DataVXJournal of Materials SciencePaper
journal article·2008-06Open access

Synthesis of lamellar mesostructured calcium phosphates using n-alkylamines as structure-directing agents in alcohol/water mixed solvent systems

Nobuaki Ikawa, Yasunori Oumi, Tatsuo Kimura, Takuji Ikeda, Tsuneji Sano

Journal of Materials Science· Volume 43· Issue 12
Publisher pageOpen full text
Source abstract

Abstract

Lamellar mesostructured calcium phosphates constructed by ionic bonds were prepared by using n-alkylamines (n-CnH2n+1NH2, n = 8–18) at room temperature in the mixed solvent systems of aliphatic alcohol (CnH2n+1OH, n = 1–4) and water, and the synthetic conditions were investigated in detail. The mixed solvent systems suppressed the formation of crystalline calcium phosphates like brushite (CaHPO4·2H2O) and monetite (CaHPO4) at low temperatures, successfully affording pure lamellar mesostructured calcium phosphates. Other crystalline phases such as hydroxyapatite (Ca10(PO4)6(OH)2) were not formed under the conditions with the Ca/P molar ratios in the range of 0.7–1.0 in the starting mixtures. The Ca/P molar ratio of the lamellar mesostructured calcium phosphates was ca. 1.0, calculated by ICP and 31P MAS NMR data. Interestingly, the kind of alcohols strongly influenced the solubilities of calcium phosphate species and n-alkylamines, and then lamellar mesostructured phases were obtained with some morphological variation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Bone Tissue Engineering Materials · Mesoporous Materials and Catalysis · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Yanagisawa T, Shimizu T, Kuroda K, Kato C (1990) Bull Chem Soc Jpn 63:988. doi:https://doi.org/10.1246/bcsj.63.98810.1246/bcsj.63.988 ↗
2. Inagaki S, Fukushima Y, Kudoda K (1993) J Chem Soc Chem Commun 680. doi:https://doi.org/10.1039/c3993000068010.1039/c39930000680 ↗
3. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710. doi:https://doi.org/10.1038/359710a010.1038/359710a0 ↗
4. Beck S, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CT-W, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL (1992) J Am Chem Soc 114:10834. doi:https://doi.org/10.1021/ja00053a02010.1021/ja00053a020 ↗
5. Zhao D, Feng L, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548. doi:https://doi.org/10.1126/science.279.5350.54810.1126/science.279.5350.548 ↗
6. Zhao XS, Lu GQ, Millar GJ (1996) Ind Eng Chem Res 35:2075. doi:https://doi.org/10.1021/ie950702a10.1021/ie950702a ↗
7. Selvam P, Bhatia SK, Sonwane CG (2001) Ind Eng Chem Res 40:3237. doi:https://doi.org/10.1021/ie001066610.1021/ie0010666 ↗
8. Sayari A (1996) Chem Mater 8:1840. doi:https://doi.org/10.1021/cm950585±10.1021/cm950585± ↗
9. Corma A (1997) Chem Rev 97:2373. doi:https://doi.org/10.1021/cr960406n10.1021/cr960406n ↗
10. Taguchi A, Schüth F (2005) Micropor Mesopor Mater 77:1. doi:https://doi.org/10.1016/j.micromeso.2004.06.03010.1016/j.micromeso.2004.06.030 ↗
11. Schüth F (2003) Angew Chem Int Ed 42:3604. doi:https://doi.org/10.1002/anie.20030059310.1002/anie.200300593 ↗
12. Monma H (1995) Inorg Mater 2:401
13. Rodriguez-Lorenzo LM, Vallet-Regi M (2000) Chem Mater 12:2460. doi:https://doi.org/10.1021/cm001033g10.1021/cm001033g ↗
14. Uota M, Arakawa H, Kitamura N, Yoshimura T, Tanaka J, Kijima T (2005) Langmuir 21:4724. doi:https://doi.org/10.1021/la050029m10.1021/la050029m ↗
15. Vallet-Regí M, Ruiz-González L, Izquierdo-Barba I, González-Calbet JM (2006) J Mater Chem 16:26. doi:https://doi.org/10.1039/b509744d10.1039/b509744d ↗
16. Huo Q, Leon R, Petroff PM, Stucky GD (1995) Science 268:1324. doi:https://doi.org/10.1126/science.268.5215.132410.1126/science.268.5215.1324 ↗
17. Huo Q, Margolese DI, Stucky GD (1996) Chem Mater 8:1147. doi:https://doi.org/10.1021/cm960137h10.1021/cm960137h ↗
18. Behrens P (1996) Angew Chem Int Ed 35:515. doi:https://doi.org/10.1002/anie.19960515110.1002/anie.199605151 ↗
19. Sayari A, Liu P (1997) Micropor Mater 12:149. doi:https://doi.org/10.1016/S0927-6513(97)00059-X10.1016/S0927-6513(97)00059-X ↗
20. Schüth F (2001) Chem Mater 13:3184. doi:https://doi.org/10.1021/cm011030j10.1021/cm011030j ↗
21. Tiemann M, Fröba M (2001) Chem Mater 13:3211. doi:https://doi.org/10.1021/cm011037110.1021/cm0110371 ↗
22. Kimura T (2005) Micropor Mesopor Mater 77:97. doi:https://doi.org/10.1016/j.micromeso.2004.08.02310.1016/j.micromeso.2004.08.023 ↗
23. Yu C, Tian B, Zhao D (2003) Curr Opin Solid State Mater Sci 7:191. doi:https://doi.org/10.1016/j.cossms.2003.10.00410.1016/j.cossms.2003.10.004 ↗
24. Gao Q, Xu R, Chen J, Li R, Li S, Qui S, Yue YJ (1997) Chem Mater 9:457. doi:https://doi.org/10.1021/cm960261110.1021/cm9602611 ↗
25. Kimura T, Sugawara Y, Kuroda K (1999) Chem Mater 11:508. doi:https://doi.org/10.1021/cm981036h10.1021/cm981036h ↗
26. Mal NK, Fujiwara M, Ichikawa S, Kuraoka K (2002) J Ceram Soc Jpn 110:89010.2109/jcersj.110.890 ↗
27. Mal NK, Ichikawa S, Fujiwara M (2003) Chem Commun 872. doi:https://doi.org/10.1039/b300323j10.1039/b300323j ↗
28. Roca M, Haskouri JE, Cabrera S, Beltrán-Porter A, Alamo J, Beltrán-Porter D, Macros MD, Amorós P (1998) Chem Commun 1883. doi:https://doi.org/10.1039/a803896a10.1039/a803896a ↗
29. Dasgupta S, Agarwal M, Datta A (2002) J Mater Chem 12:162. doi:https://doi.org/10.1039/b109472f10.1039/b109472f ↗
30. Jiménez-Jiménez J, Maireles-Torres P, Olivera-Pastor P, Rodríguez-Castellón E, Jiménez-López A, Jones DJ, Rozière J (1998) Adv Mater 10:812. doi:https://doi.org/10.1002/(SICI)1521-4095(199807)10:10≤812::AID-ADMA812≥3.0.CO;2-A10.1002/(SICI)1521-4095(199807)10:10≤812::AID-ADMA812≥3.0.CO;2-A ↗
31. Jones DJ, Aptel G, Brandhorst M, Jacquin M, Jiménez-Jiménez J, Jiménez-López A, Maireles-Torres P, Piwonski I, Rodríguez-Castellón E, Zajac J, Rozière J (2000) J Mater Chem 10:1957. doi:https://doi.org/10.1039/b002474k10.1039/b002474k ↗
32. Bhaumik A, Inagaki S (2001) J Am Chem Soc 123:691. doi:https://doi.org/10.1021/ja002481s10.1021/ja002481s ↗
33. Guo X, Ding W, Wang X, Yan Q (2001) Chem Commun 709. doi:https://doi.org/10.1039/b100630o10.1039/b100630o ↗
34. Chang J-S, Park S-E, Gao Q, Férey G, Cheetham AK (2001) Chem Commun 859. doi:https://doi.org/10.1039/b009160j10.1039/b009160j ↗
35. Tarafdar A, Biswas S, Pramanik NK, Pramanik P (2006) Micropor Mesopor Mater 89:204. doi:https://doi.org/10.1016/j.micromeso.2005.10.02710.1016/j.micromeso.2005.10.027 ↗
36. Mal NK, Ichikawa S, Fujiwara M (2002) Chem Commun 112. doi:https://doi.org/10.1039/b109948e10.1039/b109948e ↗
37. Ozin GA, Varaksa N, Coombs N, Davies JE, Perovic DD, Ziliox M (1997) J Mater Chem 7:1601. doi:https://doi.org/10.1039/a702416i10.1039/a702416i ↗
38. Soten I, Ozin GA (1999) J Mater Chem 9:703. doi:https://doi.org/10.1039/a806045b10.1039/a806045b ↗
39. Yao J, Tjandra W, Chen YZ, Tam KC, Ma J, Soh B (2003) J Mater Chem 13:3053. doi:https://doi.org/10.1039/b308801d10.1039/b308801d ↗
40. Schmidt SM, McDonald J, Pineda ET, Verwilst AM, Chen Y, Josephs R, Ostefin AE (2006) Micropor Mesopor Mater 94:330. doi:https://doi.org/10.1016/j.micromeso.2006.04.00610.1016/j.micromeso.2006.04.006 ↗
41. Tokuoka Y, Ito Y, Kitahara K, Niikura Y, Ochiai A, Kawashima N (2006) Chem Lett 35:1220. doi:https://doi.org/10.1246/cl.2006.122010.1246/cl.2006.1220 ↗
42. Zhao YF, Ma J (2005) Micropor Mesopor Mater 87:110. doi:https://doi.org/10.1016/j.micromeso.2005.07.04610.1016/j.micromeso.2005.07.046 ↗
43. Ikawa N, Oumi Y, Kimura T, Ikeda T, Sano T (2006) Chem Lett 35:948. doi:https://doi.org/10.1246/cl.2006.94810.1246/cl.2006.948 ↗
44. Eanes ED, Gillessen IH, Posner AS (1965) Nature 208:365. doi:https://doi.org/10.1038/208365a010.1038/208365a0 ↗
45. Oliver SRJ, Ozin GA (1998) J Mater Chem 8:1081. doi:https://doi.org/10.1039/a708598b10.1039/a708598b ↗
46. Sivakumar GR, Girija EK, Karukura SN, Subramanian C (1998) Cryst Res Technol 33:197. doi:https://doi.org/10.1002/(SICI)1521-4079(1998)33:2≤197::AID-CRAT197≥3.0.CO;2-K10.1002/(SICI)1521-4079(1998)33:2≤197::AID-CRAT197≥3.0.CO;2-K ↗
47. Larson MJ, Thorsen A, Jensen SJ (1985) Calcif Tissue Int 37:189. doi:https://doi.org/10.1007/BF0255484010.1007/BF02554840 ↗
48. Kim S, Ryu HS, Shin H, Jung HS, Hong KS (2005) Mater Chem Phys 91:500. doi:https://doi.org/10.1016/j.matchemphys.2004.12.01610.1016/j.matchemphys.2004.12.016 ↗
49. Aue WP, Roufosse AH, Glimcher MJ, Griffin RG (1984) Biochemistry 23:6110. doi:https://doi.org/10.1021/bi00320a03210.1021/bi00320a032 ↗
50. Miquel JL, Facchini L, Legrand AP, Rey C, Lemaitre J (1990) Colloids Surfaces 45:427. doi:https://doi.org/10.1016/0166-6622(90)80041-210.1016/0166-6622(90)80041-2 ↗
51. Furuichi K, Oaki Y, Imai H (2006) Chem Mater 18:229. doi:https://doi.org/10.1021/cm052213z10.1021/cm052213z ↗
52. Simonutti R, Comotti A, Bracco S, Sozzani P (2001) Chem Mater 13:771. doi:https://doi.org/10.1021/cm001088i10.1021/cm001088i ↗
53. Kooli F, Mianhui L, Alshahateet SF, Chen F, Yinghuai Z (2006) J Phys Chem Solids 67:926. doi:https://doi.org/10.1016/j.jpcs.2006.01.00510.1016/j.jpcs.2006.01.005 ↗
54. Kitaigorodskii AI (1973) Molecular crystals and molecules. Academic Press, New York