journal article·2012-01

Synthesis and capacitive property of δ-MnO2 with large surface area

Xin Zhang, Xiaopei Chang, Na Chen, Kuan Wang, Liping Kang, Zong-huai Liu

Journal of Materials Science· Volume 47· Issue 2
Publisher page

Abstract

δ-MnO2 with layered structure is synthesized in a mixed system of KMnO4 and C3H6O (epoxypropane) by a facile low-temperature hydrothermal method at 90 °C for 24 h. The obtained product is characterized by X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy, and N2 adsorption–desorption, and its electrochemical property was investigated by cyclic voltammetry method. Experiment results show that the as-synthesized product has a layered structure and a high specific surface area of 188 m2 g−1, and C3H6O existing in the reaction system plays a crucial role for the formation of δ-MnO2 particles. Electrochemical characterization indicates that the prepared material exhibits an ideal capacitive behavior with the initial capacitance value of 296 F g−1 in 1 mol L−1 Na2SO4 aqueous solution at a scan rate of 5 mV s−1 and good cycling behavior.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Polyoxometalates: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Yan D, Yan PX, Cheng S, Chen JT, Zhuo RF, Feng JJ, Zhang GA (2009) Cryst Growth Des 9:21810.1021/cg800312u ↗
2. Nagarajan N, Cheong M, Zhitomirsky I (2007) Mater Chem Phys 103:4710.1016/j.matchemphys.2007.01.005 ↗
3. Beaudrouet E, Salle ALGL, Guyomard D (2009) Electrochim Acta 54:124010.1016/j.electacta.2008.08.072 ↗
4. Tian ZR, Tong W, Wang JY, Duan NG, Krishnan VV, Suib SL (1997) Science 276:92610.1126/science.276.5314.926 ↗
5. Yan J, Fan ZJ, Wei T, Qian WZ, Zhang ML, Wei F (2010) Carbon 48:382510.1016/j.carbon.2010.06.047 ↗
6. Ma SB, Nam KW, Yoon WS, Yang XQ, Ahn KY, Oh KH, Kim KB (2008) J Power Sour 178:48310.1016/j.jpowsour.2007.12.027 ↗
7. Komaba S, Ogata A, Tsuchikawa T (2008) Electrochem Commun 10:143510.1016/j.elecom.2008.07.025 ↗
8. An GM, Yu P, Xiao MJ, Liu ZM, Miao ZJ, Ding KL, Mao LQ (2008) Nanotechnology 19:27570910.1088/0957-4484/19/27/275709 ↗
9. Yu P, Zhang X, Wang DL, Wang L, Ma YW (2009) Cryst Growth Des 9:52810.1021/cg800834g ↗
10. Devaraj S, Munichandraiah N (2008) J Phys Chem C 112:440610.1021/jp7108785 ↗
11. Luo JY, Cheng L, Xia YY (2007) Electrochem Commun 9:140410.1016/j.elecom.2007.01.058 ↗
12. Tang XH, Liu Z-H, Zhang CX, Yang ZP, Wang ZL (2009) J Power Sour 193:93910.1016/j.jpowsour.2009.04.037 ↗
13. Wei WF, Cui XW, Chen WX, Ivey DG (2011) Chem Soc Rev 40:169710.1039/C0CS00127A ↗
14. Ma RZ, Bando Y, Zhang LQ, Sasaki T (2004) Adv Mater 16:91810.1002/adma.200306592 ↗
15. Liu ZP, Ma RZ, Ebina Y, Takada K, Sasaki T (2007) Chem Mater 19:650410.1021/cm7019203 ↗
16. Zhang LC, Kang LP, Lv H, Su ZK, Ooi K, Liu Z-H (2008) J Mater Res 23:78010.1557/JMR.2008.0091 ↗
17. Ge JC, Zhuo LH, Yang F, Tang B, Wu LZ, Tung C (2006) J Phys Chem B 110:1785410.1021/jp0631127 ↗
18. Subramanian V, Zhu HW, Wei BQ (2006) J Power Sour 159:36110.1016/j.jpowsour.2006.04.012 ↗
19. Subramanian V, Zhu HW, Vajtai R, Ajayan PM, Wei BQ (2005) J Phys Chem B 109:2020710.1021/jp0543330 ↗
20. Yuan CZ, Gao B, Zhang XG (2007) J Power Sour 173:60610.1016/j.jpowsour.2007.04.034 ↗
21. Kruk M, Jaroniec M (2001) Chem Mater 13:316910.1021/cm0101069 ↗
22. Xu RR, Pang WQ (2005) Chemistry—zeolites and porous materials. Science Press, Beijing
23. Xu CJ, Li BH, Du HD, Kang FY, Zeng YQ (2008) J Power Sour 180:66410.1016/j.jpowsour.2008.02.029 ↗
24. Yuan JQ, Liu Z-H, Qiao SF, Ma XR, Xu NC (2009) J Power Sour 189:127810.1016/j.jpowsour.2008.12.148 ↗