journal article·2007-07

Strength and fracture toughness of nano and micron-silica particles bidispersed epoxy composites: evaluated by fragility parameter

Soon-Chul Kwon, Tadaharu Adachi

Journal of Materials Science· Volume 42· Issue 14
Publisher page

Abstract

In this study, we discuss the composition effect of 240 nm and 1.56 μm-silica particles on strength and fracture toughness by examining two parameters, fragility and glass transition temperature, that were derived from the thermo-viscoelasticity measurements. Experimental results showed that the composites had a lower fragility with higher strength and fracture toughness as the content of nanoparticles was increased regardless of glass transition temperature. The improvement in mechanical properties from adding nanoparticles was definitely explained by the fragility represented the heterogeneity in polymer matrix, and this was related to the interaction between particles and matrix. The fragility was found to be an effective parameter for evaluating strength and fracture toughness of epoxy composite containing a bidispersion of nano and micron-silica particles.
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Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Epoxy Resin Curing Processes · Polymer crystallization and properties

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References (28)

Show source-provided references
1. Kinloch AJ, Taylor AC (2003) J Mater Sci Lett 22:143910.1023/A:1025719715808 ↗
2. Kinloch AJ, Lee JH, Taylor AC, Sprenger S, Eger C, Egan D (2003) J Adhesion 79:86710.1080/00218460309551 ↗
3. Huang KS, Nien YH, Chen JS, Shieh TR, Chen JW (2006) Polym Compos 27:19510.1002/pc.20173 ↗
4. Rong MZ, Zhang MQ, Pan SL, Lehmann B, Friedrich K (2004) Polym Int 53:17610.1002/pi.1307 ↗
5. Brechet Y, Cavaille J-YY, Chabert E, Chazeau L, Dendievel R, Flandin L, Gauthier C (2001) Adv Eng Mater 3:57110.1002/1527-2648(200108)3:8<571::AID-ADEM571>3.0.CO;2-M ↗
6. Kovacevic V, Lucic S, Leskovac M (2002) J Adhesion Sci 16:134310.1163/156856102320252840 ↗
7. Park JH, Jana SC (2003) Polymer 44:209110.1016/S0032-3861(03)00075-2 ↗
8. Nikkeshi S, Kudo M, Masuko T (1998) J Appl Polym Sci 69:259310.1002/(SICI)1097-4628(19980926)69:13<2593::AID-APP9>3.0.CO;2-5 ↗
9. Miyagawa H, Rich MJ, Drzal LT (2005) Polym Compos 26:4210.1002/pc.20071 ↗
10. Wu WL, Hu JT, Hunston DL (1990) Polym Eng Sci 30:83510.1002/pen.760301406 ↗
11. Araki W, Adachi T, Yamaji A (2006) Recent Res Dev Appl Polym Sci 3:205
12. Angell CA (1988) J Phys Chem Solid 49:86310.1016/0022-3697(88)90002-9 ↗
13. Matsuoka S, Quan X, Bair HE, Boyle DJ (1989) Macromolecules 22:409310.1021/ma00200a048 ↗
14. Racich JL, Koutsky JA (1976) J Appl Polym Sci 20:211110.1002/app.1976.070200808 ↗
15. Si P, Bian X, Zhang J, Li H, Sun M, Zhao Y (2003) J Phys Condens Matter 15:540910.1088/0953-8984/15/32/302 ↗
16. Böhmer R, Ngai KL, Angell CA, Plazek DJ (1993) J Chem Phys 99:420110.1063/1.466117 ↗
17. Kanaya T, Kawaguchi T, Kaji K (1996) J Chem Phys 104:384110.1063/1.471037 ↗
18. Kanaya T, Tsukushi I, Kaji K (1997) Prog Theoret Phys Suppl 126:13310.1143/PTPS.126.133 ↗
19. Adachi T, Araki W, Nakahara T, Yamaji A, Gamou M (2002) J Appl Polym Sci 86:226110.1002/app.11206 ↗
20. Nielsen LE, Landel RF (1994) Mechanical properties of polymers and composites. Marcel Dekker, New York, p 131
21. Kwon S-C, Adachi T, Araki W, Yamaji A (2006) Acta Mater 54:336910.1016/j.actamat.2006.03.026 ↗
22. Araki W, Adachi T, Yamaji A, Gamou M (2002) J Appl Polym Sci 86:226610.1002/app.11208 ↗
23. Araki W, Adachi T, Yamaji A (2003) JSME Int J 46:16310.1299/jsmea.46.163 ↗
24. Plazek DJ, Choy IC (1989) J Polym Sci Pt 27:30710.1002/polb.1989.090270207 ↗
25. Plazek DJ, Choy IC, Kelley FN, Meerwall E, Suş LJ (1982) Rubber Chem Tech 56:86610.5254/1.3538161 ↗
26. Schwarzl F, Staverman AJ (1952) J Appl Phys 23:83810.1063/1.1702316 ↗
27. Benthem JP, Koiter WT (1975) In: Mechanical fracture, vol. 1 Methods of analysis and solutions of crack problems. Noordhoff International Publishing, Leyden
28. Kwon S-C, Adachi T, Araki W, Yamaji A (2005) Key Eng Mat 297–300:20710.4028/www.scientific.net/KEM.297-300.207 ↗