Biomimetic synthesis of needle-like nano-hydroxyapatite templated by double-hydrophilic block copolymer
Source abstract
Abstract
Double-hydrophilic block copolymer (DHBC) poly-(vinylpyrrolidone)-b-poly(vinylpyrrolidone-alt-maleic anhydride)-b-poly-(vinylpyrrolidone) (PVP-b-P(NVP-alt-MAn)-b-PVP) was synthesised as the biomimetic template for the hydroxyapatite (HAP) nanocrystal synthesis. Needle-like HAP nanocrystals can be formed in the presence of PVP108-P(NVP-MAn)28-PVP108. Comparing to the HAP nanocrystals formed in the presence of poly-(vinylpyrrolidone) (PVP) homopolymer, the HAP nanocrystal formed with DHBC is more stable and never precipitate in water after preparation. The crystallization process and the morphology of the final nano-HAP crystal can be controlled by adjusting DHBC molecular structure.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Bone Tissue Engineering Materials · Orthopaedic implants and arthroplasty · biodegradable polymer synthesis and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (20)
Show source-provided references
1. Cai YR, Tang RK (2008) J Mater Chem 18:377510.1039/b805407j ↗
2. Vallet-Regi M, Gonza′lez-Calbet JM (2004) Prog Solid State Chem 32:110.1016/j.progsolidstchem.2004.07.001 ↗
3. Chen H, Chen Y, Orr BG, Banaszak-Holl M, Majoros I, Clarkson BH (2004) Langmuir 20:416810.1021/la0303005 ↗
4. Sergey V, Dorozhkin SV (2007) J Mater Sci 42:1061. doi: 10.1007/s10853-006-1467-810.1007/s10853-006-1467-8 ↗
5. Boduch-Lee KA, Chapman T, Petricca SE, Marra KG, Kumta P (2004) Macromolecules 37:895910.1021/ma0493630 ↗
6. Kaneko T, Ogomi D, Mitsugi R, Serizawa T, Akashi M (2004) Chem Mater 16:559610.1021/cm0490975 ↗
7. Malkaj P, Pierri E, Dalas E (2005) J Mater Sci Mater Med 16:73310.1007/s10856-005-2610-9 ↗
8. Song J, Saiz E, Bertozzi CR (2003) J Am Chem Soc 125:123610.1021/ja028559h ↗
9. Song J, Malathong V, Bertozzi CR (2005) J Am Chem Soc 127:336610.1021/ja043776z ↗
10. Zhang W, Liao SS, Cui FZ (2003) Chem Mater 15:322110.1021/cm030080g ↗
11. Pan HH, Tao JH, Xu XR, Tang RK (2007) Langmuir 23:897210.1021/la700567r ↗
12. Zhang YJ, Lu J (2008) J Cryst Growth Des 8:210110.1021/cg060880e ↗
13. Colfen H (2001) Macromol Rapid Commun 22:21910.1002/1521-3927(20010201)22:4<219::AID-MARC219>3.0.CO;2-G ↗
14. Sedlak M, Antonietti M, Colfen H (1998) Macromol Chem Phys 199:24710.1002/(SICI)1521-3935(19980201)199:2<247::AID-MACP247>3.0.CO;2-9 ↗
15. Tjandra W, Yao J, Ravi P, Kam C, Tam KC, Alamsjah A (2005) Chem Mater 17:486510.1021/cm050679b ↗
16. Colfen H, Antonietti M (1998) Langmuir 14:58210.1021/la970765t ↗
17. Qi L, Colfen H, Antonietti M (2000) Angew Chem Int Ed 39:60410.1002/(SICI)1521-3773(20000204)39:3<604::AID-ANIE604>3.0.CO;2-B ↗
18. Yu SH, Antonietti M, Colfen H, Giersig M (2002) Angew Chem Int Ed 41:235610.1002/1521-3773(20020703)41:13<2356::AID-ANIE2356>3.0.CO;2-U ↗
19. Yu SH, Antonietti M, Colfen H, Hartmann J (2003) Nano Lett 3:37910.1021/nl025722y ↗
20. Mayadunne RTA, Rizzardo E, Chiefari J (2000) Macromolecules 33:24310.1021/ma991451a ↗