Thermodynamic interaction and mechanical characteristics of Nylon 6 and polyhedral oligomeric silsesquioxane nanohybrids
Source abstract
Abstract
Polyhedral oligomeric silsesquioxane (POSS) reagents have unique hybrid chemical compositions containing nano-sized cage structures with dimensions comparable to those of most polymer segments and coils. This article reports a generalized functionalization scheme of POSS that is suitable as a nanohybrid with Nylon 6. The thermodynamic interaction energy density, thermodynamic solubility parameter, and activation energy of the specific interaction between Nylon 6 and POSS were examined. The mechanical, thermal, and morphological properties of the Nylon 6 nanohybrids were also analyzed and compared with the theoretical estimation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Silicone and Siloxane Chemistry · Polymer Nanocomposites and Properties · Synthesis and characterization of novel inorganic/organometallic compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (49)
Show source-provided references
1. Alexandre M, Dubois P (2000) Mater Sci Eng Rep 28:110.1016/S0927-796X(00)00012-7 ↗
2. Potschke P, Pegel S, Claes M, Bonduel D (2008) Macromol Rapid Commun 29:24410.1002/marc.200700637 ↗
3. Lim SK, Kim JW, Chin IJ, Kwon YK, Choi HJ (2002) Chem Mater 14:198910.1021/cm010498j ↗
4. Lim SK, Lee EH, Chin IJ (2008) J Mater Res 23:116810.1557/jmr.2008.0148 ↗
5. Liu YD, Fang FF, Choi HJ (2011) Soft Matter 7:278210.1039/c0sm01279c ↗
6. Zhang WL, Liu YD, Choi HJ (2011) J Mater Chem 21:691610.1039/c1jm10323g ↗
7. Park BJ, Fang FF, Choi HJ (2010) Soft Matter 6:524610.1039/c0sm00014k ↗
8. Li G, Wang L, Ni H, Pittman CU (2001) J Inorg Organomet Polym 11:12310.1023/A:1015287910502 ↗
9. Sanchez C, Soler-Illia GJDA, Ribot F, Lalot T, Mayer CR, Cabuil V (2001) Chem Mater 13:306110.1021/cm011061e ↗
10. Pielichowski K, Njuguna J, Janowski B, Pielichowski J (2006) Adv Polym Sci 201:22510.1007/12_077 ↗
11. Xie P, Zhang R (1997) Polym Adv Technol 8:64910.1002/(SICI)1099-1581(199711)8:11<649::AID-PAT696>3.0.CO;2-H ↗
12. Lichtenhan JD (1995) Comments Inorg Chem 17:11510.1080/02603599508035785 ↗
13. Park JY, Kim MG, Kim JB (2008) Macromol Rapid Commun 29:153210.1002/marc.200800324 ↗
14. Deng JJ, Polidan JT, Hottle JR, Farmer-Creely CE, Viers BD, Esker AR (2002) J Am Chem Soc 124:1519410.1021/ja027860v ↗
15. Haddad TS, Lichtenhan JD (1996) Macromolecules 29:730210.1021/ma960609d ↗
16. Schwab JJ, Lichtenhan JD (1998) Appl Organomet Chem 12:70710.1002/(SICI)1099-0739(199810/11)12:10/11<707::AID-AOC776>3.0.CO;2-1 ↗
17. Choi J, Harcup J, Yee AF, Zhu Q, Laine RM (2001) J Am Chem Soc 123:1142010.1021/ja010720l ↗
18. Zheng L, Waddon AJ, Farris RJ, Coughlin EB (2002) Macromolecules 35:237510.1021/ma011855e ↗
19. Constable GS, Lesser AJ, Coughlin EB (2004) Macromolecules 37:127610.1021/ma034989w ↗
20. Cardoen G, Coughlin EB (2004) Macromolecules 37:512310.1021/ma049769c ↗
21. Verker R, Grossman E, Gouzman I, Eliaz N (2009) Compos Sci Technol 69:217810.1016/j.compscitech.2009.06.001 ↗
22. Wu J, Haddad TS, Mather PT (2009) Macromolecules 42:114210.1021/ma8024267 ↗
23. Somboonsub B, Thongyai S, Praserthdam PJ (2009) Appl Polym Sci 114:329210.1002/app.30663 ↗
24. Tsuchida A, Bolln C, Sernetz FG, Frey H, Mulhaupt R (1997) Macromolecules 30:281810.1021/ma960846g ↗
25. Zheng L, Farris RJ, Coughlin EB (2001) J Polym Sci A 39:292010.1002/pola.1272 ↗
26. Li GZ, Cho H, Wang L, Toghiani H, Pittman CU (2005) J Polym Sci A 43:35510.1002/pola.20503 ↗
27. Ohno K, Sugiyama S, Koh K, Tsujii Y, Fukuda T, Yamahiro M, Oikawa H, Yamamoto Y, Ootake N, Watanabe K (2004) Macromolecules 37:851710.1021/ma048877w ↗
28. Turri S, Levi M (2005) Macromolecules 38:556910.1021/ma047304g ↗
29. Hato MJ, Ray SS, Luyt AS (2010) Adv Sci Lett 3:12310.1166/asl.2010.1122 ↗
30. Hato MJ, Ray SS, Luyt AS (2008) Macromol Mater Eng 293:75210.1002/mame.200800146 ↗
31. Lim SK, Hong EP, Song YH, Choi HJ, Chin IJ (2010) J Mater Sci 45:5984. doi: 10.1007/s10853-010-4446-z10.1007/s10853-010-4446-z ↗
32. Li Q, Xu Y, Yoon JS, Chen GX (2011) J Mater Sci 46:2324. doi: 10.1007/s10853-010-5077-010.1007/s10853-010-5077-0 ↗
33. Riedl BJ, Prud’homme RE (1984) Polym Eng Sci 24:129110.1002/pen.760241705 ↗
34. Csaki KF, Nagy M, Csempesz F (2005) Langmuir 21:76110.1021/la047827h ↗
35. Nishi T, Wang TT (1975) Macromolecules 8:90910.1021/ma60048a040 ↗
36. Barlow JW, Paul DR (1987) Polym Eng Sci 27:148210.1002/pen.760272003 ↗
37. Kim CK, Paul DR (1992) Polymer 33:163010.1016/0032-3861(92)91059-B ↗
38. Fukuda T, Nagata M, Inagaki H (1984) Macromolecules 17:54810.1021/ma00134a007 ↗
39. Shiomi T, Kohno K, Yoneda K, Tomita T, Miya M, Imai K (1985) Macromolecules 18:41410.1021/ma00145a020 ↗
40. Green PF, Doyle BL (1986) Phys Rev Lett 57:240710.1103/PhysRevLett.57.2407 ↗
41. Olabisi O (1975) Macromolecules 8:31610.1021/ma60045a014 ↗
42. van Krevelen DW (1990) Properties of polymers. Elsevier, New York
43. Jang BN, Wang D, Wilkie CA (2005) Macromolecules 38:653310.1021/ma0508909 ↗
44. Kissinger HE (1957) Anal Chem 29:170210.1021/ac60131a045 ↗
45. Mather PT, Jeon HG, Romo-Uribe A, Haddad TS, Lichtenhan JD (1999) Macromolecules 32:119410.1021/ma981210n ↗
46. Liang K, Li G, Toghiani H, Koo JH, Pittman CU (2006) Chem Mater 18:30110.1021/cm051582s ↗
47. Lim SK, Hong EP, Choi HJ, Chin IJ (2010) J Ind Eng Chem 16:18910.1016/j.jiec.2010.01.049 ↗
48. Fina A, Tabuani D, Carniato F, Frache A, Boccaleri E, Caminoa G (2006) Thermochim Acta 440:3610.1016/j.tca.2005.10.006 ↗
49. Wang J, Ye Z, Joly H (2007) Macromolecules 40:615010.1021/ma0706733 ↗