Decoration of surface-carboxylated graphene oxide with luminescent Sm3+-complexes
Source abstract
Abstract
A Sm3+ complex, tris-(2-thenoyltrifluoroacetone) mono-1,10-phenanthroline-Sm3+ [Sm(TTA)3(Phen)], can be easily integrated in situ via covalent functionalization to surface-carboxylated graphene oxide (GO-COOH) from a ethanol solution. The Sm3+ containing material has been comprehensively characterized via Fourier transform infrared spectra, X-ray photoelectron spectroscopy, UV–Vis absorption spectra, luminescence spectra, transmission electron microscopy, powder X-ray diffraction, thermogravimetric analysis (TG and DTG). The integration of rare earth complexes (RE) onto GO-COOH, as well as the individual nature of the hybrids, is confirmed. The GO-COOH with high load capacity can integrate more RE than GO. The brilliant optical properties of the GO-COOH-RE complex hybrids make them promising candidates applying in many practical fields, such as biomedical applications.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Graphene and Nanomaterials Applications · Graphene research and applications · Carbon and Quantum Dots Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (38)
Show source-provided references
1. Fang Y, Gu D, Zou Y, Wu Z, Li F, Che R, Deng Y, Tu B, Zhao D (2010) A low-concentration hydrothermal synthesis of biocompatible ordered mesoporous carbon nanospheres with tunable and uniform size. Angew Chem Int Ed 49(43):7987–799110.1002/anie.201002849 ↗
2. Lai G, Yan F, Ju H (2009) Dual signal amplification of glucose oxidase-functionalized nanocomposites as a trace label for ultrasensitive simultaneous multiplexed electrochemical detection of tumor markers. Anal Chem 81(23):9730–973610.1021/ac901996a ↗
3. Yang S, Gao H, Wang Y, Xin S, He Y, Wang Y, Zeng W (2013) A simple way to synthesize well-dispersed Gd2O3 nanoparticles onto reduced graphene oxide sheets. Mater Res Bull 48(1):37–40. doi: 10.1016/j.materresbull.2012.09.06510.1016/j.materresbull.2012.09.065 ↗
4. Malhotra R, Papadimitrakopoulos F, Rusling JF (2010) Sequential layer analysis of protein immunosensors based on single wall carbon nanotube forests. Langmuir 26(18):15050–1505610.1021/la102306z ↗
5. Loh KP, Bao Q, Eda G, Chhowalla M (2010) Graphene oxide as a chemically tunable platform for optical applications. Nat Chem 2(12):1015–102410.1038/nchem.907 ↗
6. Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, Stankovich S, Jung I, Field DA, Ventrice CA, Ruoff RS (2009) Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and micro-Raman spectroscopy. Carbon 47(1):145–152. doi: 10.1016/j.carbon.2008.09.04510.1016/j.carbon.2008.09.045 ↗
7. Eda G, Lin YY, Mattevi C, Yamaguchi H, Chen HA, Chen IS, Chen CW, Chhowalla M (2010) Blue photoluminescence from chemically derived graphene oxide. Adv Mater 22(4):505–509. doi: 10.1002/adma.20090199610.1002/adma.200901996 ↗
8. Cai W, Piner RD, Stadermann FJ, Park S, Shaibat MA, Ishii Y, Yang D, Velamakanni A, An SJ, Stoller M (2008) Synthesis and solid-state NMR structural characterization of 13C-labeled graphite oxide. Science 321(5897):1815–181710.1126/science.1162369 ↗
9. Mkhoyan KA, Contryman AW, Silcox J, Stewart DA, Eda G, Mattevi C, Miller S, Chhowalla M (2009) Atomic and electronic structure of graphene-oxide. Nano Lett 9(3):1058–106310.1021/nl8034256 ↗
10. Sun X, Liu Z, Welsher K, Robinson JT, Goodwin A, Zaric S, Dai H (2008) Nano-graphene oxide for cellular imaging and drug delivery. Nano Res 1(3):203–212. doi: 10.1007/s12274-008-8021-810.1007/s12274-008-8021-8 ↗
11. Liu Z, Robinson JT, Sun X, Dai H (2008) PEGylated nanographene oxide for delivery of water-insoluble cancer drugs. J Am Chem Soc 130(33):10876–1087710.1021/ja803688x ↗
12. Du D, Wang L, Shao Y, Wang J, Engelhard MH, Lin Y (2011) Functionalized graphene oxide as a nanocarrier in a multienzyme labeling amplification strategy for ultrasensitive electrochemical immunoassay of phosphorylated p53 (S392). Anal Chem 83(3):746–752. doi: 10.1021/ac101715s10.1021/ac101715s ↗
13. Wei T, Luo G, Fan Z, Zheng C, Yan J, Yao C, Li W, Zhang C (2009) Preparation of graphene nanosheet/polymer composites using in situ reduction-extractive dispersion. Carbon 47(9):2296–229910.1016/j.carbon.2009.04.030 ↗
14. Luo Z, Vora PM, Mele EJ, Johnson A, Kikkawa JM (2009) Photoluminescence and band gap modulation in graphene oxide. Appl Phys Lett 94(11):111909–11191310.1063/1.3098358 ↗
15. Treossi E, Melucci M, Liscio A, Gazzano M, Samorì P, Palermo V (2009) High-contrast visualization of graphene oxide on dye-sensitized glass, quartz, and silicon by fluorescence quenching. J Am Chem Soc 131(43):15576–1557710.1021/ja9055382 ↗
16. Dong H, Gao W, Yan F, Ji H, Ju H (2010) Fluorescence resonance energy transfer between quantum dots and graphene oxide for sensing biomolecules. Anal Chem 82(13):5511–551710.1021/ac100852z ↗
17. Liu Z, Liu Q, Huang Y, Ma Y, Yin S, Zhang X, Sun W, Chen Y (2008) Organic photovoltaic devices based on a novel acceptor material: graphene. Adv Mater 20(20):3924–393010.1002/adma.200800366 ↗
18. Cao Y, Yang T, Feng J, Wu P (2011) Decoration of graphene oxide sheets with luminescent rare-earth complexes. Carbon 49(4):1502–1504. doi: 10.1016/j.carbon.2010.11.01410.1016/j.carbon.2010.11.014 ↗
19. Quici S, Cavazzini M, Marzanni G, Accorsi G, Armaroli N, Ventura B, Barigelletti F (2005) Visible and near-infrared intense luminescence from water-soluble lanthanide [Tb(III), Eu(III), Sm(III), Dy(III), Pr(III), Ho(III), Yb(III), Nd(III), Er(III)] complexes. Inorg Chem 44(3):529–53710.1021/ic0486466 ↗
20. Ishizaka T, Kurokawa Y, Makino T, Segawa Y (2001) Optical properties of rare earth ion (Nd3+Er3+ and Tb3+)-doped alumina films prepared by the sol–gel method. Opt Mater 15(4):293–29910.1016/S0925-3467(00)00045-8 ↗
21. Sabbatini N, Guardigli M, Lehn JM (1993) Coord Chem Rev 123:20110.1016/0010-8545(93)85056-A ↗
22. Jubera V, Chaminade J-P, Garcia A, Guillen F, Fouassier C (2003) Luminescent properties of Eu3+-activated lithium rare earth borates and oxyborates. J Lumin 101(1):1–1010.1016/S0022-2313(02)00335-6 ↗
23. Banks E, Okamoto Y, Ueba Y (2003) Synthesis and characterization of rare earth metal-containing polymers. I. Fluorescent properties of ionomers containing Dy3+, Er3+, Eu3+, and Sm3+. J Appl Polym Sci 25(3):359–36810.1002/app.1980.070250303 ↗
24. Yang Y, Su Q, Zhao G (2000) Photoacoustic study of the co-fluorescence effect of lanthanide ternary complexes in solid states. J Mol Struct 525(1):47–5210.1016/S0022-2860(99)00192-1 ↗
25. Wang S-J, Hu J-B, Wang Y-Y, Luo F (2012) Coating graphene oxide sheets with luminescent rare-earth complexes. J Mater Sci 48(2):805–811. doi: 10.1007/s10853-012-6799-y10.1007/s10853-012-6799-y ↗
26. Accorsi G, Armaroli N, Parisini A, Meneghetti M, Marega R, Prato M, Bonifazi D (2007) Wet adsorption of a luminescent Eu(III) complex on carbon nanotubes sidewalls. Adv Funct Mater 17(15):2975–2982. doi: 10.1002/adfm.20060069610.1002/adfm.200600696 ↗
27. Hu XW, Mao CJ, Song JM, Niu HL, Zhang SY, Huang HP (2013) Fabrication of GO/PANi/CdSe nanocomposites for sensitive electrochemiluminescence biosensor. Biosens Bioelectron 41:372–378. doi: 10.1016/j.bios.2012.08.05410.1016/j.bios.2012.08.054 ↗
28. Chang L, Chen S, Jin P, Li X (2012) Synthesis of multifunctional fluorescent magnetic graphene oxide hybrid materials. J Colloid Interface Sci 388(1):9–14. doi: 10.1016/j.jcis.2012.08.04310.1016/j.jcis.2012.08.043 ↗
29. Pei F, Liu Y, Zhang L, Wang S, Xu S, Cao S (2013) TiO2 nanocomposite with reduced graphene oxide through facile blending and its photocatalytic behaviour for hydrogen evolution. Mater Res Bull 48(8):2824–283110.1016/j.materresbull.2013.04.018 ↗
30. Liu L, Zhang W, Li X, Wu X-F, Yang C, Liu Y-D, He L, Lu Y-L, Xu R-W, Zhang X-J (2007) Preparation and luminescence properties of Sm(TTA)3Phen/NBR composites. Compos Sci Technol 67(10):2199–220710.1016/j.compscitech.2005.07.001 ↗
31. Zhang R-J, Liu H-G, Yang K-Z, Si Z-K, Zhu G-Y, Zhang H-W (1997) Fabrication and fluorescence characterization of the LB films of luminous rare earth complexes Eu(TTA)3Phen and Sm(TTA)3Phen. Thin Solid Films 295(1):228–23310.1016/S0040-6090(96)09273-5 ↗
32. Zhu J, Li Y, Chen Y, Wang J, Zhang B, Zhang J, Blau WJ (2011) Graphene oxide covalently functionalized with zinc phthalocyanine for broadband optical limiting. Carbon 49(6):1900–1905. doi: 10.1016/j.carbon.2011.01.01410.1016/j.carbon.2011.01.014 ↗
33. Chen Z, Wu Y, Huang F, Gu D, Gan F (2007) Synthesis, spectral, and thermal characterizations of Ni(II) and Cu(II) β-diketone complexes with thenoyltrifluoroacetone ligand. Spectrochim Acta A Mol Biomol Spectrosc 66(4):1024–102910.1016/j.saa.2006.05.015 ↗
34. Yang X, Zhang X, Liu Z, Ma Y, Huang Y, Chen Y (2008) High-efficiency loading and controlled release of doxorubicin hydrochloride on graphene oxide. J Phys Chem C 112(45):17554–1755810.1021/jp806751k ↗
35. Deng R, Yu J, Zhang H, Zhou L, Peng Z, Li Z, Guo Z (2007) Photoluminescence and electroluminescence properties of a samarium complex Sm(TTA)3Phen. Chem Phys Lett 443(4):258–26310.1016/j.cplett.2007.06.080 ↗
36. Liu J, Wang Y, Delai Sun D (2013) Enhanced performance of hybrid solar cells using carboxylic acid-functionalized graphene oxide supported TiO2 nanorod composites. Mater Lett 95:178–181. doi: 10.1016/j.matlet.2012.12.09210.1016/j.matlet.2012.12.092 ↗
37. Khenfouch M, Baïtoul M, Maaza M (2012) White photoluminescence from a grown ZnO nanorods/graphene hybrid nanostructure. Opt Mater 34(8):1320–1326. doi: 10.1016/j.optmat.2012.02.00510.1016/j.optmat.2012.02.005 ↗
38. Shen J, Li T, Shi M, Li N, Ye M (2012) Polyelectrolyte-assisted one-step hydrothermal synthesis of Ag-reduced graphene oxide composite and its antibacterial properties. Mater Sci Eng C 32(7):2042–2047. doi: 10.1016/j.msec.2012.05.01710.1016/j.msec.2012.05.017 ↗