Hydration-induced reinforcement of polyurethane–cement foams: solvent resistance and mechanical properties
Source abstract
Abstract
Solvent resistance and mechanical properties of hydration-induced reinforcement of polyurethane-cement foams are discussed. The results of solvent swelling measurements are reported to highlight the significant influence of the interconnected inorganic acicular structure type reinforcement within the walls of the cells of newly developed polyurethane or cement hybrid foam. It is demonstrated that the cement particles are discretely dispersed in the polyurethane matrix before the hydration step, while a state of interconnected network is acquired after the hydration step. This process provides a high resistance to solvent swelling after hydration, along with a large increase in modulus and strength. The polyurethane/cement foams have been prepared by mixing the polyol with catalysts, surfactants, water, and anhydrous cement particles and methylene-diphenyl di-isocyanate
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Polymer composites and self-healing
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References (18)
Show source-provided references
1. Huang HH, Orler B, Wilkes GL (1987) Macromolecules 20:132210.1021/ma00172a026 ↗
2. Sanchez C, Julián B, Belleville P, Popall M (2005) J Mater Chem 15:3559. doi: 10.1039/b509097k10.1039/b509097k ↗
3. Dorozhkin SV (2009) J Mater Sci 44:2343. doi: 10.1007/s10853-008-3124-x10.1007/s10853-008-3124-x ↗
4. Cluff DRA, Esmaeli S (2009) J Mater Sci 44:3867. doi: 10.1007/s10853-009-3525-510.1007/s10853-009-3525-5 ↗
5. Maji PK, Guchhait PK, Bhowmick AK (2009) J Mater Sci 44:5861. doi: 10.1007/s10853-009-3827-710.1007/s10853-009-3827-7 ↗
6. Castella N, Karger-Kocsis J, Grishchuk S, Unik M (2010) J Mater Sci 45:1734. doi: 10.1007/s10853-009-4145-910.1007/s10853-009-4145-9 ↗
7. Romero PG, Sanchez C (2004) Functional hybrid materials. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
8. Mascia L (1995) Trends Polym Sci 3:61
9. Mascia L (2010) In: Xanthos M (ed) In situ generated fillers. Wiley, VCH Verlag GmbH & Co., Weinheim
10. Verdolotti L, Di Maio E, Lavorgna M, Iannace S (2006) Patent nos. IT2006MI01325, WO2008/007187
11. Verdolotti L, Di Maio E, Lavorgna M, Iannace S (2008) J Appl Polym Sci 107:110.1002/app.24997 ↗
12. Iannace G, Masullo M, Di Maio E, Verdolotti L (2009) RIA 33:49
13. Mascia L, Prezzi L, Lavorgna M (2005) Polym Eng Sci 45:103910.1002/pen.20372 ↗
14. Verdolotti L, Forte G, Germino N, Di Maio E, Lavorgna M, Iannace S (2010) In: ICPIC proceedings, pp 273–278
15. Powers TC (1949) ASTM Bull 158:68
16. Chuang WY, Young TH, Wang DM, Luo RL, Sun YM (2000) Polymer 41:833910.1016/S0032-3861(00)00176-2 ↗
17. ASTM D1621 (2004) Standard test method for compressive properties of rigid cellular plastics
18. Taylor HFW (2004) In: Telford Thomas Service (ed) Cement chemistry. Academic Press, London