journal article·2007-12

Aqueous processing of lithium-ion battery cathodes using hydrogen peroxide-treated vapor-grown carbon fibers for improvement of electrochemical properties

Jyh-Tsung Lee, Yung-Ju Chu, Fu-Ming Wang, Chang-Rung Yang, Chia-Chen Li

Journal of Materials Science· Volume 42· Issue 24
Publisher page

Abstract

The electrochemical behavior of aqueous processing lithium cobalt oxide (LiCoO2) cathodes used hydrogen peroxide (H2O2)-treated vapor-grown carbon fibers (VGCFs) as a conductive agent for lithium-ion batteries has been investigated and improved. The sedimentation experiments show that the dispersibility in water of H2O2-treated VGCFs is better than that of KS-6 (flaky graphite) or as-received VGCFs. This improvement is due to the surface chemistry of H2O2-treated VGCFs has become more hydrophilic that was evidenced by its significant shift of iso-electric point (I.E.P) from pH 6.7 to 5.0. As a result, the H2O2-treated VGCFs can be well-dispersed in the LiCoO2 electrode which was observed by scanning electron microscope. Furthermore, the rate capability results of electrodes show that addition with H2O2-treated VGCFs has better performance than that with KS-6 or as-received VGCFs.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

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References (31)

Show source-provided references
1. Dey AN, Sulliva BP (1970) J Electrochem Soc 117:22210.1149/1.2407470 ↗
2. Wolverton C, Zunger A (1998) J Electrochem Soc 145:242410.1149/1.1838653 ↗
3. Cheon SE, Kwon CW, Kim DB, Hong SJ, Kim HT, Kim SW (2000) Electrochim Acta 46:59910.1016/S0013-4686(00)00626-5 ↗
4. Fransson L, Eriksson T, Edström K, Gustafsson T, Thomas JO (2001) J Power Sources 101:110.1016/S0378-7753(01)00481-5 ↗
5. Liu Z, Yu A, Lee JY (1998) J Power Sources 74:22810.1016/S0378-7753(98)00071-8 ↗
6. Kim KM, Jeon WS, Chung IJ, Chang SH (1999) J Power Sources 83:10810.1016/S0378-7753(99)00281-5 ↗
7. Kosova N, Devyatkina E, Osintsey D (2004) J Mater Sci 39:503110.1023/B:JMSC.0000039181.03644.b0 ↗
8. Kim J, Kim B, Lee JG, Cho J, Park B (2005) J Power Sources 139:28910.1016/j.jpowsour.2004.07.008 ↗
9. Li CC, Lee JT, Lo CY, Wu MS (2005) Electrochem Solid State Lett 8:A50910.1149/1.2012287 ↗
10. Li CC, Lee JT, Peng XW (2006) J Electrochem Soc 153:A80910.1149/1.2177071 ↗
11. Yang HQ, Li DP, Han S, Li N, Lin BX (1995) J Power Sources 58:22110.1016/S0378-7753(96)02380-4 ↗
12. Saekil S, Lee J, Zhang Q, Saito F (2004) Int J Miner Process 74S:S37310.1016/j.minpro.2004.08.002 ↗
13. Nahass P, Rhine WE, Pober RL, Bowen HK, Robbins WL (1990) In: Nair KM, Pohanka R, Buchanan RC (eds) Ceramic transactions, vol 15. American Ceramic Society, Westerville, p 355
14. Endo M, Kim YA, Takeda T, Hong SH, Matusita T, Hayashi T, Dresselhaus MS (2001) Carbon 39:128710.1016/S0008-6223(00)00295-5 ↗
15. Mizuno F, Hayashi A, Tadanaga K, Tatsumisago M (2005) J Electrochem Soc 152:A149910.1149/1.1939633 ↗
16. Mizuno F, Hayashi A, Tadanaga K, Tatsumisago M (2005) J Power Sources 146:71110.1016/j.jpowsour.2005.03.161 ↗
17. Her LJ, Hong JL, Chang CC (2006) J Power Sources 157:45710.1016/j.jpowsour.2005.07.047 ↗
18. Liu J, Rinzler AG, Dai HJ, Hafner JH, Bradley RK, Boul PJ, Lu A, Iverson T, Shelimov K, Huffman CB, Rodriguez-Macias F, Shon YS, Lee TR, Colbert DT, Smalley RE (1998) Science 280:125310.1126/science.280.5367.1253 ↗
19. Jia Z, Wang Z, Liang J, Wei B, Wu D (1999) Carbon 37:90310.1016/S0008-6223(98)00229-2 ↗
20. Saito T, Matsushige K, Tanaka K (2002) Physica B 323:28010.1016/S0921-4526(02)00999-7 ↗
21. Wang Y, Wu J, Wei F (2003) Carbon 41:293910.1016/S0008-6223(03)00390-7 ↗
22. Hilding J, Grulke EA, Zhang ZG, Lockwood F (2003) J Disper Sci Technol 24:110.1081/DIS-120017941 ↗
23. Hirsch A (2002) Angew Chem Int Ed 41:185310.1002/1521-3773(20020603)41:11<1853::AID-ANIE1853>3.0.CO;2-N ↗
24. Hamon MA, Chen J, Hu H, Chen Y, Itkis ME, Rao AM, Eklund PC, Haddon RC (1999) Adv Mater 11:83410.1002/(SICI)1521-4095(199907)11:10<834::AID-ADMA834>3.0.CO;2-R ↗
25. Li CC, Lin JL, Huang SJ, Lee JT, Chen CH (2007) Colloids Surf A 297:27510.1016/j.colsurfa.2006.10.022 ↗
26. Goto H, Furuta T, Fujiwara Y, Ohashi T (2003) US patent 20030007924A1
27. Hernadi K, Siska A, Thien-Nga L, Forrob L, Kiricsi I (2001) Solid State Ionics 141:20310.1016/S0167-2738(01)00789-5 ↗
28. Gil A, de la Puente G, Grange P (1997) Microporous Mater 12:5110.1016/S0927-6513(97)00057-6 ↗
29. Concheso A, Santamaría R, Menéndez R, Jiménez-Mateos JM, Alcántara R, Lavela P, Tirado JL (2006) Electrochim Acta 52:128110.1016/j.electacta.2006.07.029 ↗
30. Xing Y, Li L, Chusuei CC, Hull RV (2005) Langmuir 21:418510.1021/la047268e ↗
31. Hontora-Lucas C, Lopez-Peinado AJ, Lopez-Gonzales JD, Rojas-Cervantes ML, Martin-Aranda RM (1995) Carbon 33:158510.1016/0008-6223(95)00120-3 ↗