Layered Co–Mn hydroxide nanoflakes grown on carbon cloth as binder-free flexible electrodes for supercapacitors
Source abstract
Abstract
The layered Co–Mn hydroxide nanoflakes grown on carbon cloth (CC) have been successfully fabricated via a facile solvothermal method in a mixed solvent of water and methanol. The structure and morphology of final products could be readily tuned in a wide range by tuning volume ratios of methanol and water. The electrochemical measurements revealed that layered Co–Mn hydroxide nanoflakes grown on CC, exhibit a high-specific capacitance and remarkable cycling stability, which is of great importance for their practical applications in high-performance supercapacitor. Moreover, the specific capacitances of layered hydroxides would be enhanced with the expansion of interlayer spacing.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (34)
Show source-provided references
1. Li H, Ma J, Evans DG, Zhou T, Li F, Duan X (2006) Molecular dynamics modeling of the structures and binding energies of α-nickel hydroxides and nickel-aluminum layered double hydroxides containing various interlayer guest anions. Chem Mater 18:4405–441410.1021/cm060867h ↗
2. Arizaga GGC, Satyanarayana KG, Wypych F (2007) Layered hydroxide salts: synthesis, properties and potential applications. Solid State Ion 178:1143–116210.1016/j.ssi.2007.04.016 ↗
3. Geng F, Xin H, Matsushita Y, Ma R, Tanaka M, Izumi F, Iyi N, Sasaki T (2008) New layered rare-earth hydroxides with anion-exchange properties. Chemistry 14:9255–926010.1002/chem.200800127 ↗
4. Tezuka S, Chitrakar R, Sonoda A, Ooi K, Tomida T (2004) Studies on selective adsorbents for oxo-anions. Nitrate ion-exchange properties of layered double hydroxides with different metal atoms. Green Chem 6:104–10910.1039/b314938m ↗
5. Tsyganok AI, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T (2003) Dry reforming of methane over catalysts derived from nickel-containing Mg–Al layered double hydroxides. J Catal 213:191–20310.1016/S0021-9517(02)00047-7 ↗
6. Yang J-H, Han Y-S, Park M, Park T, Hwang S-J, Choy J-H (2007) New inorganic-based drug delivery system of indole-3-acetic acid-layered metal hydroxide nanohybrids with controlled release rate. Chem Mater 19:2679–268510.1021/cm070259h ↗
7. Stefanakis D, Ghanotakis DF (2010) Synthesis and characterization of gadolinium nanostructured materials with potential applications in magnetic resonance imaging, neutron-capture therapy and targeted drug delivery. J Nanopart Res 12:1285–129710.1007/s11051-010-9848-y ↗
8. Park HW, Chae JS, Park S-M, Kim K-B, Roh KC (2013) Nickel-based layered double hydroxide from guest vanadium oxide anions. Met Mater Int 19:887–89410.1007/s12540-013-4034-2 ↗
9. Schneiderová B, Demel J, Pleštil J, Tarábková H, Bohuslav J, Lang K (2014) Electrochemical performance of cobalt hydroxide nanosheets formed by the delamination of layered cobalt hydroxide in water. Dalton Trans 43:10484–1049110.1039/c4dt00141a ↗
10. Zhu J, Chen S, Zhou H, Wang X (2012) Fabrication of a low defect density graphene-nickel hydroxide nanosheet hybrid with enhanced electrochemical performance. Nano Research 5:11–1910.1007/s12274-011-0179-9 ↗
11. Chen W, Yang Y, Shao H, Fan J (2008) Tunable electrochemical properties brought about by partial cation exchange in hydrotalcite-like Ni-Co/Co-Ni hydroxide nanosheets. The Journal of Physical Chemistry C 112:17471–1747710.1021/jp804776j ↗
12. Han J, Dou Y, Zhao J, Wei M, Evans DG, Duan X (2013) Flexible CoAl LDH@PEDOT core/shell nanoplatelet array for high-performance energy storage. Small 9:98–10610.1002/smll.201201336 ↗
13. Gao Z, Wang J, Li Z, Yang W, Wang B, Hou M, He Y, Liu Q, Mann T, Yang P, Zhang M, Liu L (2011) Graphene nanosheet/Ni2+/Al3+ layered double-hydroxide composite as a novel electrode for a supercapacitor. Chem Mater 23:3509–351610.1021/cm200975x ↗
14. Yuan Y, Bi H, He G, Zhu J, Chen H (2014) A facile hydrothermal synthesis of a MnCo2O4@reduced graphene oxide nanocomposite for application in supercapacitors. Chem Lett 43:83–8510.1246/cl.130815 ↗
15. Li L, Zhang YQ, Liu XY, Shi SJ, Zhao XY, Zhang H, Ge X, Cai GF, Gu CD, Wang XL, Tu JP (2014) One-dimension MnCo2O4 nanowire arrays for electrochemical energy storage. Electrochim Acta 116:467–47410.1016/j.electacta.2013.11.081 ↗
16. Zhao J, Chen J, Xu S, Shao M, Yan D, Wei M, Evans DG, Duan X (2013) CoMn-layered double hydroxide nanowalls supported on carbon fibers for high-performance flexible energy storage devices. J Mater Chem A 1:8836–884310.1039/c3ta11452j ↗
17. He Y, Chen W, Gao C, Zhou J, Li X, Xie E (2013) An overview of carbon materials for flexible electrochemical capacitors. Nanoscale 5:8799–882010.1039/c3nr02157b ↗
18. Yu M, Zeng Y, Zhang C, Lu X, Zeng C, Yao C, Yang Y, Tong Y (2013) Titanium dioxide@polypyrrole core-shell nanowires for all solid-state flexible supercapacitors. Nanoscale 5:10806–1081010.1039/c3nr03578f ↗
19. Zheng H, Zhai T, Yu M, Xie S, Liang C, Zhao W, Wang SCI, Zhang Z, Lu X (2013) TiO2@C core–shell nanowires for high-performance and flexible solid-state supercapacitors. J Mater Chem C 1:225–22910.1039/C2TC00047D ↗
20. Liu X, Ma R, Bando Y, Sasaki T (2012) A general strategy to layered transition-metal hydroxide nanocones: tuning the composition for high electrochemical performance. Adv Mater 24:2148–215310.1002/adma.201104753 ↗
21. Zhai C, Du N, Yang HZD (2011) Large-scale synthesis of ultrathin hexagonal tin disulfide nanosheets with highly reversible lithium storage. Chem Commun 47:1270–127210.1039/C0CC03023F ↗
22. Zhao T, Jiang H, Ma J (2011) Surfactant-assisted electrochemical deposition of α-cobalt hydroxide for supercapacitors. J Power Sources 196:860–86410.1016/j.jpowsour.2010.06.042 ↗
23. Cheng S, Yang L, Liu Y, Lin W, Huang L, Chen D, Wong CP, Liu M (2013) Carbon fiber paper supported hybrid nanonet/nanoflower nickel oxide electrodes for high-performance pseudo-capacitors. J Mater Chem A 1:770910.1039/c3ta10560a ↗
24. Song F, Hu X (2014) Ultrathin cobalt-manganese layered double hydroxide is an efficient oxygen evolution catalyst. J Am Chem Soc 136:16481–1648410.1021/ja5096733 ↗
25. Burda C, Chen XB, Narayanan R, El-Sayed MA (2005) Chemistry and properties of nanocrystals of different shapes. Chem Rev 105:1025–110210.1021/cr030063a ↗
26. Deng F, Yu L, Sun M, Lin T, Cheng G, Lan B, Ye F (2014) Controllable growth of hierarchical NiCo2O4 Nanowires and nanosheets on carbon fiber paper and their morphology-dependent pseudocapacitive performances. Electrochim Acta 133:382–39010.1016/j.electacta.2014.04.070 ↗
27. Cong H-P, Yu S-H (2008) Shape control of cobalt carbonate particles by a hydrothermal process in a mixed solvent: an efficient precursor to nanoporous cobalt oxide architectures and their sensing property. Cryst Growth Des 9:210–21710.1021/cg8003068 ↗
28. Yu L, Zhang L, Wu HB, Zhang G, Lou XW (2013) Controlled synthesis of hierarchical CoxMn3-xO4 array micro-/nanostructures with tunable morphology and composition as integrated electrodes for lithium-ion batteries. Energy Environ Sci 6:2664–267110.1039/C3EE41181H ↗
29. Wu J, Lü X, Zhang L, Huang F, Xu F (2009) Dielectric constant controlled solvothermal synthesis of a TiO2 photocatalyst with tunable crystallinity: a strategy for solvent selection. Eur J Inorg Chem 2009:2789–279510.1002/ejic.200900199 ↗
30. Zhou W-J, Zhang J, Xue T, Zhao D-D, Li H-L (2008) Electrodeposition of ordered mesoporous cobalt hydroxide film from lyotropic liquid crystal media for electrochemical capacitors. J Mater Chem 18:905–91010.1039/b715070a ↗
31. Li J, Xiong S, Li X, Qian Y (2013) A facile route to synthesize multiporous MnCo2O4 and CoMn2O4 spinel quasi-hollow spheres with improved lithium storage properties. Nanoscale 5:2045–205410.1039/c2nr33576j ↗
32. Zhang H, Chen Y, Wang W, Zhang G, Zhuo M, Zhang H, Yang T, Li Q, Wang T (2013) Hierarchical Mo-decorated Co3O4 nanowire arrays on Ni foam substrates for advanced electrochemical capacitors. J Mater Chem A 1:859310.1039/c3ta11152k ↗
33. Guan C, Liu J, Cheng C, Li H, Li X, Zhou W, Zhang H, Fan HJ (2011) Hybrid structure of cobalt monoxide nanowire @ nickel hydroxidenitrate nanoflake aligned on nickel foam for high-rate supercapacitor. Energy Environ Sci 4:449610.1039/c1ee01685g ↗
34. Xia XH, Tu JP, Zhang YQ, Wang XL, Gu CD, Zhao XB, Fan HJ (2012) High-quality metal oxide core/shell nanowire arrays on conductive substrates for electrochemical energy storage. ACS Nano 6:5531–553810.1021/nn301454q ↗