Cho TH, Park SM, Yoshio M, Hirai T, Hideshima Y (2005) J Power Sources 142:30610.1016/j.jpowsour.2004.10.016 ↗
17. Lee MH, Kang YJ, Myung ST, Sun YK (2004) Electrochim Acta 50:93910.1016/j.electacta.2004.07.038 ↗
18. Tong DG, Lai QY, Wei NN, Tang AD, Tang LX, Huang KL, Ji XY (2005) Mater Chem Phys 94:42310.1016/j.matchemphys.2005.05.025 ↗
19. Li DC, Muta T, Zhang LQ, Yoshio M, Noguchi H (2004) J Power Sources 132:15010.1016/j.jpowsour.2004.01.016 ↗
20. Ding N, Ge XW, Chen CH (2005) Mater Res Bull 40:145110.1016/j.materresbull.2005.04.022 ↗
21. Xu HY, Xie S, Ding N, Liu BL, Shang Y, Chen CH (2006) Electrochim Acta 51:435210.1016/j.electacta.2005.12.014 ↗
22. Myung ST, Komaba S, Kurihara K, Hosoya K, Kumagai N, Sun YK, Nakai I, Yonemura M, Kamiyama T (2006) Chem Mater 18:165810.1021/cm052704j ↗
23. Kim JM, Chung HT (2004) Electrochim Acta 49:93710.1016/j.electacta.2003.10.005 ↗
24. Choi J, Manthiram A (2005) Electrochem Solid-State Lett 8:C10210.1149/1.1943567 ↗
25. Shaju KM, Subba Rao GV, Chowdari BVR (2002) Electrochim Acta 48:14510.1016/S0013-4686(02)00593-5 ↗
26. Li DC, Muta T, Zhang LQ, Yoshio M, Noguchi H (2004) J Power Sources 132:15010.1016/j.jpowsour.2004.01.016 ↗