Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries
Source abstract
Abstract
In this work, a novel composite of Co3O4 nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co3O4 particles are homogenously embedded in the CNOs. Due to the unique nano-structure, the electrolyte contacts well with the active materials, leading to a better transfer of lithium ions. Moreover, the unique nano-structure not only buffers the volume changes but also facilitates the shuttling of electrons during the cycling process. As a result, the electrode made up of Co3O4/CNOs composite delivers favorable cycling performance (676 mAh g−1 after 200 cycles) and rate capability (557 mAh g−1 at the current of 1 C), showing a promising prospect for lithium-ion batteries as anode materials.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies
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References (65)
Show source-provided references
1. Cheng X-B, Zhang Q, Wang H-F, Tian G-L, Huang J-Q, Peng H-J, Zhao M-Q, Wei F (2015) Nitrogen-doped herringbone carbon nanofibers with large lattice spacings and abundant edges: catalytic growth and their applications in lithium ion batteries and oxygen reduction reactions. Catal Today 249:244–25110.1016/j.cattod.2014.10.047 ↗
2. Liu X, Wu Y, Yang Z, Pan F, Zhong X, Wang J, Gu L, Yu Y (2015) Nitrogen-doped 3D macroporous graphene frameworks as anode for high performance lithium-ion batteries. J Power Sources 293:799–80510.1016/j.jpowsour.2015.05.074 ↗
3. Li Y, Lv X, Lu J, Li J (2010) Preparation of SnO2-nanocrystal/graphene-nanosheets composites and their lithium storage ability. J Phys Chem C 114(49):21770–2177410.1021/jp1050047 ↗
4. Wu Y-P, Rahm E, Holze R (2003) Carbon anode materials for lithium ion batteries. J Power Sources 114(2):228–23610.1016/S0378-7753(02)00596-7 ↗
5. Park MS, Wang GX, Kang YM, Wexler D, Dou SX, Liu HK (2007) Preparation and electrochemical properties of SnO2 nanowires for application in lithium-ion batteries. Angew Chem 119(5):764–76710.1002/ange.200603309 ↗
6. Gao S, Yang S, Shu J, Zhang S, Li Z, Jiang K (2008) Green fabrication of hierarchical CuO hollow micro/nanostructures and enhanced performance as electrode materials for lithium-ion batteries. J Phys Chem C 112(49):19324–1932810.1021/jp808545r ↗
7. Cui Z-M, Jiang L-Y, Song W-G, Guo Y-G (2009) High-yield gas–liquid interfacial synthesis of highly dispersed Fe3O4 nanocrystals and their application in lithium-ion batteries. Chem Mater 21(6):1162–116610.1021/cm8033609 ↗
8. Li D, Yang D, Zhu X, Jing D, Xia Y, Ji Q, Cai R, Li H, Che Y (2014) Simple pyrolysis of cobalt alginate fibres into Co3O4/C nano/microstructures for a high-performance lithium ion battery anode. J Mater Chem A 2(44):18761–1876610.1039/C4TA03052D ↗
9. Gou J, Xie S, Liu Y, Liu C (2016) Flower-like nickel-cobalt hydroxides converted from phosphites for high rate performance hybrid supercapacitor electrode materials. Electrochim Acta 210:915–92410.1016/j.electacta.2016.05.213 ↗
10. Yan D, Zhang H, Chen L, Zhu G, Li S, Xu H, Yu A (2014) Biomorphic synthesis of mesoporous Co3O4 microtubules and their pseudocapacitive performance. ACS Appl Mater Interfaces 6(18):15632–1563710.1021/am5044449 ↗
11. Xiao Y, Liu S, Feng L, Zhang A, Zhao J, Fang S, Jia D (2012) 3D Hierarchical Co3O4 twin-spheres with an urchin-like structure: large-scale synthesis, multistep-splitting growth, and electrochemical pseudocapacitors. Adv Funct Mater 22(19):4052–405910.1002/adfm.201200519 ↗
12. Numan A, Shahid MM, Omar FS, Ramesh K, Ramesh S (2017) Facile fabrication of cobalt oxide nanograin-decorated reduced graphene oxide composite as ultrasensitive platform for dopamine detection. Sensors Actuators B Chem 238:1043–105110.1016/j.snb.2016.07.111 ↗
13. Sun GL, Ma LY, Ran JB, Shen XY, Tong H (2016) Incorporation of homogeneous Co3O4 into a nitrogen-doped carbon aerogel via a facile in situ synthesis method: implications for high performance asymmetric supercapacitors. J Mater Chem A 4(24):9542–955410.1039/C6TA03884K ↗
14. Hsieh C-T, Lin J-S, Chen Y-F, Teng H (2012) Pulse microwave deposition of cobalt oxide nanoparticles on graphene nanosheets as anode materials for lithium ion batteries. J Phys Chem C 116(29):15251–1525810.1021/jp3041499 ↗
15. Zhang MM, Li R, Chang XX, Xue C, Gou XL (2015) Hybrid of porous cobalt oxide nanospheres and nitrogen-doped graphene for applications in lithium-ion batteries and oxygen reduction reaction. J Power Sources 290:25–3410.1016/j.jpowsour.2015.04.178 ↗
16. Zhou XY, Shi JJ, Liu Y, Su QM, Zhang J, Du GH (2014) Microwave irradiation synthesis of Co3O4 quantum dots/graphene composite as anode materials for Li-ion battery. Electrochim Acta 143:175–17910.1016/j.electacta.2014.08.023 ↗
17. Won JM, Cho JS, Kang YC (2016) Superior electrochemical properties of SiO2-doped Co3O4 hollow nanospheres obtained through nanoscale Kirkendall diffusion for lithium-ion batteries. J Alloy Compd 680:366–37210.1016/j.jallcom.2016.04.104 ↗
18. Zhang YP, Zhuo QQ, Lv XX, Ma YY, Zhong J, Sun XH (2015) NiO-Co3O4 nanoplate composite as efficient anode in Li-ion battery. Electrochim Acta 178:590–59610.1016/j.electacta.2015.08.044 ↗
19. Wu BB, Zhang SL, Yao F, Huo RJ, Zhang FZ, Xu SL (2016) Nitrogen-doped carbon and high-content alumina containing bi-active cobalt oxides for efficient storage of lithium. J Colloid Interf Sci 462:183–19010.1016/j.jcis.2015.09.069 ↗
20. Wenelska K, Neef C, Schlestein L, Klingeler R, Kalenczuk RJ, Mijowska E (2015) Carbon nanotubes decorated by mesoporous cobalt oxide as electrode material for lithium-ion batteries. Chem Phys Lett 635:185–18910.1016/j.cplett.2015.06.072 ↗
21. Wang G, Meng Y, Wang L, Xia J, Zhu F, Zhang Y (2017) Yolk-shell Co3O4–CoO/carbon composites for lithium-ion batteries with enhanced electrochemical properties. Int J Electrochem Sci 12:2618–262710.20964/2017.04.73 ↗
22. Zhang DH, Zou WB (2013) Decorating reduced graphene oxide with Co3O4 hollow spheres and their application in supercapacitor materials. Curr Appl Phys 13(8):1796–180010.1016/j.cap.2013.07.001 ↗
23. Xu YN, Wang XF, An CH, Wang YJ, Jiao LF, Yuan HT (2014) Synthesis of cobalt oxide-reduced graphene nanocomposite and its enhanced electrochemical properties as negative material for alkaline secondary battery. J Power Sources 272:328–33410.1016/j.jpowsour.2014.08.099 ↗
24. Yao WL, Yang J, Wang JL, Tao LA (2008) Synthesis and electrochemical performance of carbon nanofiber-cobalt oxide composites. Electrochim Acta 53(24):7326–733010.1016/j.electacta.2008.04.010 ↗
25. Yao WL, Wang JL, Yang J, Du GD (2008) Novel carbon nanofiber-cobalt oxide composites for lithium storage with large capacity and high reversibility. J Power Sources 176(1):369–37210.1016/j.jpowsour.2007.10.073 ↗
26. Zhan L, Wang YL, Qiao WM, Ling LC, Yang SB (2012) Hollow carbon spheres with encapsulation of Co3O4 nanoparticles as anode material for lithium ion batteries. Electrochim Acta 78:440–44510.1016/j.electacta.2012.06.017 ↗
27. Wu JF, Zuo L, Song YH, Chen YQ, Zhou RH, Chen SH, Wang L (2016) Preparation of biomass-derived hierarchically porous carbon/Co3O4 nanocomposites as anode materials for lithium-ion batteries. J Alloy Compd 656:745–75210.1016/j.jallcom.2015.10.063 ↗
28. Abouelsayed A, Anis B, Hassaballa S, Khalil ASG, Rashed UM, Eid KA, Al-Ashkar E, El hotaby W (2017) Preparation, characterization, Raman, and terahertz spectroscopy study on carbon nanotubes, graphene nano-sheets, and onion like carbon materials. Mater Chem Phys 189:127–13510.1016/j.matchemphys.2016.12.065 ↗
29. Zhu C, Xu F, Chen J, Min H, Dong H, Tong L, Qasim K, Li S, Sun L (2016) Nitrogen-doped carbon onions encapsulating metal alloys as efficient and stable catalysts for dye-sensitized solar cells. J Power Sources 303:159–16710.1016/j.jpowsour.2015.10.111 ↗
30. Asokan V, Nørgaard Madsen D, Kosinski P, Myrseth V (2015) Transformation of carbon black into carbon nano-beads and nanotubes: the effect of catalysts. New Carbon Mater 30(1):19–2910.1016/S1872-5805(15)60172-X ↗
31. Meng Y, Xia J, Zhu F, Zhang Y (2016) Synthesis of N-doped carbon by microwave-assisted pyrolysis ionic liquid for lithium-ion batteries. Int J Electrochem Sci 11:9881–989010.20964/2016.12.08 ↗
32. Wang X, Dai S (2010) Ionic liquids as versatile precursors for functionalized porous carbon and carbon–oxide composite materials by confined carbonization. Angew Chem Int Ed 49(37):6664–666810.1002/anie.201003163 ↗
33. Lee JS, Wang X, Luo H, Baker GA, Dai S (2009) Facile ionothermal synthesis of microporous and mesoporous carbons from task specific ionic liquids. J Am Chem Soc 131(13):4596–459710.1021/ja900686d ↗
34. Zhi L, Hu YS, Hamaoui BE, Wang X, Lieberwirth I, Kolb U, Maier J, Müllen K (2008) Precursor-controlled formation of novel carbon/metal and carbon/metal oxide nanocomposites. Adv Mater 20(9):1727–173110.1002/adma.200702654 ↗
35. Fulvio PF, Lee JS, Mayes RT, Wang X, Mahurin SM, Dai S (2011) Boron and nitrogen-rich carbons from ionic liquid precursors with tailorable surface properties. Phys Chem Chem Phys 13(30):13486–1349110.1039/c1cp20631a ↗
36. Lou YB, Liang J, Peng YL, Chen JX (2015) Ultra-small Co3O4 nanoparticles-reduced graphene oxide nanocomposite as superior anodes for lithium-ion batteries. Phys Chem Chem Phys 17(14):8885–889310.1039/C4CP06077F ↗
37. Rahman MM, Wang J-Z, Deng X-L, Li Y, Liu H-K (2009) Hydrothermal synthesis of nanostructured Co3O4 materials under pulsed magnetic field and with an aging technique, and their electrochemical performance as anode for lithium-ion battery. Electrochim Acta 55(2):504–51010.1016/j.electacta.2009.08.068 ↗
38. Huang H, Gao S, Wu A-M, Cheng K, Li X-N, Gao X-X, Zhao J-J, Dong X-L, Cao G-Z (2017) Fe3N constrained inside C nanocages as an anode for Li-ion batteries through post-synthesis nitridation. Nano Energy 31:74–8310.1016/j.nanoen.2016.10.059 ↗
39. Zhang J, Zhang L, Yang S, Li D, Xie Z, Wang B, Xia Y, Quan F (2017) Facile strategy to produce N-doped carbon aerogels derived from seaweed for lithium-ion battery anode. J Alloy Compd 701:256–26110.1016/j.jallcom.2017.01.082 ↗
40. Wang Q, Wu MY, Meng SJ, Zang XX, Dai ZY, Si WL, Huang W, Dong XC (2016) Hydrazine sensor based on Co3O4/rGO/carbon cloth electrochemical electrode. Adv Mater Interfaces 3(12). doi: 10.1002/admi.20150069110.1002/admi.201500691 ↗
41. Wang B, Lu X-Y, Tang Y, Ben W (2016) General polyethyleneimine-mediated synthesis of ultrathin hexagonal Co3O4 nanosheets with reactive facets for lithium-ion batteries. ChemElectroChem 3(1):55–6510.1002/celc.201500377 ↗
42. Zhang G, Lu WT, Cao FF, Xiao ZD, Zheng XS (2016) N-doped graphene coupled with Co nanoparticles as an efficient electrocatalyst for oxygen reduction in alkaline media. J Power Sources 302:114–12510.1016/j.jpowsour.2015.10.055 ↗
43. Qu GL, Geng HB, Ge DH, Zheng JW, Gu HW (2016) Graphene-coated mesoporous Co3O4 fibers as an efficient anode material for Li-ion batteries. RSC Adv 6(75):71006–7101110.1039/C6RA15404B ↗
44. Li R, Wei Z, Gou X, Xu W (2013) Phosphorus-doped graphene nanosheets as efficient metal-free oxygen reduction electrocatalysts. RSC Adv 3(25):9978–998410.1039/c3ra41079j ↗
45. Reddy ALM, Srivastava A, Gowda SR, Gullapalli H, Dubey M, Ajayan PM (2010) Synthesis of nitrogen-doped graphene films for lithium battery application. ACS Nano 4:6337–634210.1021/nn101926g ↗
46. Li D, Shi D, Chen Z, Liu H, Jia D, Guo Z (2013) Enhanced rate performance of cobalt oxide/nitrogen doped graphene composite for lithium ion batteries. RSC Adv 3(15):5003–500810.1039/c3ra22765k ↗
47. Li Y, Zhao Y, Cheng H, Hu Y, Shi G, Dai L, Qu L (2012) Nitrogen-doped graphene quantum dots with oxygen-rich functional groups. J Am Chem Soc 134(1):15–1810.1021/ja206030c ↗
48. Lin Z, Waller G, Liu Y, Liu M, Wong C-P (2012) Facile synthesis of nitrogen-doped graphene via pyrolysis of graphene oxide and urea, and its electrocatalytic activity toward the oxygen-reduction reaction. Adv Energy Mater 2(7):884–88810.1002/aenm.201200038 ↗
49. Wang X, Li X, Zhang L, Yoon Y, Weber PK, Wang H, Guo J, Dai H (2009) N-doping of graphene through electrothermal reactions with ammonia. Science 324(5928):768–77110.1126/science.1170335 ↗
50. Bulusheva LG, Okotrub AV, Kurenya AG, Zhang H, Zhang H, Chen X, Song H (2011) Electrochemical properties of nitrogen-doped carbon nanotube anode in Li-ion batteries. Carbon 49(12):4013–402310.1016/j.carbon.2011.05.043 ↗
51. Wang R, Liu P, Lang J, Zhang L, Yan X (2017) Coupling effect between ultra-small Mn3O4 nanoparticles and porous carbon microrods for hybrid supercapacitors. Energy Storage Mater 6:53–6010.1016/j.ensm.2016.10.002 ↗
52. Guo L, Ding Y, Qin C, Li W, Du J, Fu Z, Song W, Wang F (2016) Nitrogen-doped porous carbon spheres anchored with Co3O4 nanoparticles as high-performance anode materials for lithium-ion batteries. Electrochim Acta 187:234–24210.1016/j.electacta.2015.11.065 ↗
53. Wu FF, Ma XJ, Feng JK, Qian YT, Xiong SL (2014) 3D Co3O4 and CoO@C wall arrays: morphology control, formation mechanism, and lithium-storage properties. J Mater Chem A 2(30):11597–1160510.1039/C4TA01676A ↗
54. Hu R, Zhang H, Bu Y, Zhang H, Zhao B, Yang C (2017) Porous Co3O4 nanofibers surface-modified by reduced graphene oxide as a durable, high-rate anode for lithium ion battery. Electrochim Acta 228:241–25010.1016/j.electacta.2017.01.067 ↗
55. Yin D, Huang G, Sun Q, Li Q, Wang X, Yuan D, Wang C, Wang L (2016) RGO/Co3O4 composites prepared using GO-MOFs as precursor for advanced lithium-ion batteries and supercapacitors electrodes. Electrochim Acta 215:410–41910.1016/j.electacta.2016.08.110 ↗
56. Cabana J, Monconduit L, Larcher D, Palacin MR (2010) Beyond intercalation-based Li-ion batteries: the state of the art and challenges of electrode materials reacting through conversion reactions. Adv Mater 22(35):E170–E19210.1002/adma.201000717 ↗
57. Xing X, Liu RL, Liu SQ, Xiao S, Xu Y, Wang C, Wu DQ (2016) Surfactant-assisted hydrothermal synthesis of cobalt oxide/nitrogen-doped graphene framework for enhanced anodic performance in lithium ion batteries. Electrochim Acta 194:310–31610.1016/j.electacta.2016.02.096 ↗
58. Chae B-M, Oh E-S, Lee Y-K (2015) Conversion mechanisms of cobalt oxide anode for Li-ion battery: in situ X-ray absorption fine structure studies. J Power Sources 274:748–75410.1016/j.jpowsour.2014.10.108 ↗
59. Luo L, Wu J, Xu J, Dravid VP (2014) Atomic resolution study of reversible conversion reaction in metal oxide electrodes for lithium-ion battery. ACS Nano 8(11):11560–1156610.1021/nn504806h ↗
60. Zhu WJ, Huang H, Gan YP, Tao XY, Xia Y, Zhang WK (2014) Mesoporous cobalt monoxide nanorods grown on reduced graphene oxide nanosheets with high lithium storage performance. Electrochim Acta 138:376–38210.1016/j.electacta.2014.06.104 ↗
61. Fang H, Zhang S, Liu W, Du Z, Wu X, Xing Y (2013) Hierarchical Co3O4@multiwalled carbon nanotube nanocable films with superior cyclability and high lithium storage capacity. Electrochim Acta 108:651–65910.1016/j.electacta.2013.07.021 ↗
62. Liang Y, Li Y, Wang H, Zhou J, Wang J, Regier T, Dai H (2011) Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. Nat Mater 10(10):780–78610.1038/nmat3087 ↗
63. Wang G, Shen X, Yao J, Park J (2009) Graphene nanosheets for enhanced lithium storage in lithium ion batteries. Carbon 47(8):2049–205310.1016/j.carbon.2009.03.053 ↗
64. Laruelle S, Grugeon S, Poizot P, Dollé M, Dupont L, Tarascon JM (2002) On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential. J Electrochem Soc 149(5):A627–A63410.1149/1.1467947 ↗
65. Peng C, Chen B, Qin Y, Yang S, Li C, Zuo Y, Liu S, Yang J (2012) Facile ultrasonic synthesis of CoO quantum dot/graphene nanosheet composites with high lithium storage capacity. ACS Nano 6(2):1074–108110.1021/nn202888d ↗