Self-supported ultrathin mesoporous CoFe2O4/CoO nanosheet arrays assembled from nanowires with enhanced lithium storage performance
Source abstract
Abstract
Self-supported two-dimensional metal oxide nanosheet arrays have attracted great attention in lithium-ion batteries (LIBs) due to their superior structure advantages such as large surface area, good structure stability, and high electronic conductivity compared to one dimensional (1D) nanowires. Herein, we design the self-supported mesoporous CoFe2O4/CoO nanosheet arrays assembled from the nanowires precursor based on the combination of hydrothermal and atomic layer deposition techniques. The assembled CoFe2O4/CoO nanosheets exhibit an ultra-high initial charge capacity of 1705 mAhg−1 and good cycling stability (1043 mAhg−1 after 50 cycles) when directly used as a binder-free anode of LIBs.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Magnetic Properties and Synthesis of Ferrites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (50)
Show source-provided references
1. Bruce PG, Scrosati B, Tarascon JM (2008) Nanomaterials for rechargeable lithium batteries. Angew Chem Int Ed 47:2930–294610.1002/anie.200702505 ↗
2. Tarascon JM, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414:359–36710.1038/35104644 ↗
3. Poizot P, Laruelle S, Grugeon S, Tarascon JM (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–49910.1038/35035045 ↗
4. Jiang J, Li YY, Huang XT, Yuan CZ, Lou XW (2012) Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage. Adv Mater 20:5166–518010.1002/adma.201202146 ↗
5. Peng C, Chen B, Qin Y, Yang J (2012) Facile ultrasonic synthesis of CoO quantum dot/graphene nanosheet composites with high lithium storage capacity. ACS Nano 6:1074–109110.1021/nn202888d ↗
6. Yu L, Zhang L, Wu HB, Zhang G, Lou XWD (2013) Controlled synthesis of hierarchical CoxMn3−xO4 array micro-nanostructures with tunable morphology and composition as integrated electrodes for lithium-ion batteries. Energy Environ Sci 6:2664–267110.1039/C3EE41181H ↗
7. Li Y, Tan B, Wu Y (2008) Mesoporous Co3O4 nanowire arrays for lithium ion batteries with high capacity and rate capability. Nano Lett 8(1):265–27010.1021/nl0725906 ↗
8. Lou XW, Deng D, Archer LA (2007) Self-supported formation of needlelike Co3O4 nanotubes and their application as lithium-ion battery electrodes. Adv Mater 20(2):258–262
9. Du N, Zhang H, Tu JP (2007) Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates: a highly efficient material For Li-battery applications. Adv Mater 19(24):4505–450910.1002/adma.200602513 ↗
10. Wu FD, Wang Y (2011) Self-assembled echinus-like nanostructures of mesoporous CoO nanorod@CNT for lithium-ion batteries. J Mater Chem 21(18):663610.1039/c0jm04346j ↗
11. Li D, Ding L-X, Wang S, Cai D, Wang H (2014) Ultrathin and highly-ordered CoO nanosheet arrays for lithium-ion batteries with high cycle stability and rate capability. J Mater Chem A 2(16):562510.1039/C3TA14826B ↗
12. Wu F, Ma X, Feng J, Qian Y, Xiong S (2014) 3D Co3O4 and CoO@C wall arrays: morphology control, formation mechanism, and lithium-storage properties. J Mater Chem A 2(30):1159710.1039/C4TA01676A ↗
13. Liu Y, Jiao Y, Zhou H, Yu X, Qu F, Wu X (2014) Rational design of WO3 nanostructures as the anode materials for lithium-ion batteries with enhanced electrochemical performance. Nano-Micro Lett 7(1):12–1610.1007/s40820-014-0013-5 ↗
14. Pan L, Zhao H, Shen W, Dong X, Xu J (2013) Surfactant-assisted synthesis of a Co3O4/reduced graphene oxide composite as a superior anode material for Li-ion batteries. J Mater Chem A 1(24):715910.1039/c3ta01498c ↗
15. Sun J, Liu H, Chen X, Evans DG, Yang W (2013) An oil droplet template method for the synthesis of hierarchical structured Co3O4/C anodes for Li-ion batteries. Nanoscale 5(16):7564–757110.1039/c3nr02385k ↗
16. Guan Q, Cheng J, Nie F (2014) Needle-like Co3O4 anchored on the graphene with enhanced electrochemical performance for aqueous supercapacitors. ACS Appl Mater Interfaces 6(10):7626–763210.1021/am5009369 ↗
17. Wang H, Mao N, Wang X (2015) Cobalt oxide-carbon nanosheet nanoarchitecture as an anode for high-performance lithium-ion battery. ACS Appl Mater Interfaces 7(4):2882–289010.1021/am508208c ↗
18. Huang G, Zhang F, Wang L (2015) MOF route to in situ insertion of multiwalled carbon nanotubes in Co3O4 polyhedra as anode materials for lithium ion batteries. ACS Nano 9(2):1592–159910.1021/nn506252u ↗
19. Luo J, Liu J, Zeng Z et al (2013) Three-dimensional graphene foam supported Fe(3)O(4) lithium battery anodes with long cycle life and high rate capability. Nano Lett 13(12):6136–614310.1021/nl403461n ↗
20. Wang J, Zhang Q, Li X et al (2014) Three-dimensional hierarchical Co3O4/CuO nanowire heterostructure arrays on nickel foam for high-performance lithium ion batteries. Nano Energy 6:19–2610.1016/j.nanoen.2014.02.012 ↗
21. Wu H, Xu M, Wang Y, Zheng G (2013) Branched Co3O4/Fe2O3 nanowires as high capacity lithium-ion battery anodes. Nano Res 6(3):167–17310.1007/s12274-013-0292-z ↗
22. Wu JB, Guo RQ, Huang XH, Lin Y (2014) Ternary core/shell structure of Co3O4/NiO/C nanowire arrays as high-performance anode material for Li-ion battery. J Power Sources 248:115–12110.1016/j.jpowsour.2013.09.040 ↗
23. Cao KZ, Jiao LF, Yuan HT (2015) Ultra-high capacity lithium-ion batteries with hierarchical CoO nanowire clusters as binder free electrodes. Adv Funct Mater 25(7):1082–108910.1002/adfm.201403111 ↗
24. Hong YJ, Son MY, Kang YC (2013) One-pot facile synthesis of double-shelled SnO2 yolk-shell-structured powders by continuous process as anode materials for Li-ion batteries. Adv Mater 25(16):2279–228310.1002/adma.201204506 ↗
25. Cai Z, Xu L, Yan M et al (2015) Manganese oxide/carbon yolk-shell nanorod anodes for high capacity lithium batteries. Nano Lett 15(1):738–74410.1021/nl504427d ↗
26. Zhang H, Zhou L, Yu C (2014) Tailoring the void size of iron oxide@carbon yolk shell structure for optimized lithium strorage. Adv Funct Mater 24:4377–438210.1002/adfm.201470181 ↗
27. Wu R, Qian X, Zhou K (2014) Porous spinel ZnxCo3−xO4 hollow polyhedra templated for high-rate lithium-ion batteries. ACS Nano 8(6):6297–630310.1021/nn501783n ↗
28. Wang Z, Zhou L, Lou XWD (2012) Metal oxide hollow nanostructures for lithium-ion batteries. Adv Mater 24(14):1903–191110.1002/adma.201200469 ↗
29. Wu R, Qian X, Rui X et al (2014) Zeolitic imidazolate framework 67-derived high symmetric porous Co3O4 hollow dodecahedra with highly enhanced lithium storage capability. Small 10(10):1932–193810.1002/smll.201303520 ↗
30. Kim W-S, Hwa Y, Kim H-C, Choi J-H, Sohn H-J, Hong S-H (2014) SnO2@Co3O4 hollow nano-spheres for a Li-ion battery anode with extraordinary performance. Nano Res 7(8):1128–113610.1007/s12274-014-0475-2 ↗
31. Cao FF, Deng JW, Xin S et al (2011) Cu–Si nanocable arrays as high-rate anode materials for lithium-ion batteries. Adv Mater 23(38):4415–442010.1002/adma.201102062 ↗
32. Jung YS, Cavanagh AS, Riley LA et al (2010) Ultrathin direct atomic layer deposition on composite electrodes for highly durable and safe Li-ion batteries. Adv Mater 22(19):2172–217610.1002/adma.200903951 ↗
33. Kang E, Jung YS, Cavanagh AS et al (2011) Fe3O4 nanoparticles confined in mesocellular carbon foam for high performance anode materials for lithium-ion batteries. Adv Funct Mater 21(13):2430–243810.1002/adfm.201002576 ↗
34. Kohandehghan A, Kalisvaart P, Cui K, Kupsta M, Memarzadeh E, Mitlin D (2013) Silicon nanowire lithium-ion battery anodes with ALD deposited TiN coatings demonstrate a major improvement in cycling performance. J Mater Chem A 1(41):1285010.1039/c3ta12964k ↗
35. Lotfabad EM, Kalisvaart P, Kohandehghan A et al (2014) Si nanotubes ALD coated with TiO2, TiN or Al2O3 as high performance lithium ion battery anodes. J Mater Chem A 2(8):2504–251610.1039/C3TA14302C ↗
36. Yuan C, Yang L, Hou L, Shen L, Zhang X, Lou XWD (2012) Growth of ultrathin mesoporous Co3O4 nanosheet arrays on Ni foam for high-performance electrochemical capacitors. Environ Eng Sci 5:7883–7887
37. Reddy MV, Prithvi G, Loh KP, Chowdari BVR (2014) Li storage and impedance spectroscopy studies on Co3O4, CoO and CoN for Li-Ion batteries. ACS Appl Mater Interfaces 6:680–69010.1021/am4047552 ↗
38. Jiang J, Liu JP, Ding RM et al (2010) Direct synthesis of CoO porous nanowire arrays on Ti substrate and their application as lithium-ion battery electrodes. J Phys Chem C 114:929–93210.1021/jp909785g ↗
39. Du D, Yue W, Ren Y, Yang X (2014) Fabrication of graphene-encapsulated CoO/CoFe2O4 composites derived from layered double hydroxides and their application as anode materials for lithium-ion batteries. J Mater Sci 49:8031–8039. doi: 10.1007/s10853-014-8510-y10.1007/s10853-014-8510-y ↗
40. Zhang H, Liu J, Zhao G et al (2015) Probing the interfacial interaction in layered-carbon-stabilized iron oxide nanostructures: a soft x-ray spectroscopic study. ACS Appl Mater Interfaces 7(15):7863–786810.1021/am5073996 ↗
41. Zhou S, Potzger K, Xu Q et al (2009) Spinel ferrite nanocrystals embedded inside ZnO: magnetic, electronic, and magnetotransport properties. Phys Rev B 80(9):09440910.1103/PhysRevB.80.094409 ↗
42. Li M, Yin Y, Li C et al (2011) Well-dispersed bi-component-active CoO/CoFe2O4 nanocomposites with tunable performances as anode materials for lithium-ion batteries. Chem Commun 48:410–41210.1039/C1CC15322F ↗
43. Chen J, Xu L, Li W, Gao X (2005) α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications. Adv Mater 17:582–58610.1002/adma.200401101 ↗
44. Wu ZS, Ren W, Wen L et al (2010) Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 4:3187–319410.1021/nn100740x ↗
45. Zheng T, Gozdz AS, Amatucci GG (1999) Reactivity of the solid electrolyte interface on carbon electrodes at elevated temperatures. J Electrochem Soc 146:4014–401810.1149/1.1392585 ↗
46. Hu YS, Demir-Cakan R, Titirici MM, Antonietti M, Maier J (2008) Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-Ion batteries. Angew Chem Int Ed 47:1645–164910.1002/anie.200704287 ↗
47. Shen L, Che Q, Li H, Zhang X (2014) Mesoporous NiCo2O4 nanowire arrays grown on carbon textiles as binder-free flexible electrodes for energy storage. Adv Funct Mater 24:2630–263710.1002/adfm.201303138 ↗
48. Grugeon S, Laruelle S, Dupont L, Tarascon JM (2003) An update on the reactivity of nanoparticles Co-based compounds towards Li. Solid State Ionics 5:895–904
49. Laruelle S, Grugeon S, Poizot P, Dupont L, Tarascon JM (2002) On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential. J Electrochem Soc 149:627–63410.1149/1.1467947 ↗
50. Chen CH, Hwang BJ, Do JS et al (2010) An understanding of anomalous capacity of nano-sized CoO anode materials for advanced Li-ion battery. Electrochem Commun 12:496–49810.1016/j.elecom.2010.01.031 ↗