journal article·2003-08

Aggregation kinetics of sol-gel process based on titanium tetraisopropoxide

A. Soloviev, H. Jensen, E. G. Søgaard, A. V. Kanaev

Journal of Materials Science· Volume 38· Issue 15
Publisher page

Abstract

The kinetics of hydrolysis and condensation of titanium tetraisopropoxide (TTIP) under neutral conditions has been investigated by a light scattering method for different TTIP and water concentrations. The evaluation of kinetics data confirmed the complex nature of the process, which includes hydrolysis, condensation and aggregation of primary particles. Instead of commonly used inverse value of induction time, the rate of an individual particle mass growth for the adequate description of kinetics during induction period was used. Taking into account the initial water consumption allowed a unified description of kinetic data in different ranges of reagent concentrations to be obtained.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Thermal and Kinetic Analysis · Minerals Flotation and Separation Techniques · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

Show source-provided references
1. 1._ PH. Colomban, Ceram. Inter. 15 (1989) 23.10.1016/0272-8842(89)90005-9 ↗
2. T. Gerfin, M. GrÄtzel and L. Walder, Prog. Inorg. Chem. 44 (1997) 345.
3. S. Yoda, D. J. Suh and T. Sato, J. Sol-Gel Sci. and Tech. 22 (2001) 75.10.1023/A:1011216404208 ↗
4. C. J. Brinker and G. W. Scherer, “Sol-gel Science, the Physics and Chemistry of Sol-Gel Processing” (Academic Press, San Diego, 1990).
5. E. A. Barringer and H. K. Bowen, Langmuir 1 (1985) 414.10.1021/la00064a005 ↗
6. J. H. Jean and T. A. Ring, iÖid. 2 (1986) 251.10.1021/la00068a025 ↗
7. R. W. Hartel and K. A. Berlung, Mater. Res. Soc. Symp. Proc. 73 (1986) 633.10.1557/PROC-73-633 ↗
8. M. T. Harris and C. H. Byers, J. Non-Cryst. Solids 103 (1988) 49.10.1016/0022-3093(88)90415-2 ↗
9. N. V. Golubko, N. I. Yanovskaya, I. P. Romm and A. N. Ozerin, J. Sol-Gel Sci. and Tech. 20 (2001) 245.10.1023/A:1008769918083 ↗
10. V. K. Lamer and R. H. Dinegar, J. Amer. Chem. Soc. 72 (1950) 418.10.1021/ja01167a001 ↗
11. K. A. Berlung, D. R. Tallant and R.G. Dosch, in “Science of Ceramic Processing,” edited Öy D. R. Ulman and D. R. Ulrich (Wiley, New York, 1991) p. 95.
12. F. Babonneau, S. Doeuff, A. Leaustic, C. Sanchez, C. Cartier and M. Verdaguer, Inorg. Chem. 27 (1988) 3166.10.1021/ic00291a024 ↗
13. T. J. Baslow, M. E. Smith and H. J. Whitfield, J. Mater. Chem. 2 (1989) 989.
14. S. Monticone, A. Soloviev, R. Tufeu and A. V. Kanaev, AIDIC 4 (1999) 77.
15. A. Soloviev, D. Ivanov, R. Tufeu and A. V. Kanaev, J. Mater. Sci. Lett. 20 (2001) 905.10.1023/A:1010972615248 ↗
16. A. Soloviev, R. Tufue, C. Sanchez and A. V. Kanaev, J. Phys. Chem. B 105 (2001) 4175.10.1021/jp0040190 ↗
17. A. Soloviev, PhD thesis, UniversitéParis Nord, SeptemÖer 2000.
18. Michael Z.-C.-Hu, J. T. Zielke, C. H. Byers, J.-S. Lin and M. T. Harris, J. Mater. Sci. 35 (2000) 1957.10.1023/A:1004722603945 ↗
19. I. K. Yudin, G. L. Nilolaenko, V. I. Kosov, V. A. Agayan, M. A. Anisimov and J. V. Sengers, Int. J. Thermophys. 15 (1997) 1237.10.1007/BF02575258 ↗
20. M. Rivallin, A. Zeghlache, A. Soloviev, A. Gaunand and A. Kanaev, Chem. Eng. Trans. 1 (2002) 969.
21. R. E. Walpole, R. H. Myers and S. L. Myers, “ProÖaÖility and Statistics for Engineers and Scientists” (Prentice-Hall, 1998).
22. D. E. Guinnup and J. S. Schultz, J. Phys. Chem. 90 (1986) 3282.10.1021/j100405a047 ↗
23. R. Jullien, New J. Chem. 14 (1990) 239.