journal article·2017-09

A three-dimensional network structure Si/C anode for Li-ion batteries

Ying Jiang, Shi Chen, Daobin Mu, Borong Wu, Qi Liu, Zhikun Zhao, Feng Wu

Journal of Materials Science· Volume 52· Issue 18
Publisher page

Abstract

A three-dimensional (3D) network structure Si/C anode with large pores is fabricated by using gelatin-PVA as carbon source. Silicon particles are embedded in the 3D network carbon skeleton. Gaussian calculation and FTIR test are employed to analyze the role of molecules interaction in forming the 3D network structure. The modified Si/C anode exhibits a reversible capacity of 830 mA h g−1 after 100 cycles at 400 mA g−1, and a capacity of 810 mA h g−1 at 1.6 A g−1 and 521 mA h g−1 at 3.2 A g−1. The 3D network structure with large pores benefits the electrolyte penetration, and the carbon coating layer avoids the direct contact of silicon particles with the electrolyte. The carbon layer can also help buffer the volume expansion of silicon, which is good to the cycling stability. All these aspects contribute to the enhanced electrochemical performance of the Si anode.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Szczech JR, Jin S (2011) Nanostructured silicon for high capacity lithium battery anodes. Energy Environ Sci 4:56–7210.1039/C0EE00281J ↗
2. Wu H, Cui Y (2012) Designing nanostructured Si anodes for high energy lithium ion batteries. Nano Today 7:414–42910.1016/j.nantod.2012.08.004 ↗
3. Ashuri M, He Q, Shaw LL (2016) Silicon as a potential anode material for Li-ion batteries: where size, geometry and structure matter. Nanoscale 8:74–10310.1039/C5NR05116A ↗
4. Kasavajjula U, Wang CS, Appleby AJ (2007) Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells. J Power Sources 163:1003–103910.1016/j.jpowsour.2006.09.084 ↗
5. Sun F, Markotter H, Dong K, Manke I, Hilger A, Kardjilov N, Banhart J (2016) Investigation of failure mechanisms in silicon based half cells during the first cycle by micro X-ray tomography and radiography. J Power Sources 321:174–18410.1016/j.jpowsour.2016.04.126 ↗
6. Obrovac MN, Christensen L (2004) Structural changes in silicon anodes during lithium insertion/extraction. Electrochem Solid State Lett 7:A9310.1149/1.1652421 ↗
7. Tang H, Zhang J, Zhang YJ, Xiong QQ, Tong YY, Li Y, Wang XL, Gu CD, Tu JP (2015) Porous reduced graphene oxide sheet wrapped silicon composite fabricated by steam etching for lithium-ion battery application. J Power Sources 286:431–43710.1016/j.jpowsour.2015.03.185 ↗
8. Tang H, Zhang YJ, Xiong QQ, Cheng JD, Zhang Q, Wang XL, Gu CD, Tu JP (2015) Self-assembly silicon/porous reduced graphene oxide composite film as a binder-free and flexible anode for lithium-ion batteries. Electrochim Acta 156:86–9310.1016/j.electacta.2015.01.009 ↗
9. Zhang W, Wu L, Du L, Yue L, Guan R, Zhang Q, Hou G, Shao R (2016) Layer-by-layer assembly modification to prepare firmly bonded Si–graphene composites for high-performance anodes. RSC Adv 6:4835–484210.1039/C5RA19943C ↗
10. Wu H, Yu G, Pan L, Liu N, McDowell MT, Bao Z, Cui Y (2013) Stable Li-ion battery anodes by in situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles. Nat Commun 4:194310.1038/ncomms2941 ↗
11. Lijuan K, Ruiyi L, Yongqiang Y, Zaijun L (2016) Multi-faceted design of a silicon anode for high performance lithium ion batteries using silicon nanoparticles encapsulated by a multiple graphene aerogel electrode material and a tryptophan-functionalized graphene quantum dot–sodium alginate binder. RSC Adv 6:76344–7635410.1039/C6RA15257K ↗
12. Tang H, Xia XH, Zhang YJ, Tong YY, Wang XL, Gu CD, Tu JP (2015) Binary conductive network for construction of Si/Ag nanowires/rGO integrated composite film by vacuum-filtration method and their application for lithium ion batteries. Electrochim Acta 180:1068–107410.1016/j.electacta.2015.09.032 ↗
13. Tang H, J-p Tu, X-y Liu, Y-j Zhang, Huang S, W-z Li, Wang X-l, Gu C-d (2014) Self-assembly of Si/honeycomb reduced graphene oxide composite film as a binder-free and flexible anode for Li-ion batteries. J Mater Chem A 2:5834–584010.1039/C3TA15395A ↗
14. Zhang YQ, Xia XH, Wang XL, Mai YJ, Shi SJ, Tang YY, Li L, Tu JP (2012) Silicon/graphene-sheet hybrid film as anode for lithium ion batteries. Electrochem Commun 23:17–2010.1016/j.elecom.2012.07.001 ↗
15. Zhou J, Lan Y, Zhang K, Xia G, Du J, Zhu Y, Qian Y (2016) In situ growth of carbon nanotube wrapped Si composites as anodes for high performance lithium ion batteries. Nanoscale 8:4903–490710.1039/C5NR08961A ↗
16. Ren W, Wang Y, Zhang Z, Tan Q, Zhong Z, Su F (2016) Carbon-coated porous silicon composites as high performance Li-ion battery anode materials: can the production process be cheaper and greener? J Mater Chem A 4:552–56010.1039/C5TA07487H ↗
17. Zhang YC, You Y, Xin S, Yin YX, Zhang J, Wang P, Zheng XS, Cao FF, Guo YG (2016) Rice husk-derived hierarchical silicon/nitrogen-doped carbon/carbon nanotube spheres as low-cost and high-capacity anodes for lithium-ion batteries. Nano Energy 25:120–12710.1016/j.nanoen.2016.04.043 ↗
18. Wu J, Qin X, Miao C, He Y-B, Liang G, Zhou D, Liu M, Han C, Li B, Kang F (2016) A honeycomb-cobweb inspired hierarchical core–shell structure design for electrospun silicon/carbon fibers as lithium-ion battery anodes. Carbon 98:582–59110.1016/j.carbon.2015.11.048 ↗
19. Wu LL, Yang J, Zhou XY, Zhang MF, Ren YP, Nie Y (2016) Silicon nanoparticles embedded in a porous carbon matrix as a high-performance anode for lithium-ion batteries. J Mater Chem A 4:11381–1138710.1039/C6TA04398D ↗
20. Lu Z, Liu N, Lee H-W, Zhao J, Li W, Li Y, Cui Y (2015) Nonfilling carbon coating of porous silicon micrometer-sized particles for high-performance lithium battery anodes. ACS Nano 9:2540–2547. doi: 10.1021/nn505410q10.1021/nn505410q ↗
21. Wang JJ, Xu TT, Huang X, Li H, Ma TL (2016) Recent progress of silicon composites as anode materials for secondary batteries. RSC Adv 6:87778–8779010.1039/C6RA08971B ↗
22. Shi Y, Zhang J, Pan L, Shi Y, Yu G (2016) Energy gels: a bio-inspired material platform for advanced energy applications. Nano Today 11:738–76210.1016/j.nantod.2016.10.002 ↗
23. Shi Y, Zhang J, Bruck AM, Zhang Y, Li J, Stach EA, Takeuchi KJ, Marschilok AC, Takeuchi ES, Yu G (2017) A tunable 3D nanostructured conductive gel framework electrode for high-performance lithium ion batteries. Adv Mater. doi: 10.1002/adma.20160392210.1002/adma.201603922 ↗
24. Shi Y, Yu G (2016) Designing hierarchically nanostructured conductive polymer gels for electrochemical energy storage and conversion. Chem Mater 28:2466–247710.1021/acs.chemmater.5b04879 ↗
25. Shi L, Wang WK, Wang AB, Yuan KG, Jin ZQ, Yang YS (2015) Si nanoparticles adhering to a nitrogen-rich porous carbon framework and its application as a lithium-ion battery anode material. J Mater Chem A 3:18190–1819710.1039/C5TA03974F ↗
26. Qie L, Chen WM, Wang ZH, Shao QG, Li X, Yuan LX, Hu XL, Zhang WX, Huang YH (2012) Nitrogen-doped porous carbon nanofiber webs as anodes for lithium ion batteries with a superhigh capacity and rate capability. Adv Mater 24:2047–205010.1002/adma.201104634 ↗
27. Chaibi S, Benachour D, Merbah M, Cagiao ME, Calleja FJB (2015) The role of crosslinking on the physical properties of gelatin based films. Colloid Polym Sci 293:2741–275210.1007/s00396-015-3660-2 ↗
28. Song JX, Zhou MJ, Yi R, Xu T, Gordin ML, Tang DH, Yu ZX, Regula M, Wang DH (2014) Interpenetrated gel polymer binder for high-performance silicon anodes in lithium-ion batteries. Adv Funct Mater 24:5904–591010.1002/adfm.201401269 ↗
29. Pirzada T, Arvidson SA, Saquing CD, Shah SS, Khan SA (2012) Hybrid silica-PVA nanofibers via sol-gel electrospinning. Langmuir 28:5834–584410.1021/la300049j ↗
30. Zhou ZW, Liu YT, Xie XM, Ye XY (2016) Constructing novel Si@SnO2 core–shell heterostructures by Facile self-assembly of SnO2 nanowires on silicon hollow nanospheres for large, reversible lithium storage. ACS Appl Mater Interfaces 8:7092–710010.1021/acsami.6b00107 ↗
31. Kong J, Yee WA, Wei Y, Yang L, Ang JM, Phua SL, Wong SY, Zhou R, Dong Y, Li X, Lu X (2013) Silicon nanoparticles encapsulated in hollow graphitized carbon nanofibers for lithium ion battery anodes. Nanoscale 5:2967–297310.1039/c3nr34024d ↗
32. Tao HC, Huang MA, Fan LZ, Qu XH (2013) Effect of nitrogen on the electrochemical performance of core–shell structured Si/C nanocomposites as anode materials for Li-ion batteries. Electrochim Acta 89:394–39910.1016/j.electacta.2012.11.092 ↗
33. Gu J, Zeng Y, Feng X, Wu X, Zeng C, Li M (2016) Synthesis of nanosilicon@nonstoichiometric silicon oxide from bulk silicon dioxide and its lithium storage properties. J Alloys Compd 662:185–19210.1016/j.jallcom.2015.12.009 ↗
34. Zhang M, Hou X, Wang J, Li M, Hu S, Shao Z, Liu X (2014) Interweaved Si@C/CNTs&CNFs composites as anode materials for Li-ion batteries. J Alloys Compd 588:206–21110.1016/j.jallcom.2013.10.160 ↗
35. Su L, Zhou Z, Ren M (2010) Core double-shell Si@SiO2@C nanocomposites as anode materials for Li-ion batteries. Chem Commun 46:2590–259210.1039/b925696b ↗
36. Tao HC, Yang XL, Zhang LL, Ni SB (2014) Double-walled core–shell structured Si@SiO2@C nanocomposite as anode for lithium-ion batteries. Ionics 20:1547–155210.1007/s11581-014-1138-8 ↗
37. Wang J, Yu Y, Gu L, Wang C, Tang K, Maier J (2013) Highly reversible lithium storage in Si (core)-hollow carbon nanofibers (sheath) nanocomposites. Nanoscale 5:2647–265010.1039/c3nr00322a ↗
38. Marinaro M, Weinberger M, Wohlfahrt-Mehrens M (2016) Toward pre-lithiatied high areal capacity silicon anodes for Lithium-ion batteries. Electrochim Acta 206:99–10710.1016/j.electacta.2016.03.139 ↗
39. Zhao J, Lu Z, Liu N, Lee HW, McDowell MT, Cui Y (2014) Dry-air-stable lithium silicide-lithium oxide core–shell nanoparticles as high-capacity prelithiation reagents. Nat Commun 5:508810.1038/ncomms6088 ↗
40. Pang CL, Song HW, Li N, Wang CX (2015) A strategy for suitable mass production of a hollow Si@C nanostructured anode for lithium ion batteries. RSC Adv 5:6782–678910.1039/C4RA10849C ↗
41. Shao D, Tang DP, Mai YJ, Zhang LZ (2013) Nanostructured silicon/porous carbon spherical composite as a high capacity anode for Li-ion batteries. J Mater Chem A 1:15068–1507510.1039/c3ta13616g ↗